Issue 31, 2018

Preparation and characterisation of heterobimetallic copper–tungsten hydride complexes

Abstract

The preparation and structural characterisation of three new heterobimetallic hydride complexes containing 3-centre,2-electron W–H–Cu bonds is reported. These complexes have been characterised by single crystal X-ray crystallography and multinuclear NMR spectroscopy. The bonding in these complexes has been analysed by DFT calculations.

Graphical abstract: Preparation and characterisation of heterobimetallic copper–tungsten hydride complexes

Supplementary files

Article information

Article type
Paper
Submitted
20 apr 2018
Accepted
11 may 2018
First published
14 may 2018

Dalton Trans., 2018,47, 10595-10600

Preparation and characterisation of heterobimetallic copper–tungsten hydride complexes

A. Hicken, A. J. P. White and M. R. Crimmin, Dalton Trans., 2018, 47, 10595 DOI: 10.1039/C8DT01569D

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