Issue 6, 2018

Mesoporous manganese phthalocyanine-based materials for electrochemical water oxidation via tailored templating

Abstract

Electrochemical water splitting using non-noble metals as catalysts is of increasing importance for the future energy sector. In particular, efficient catalysts for the demanding oxygen evolution reaction present a major challenge. As a contribution to this field, tailored mesoporous hard template materials based on manganese phthalocyanine were prepared. The preparation method proved to be crucial to achieve suitable physicochemical properties as a basis for high catalytic activity. The materials show overpotentials between 490 and 590 mV at 10 mA cm−2 This can be mainly attributed to efficient graphitization, high Mn dispersion and tailored oxidation states.

Graphical abstract: Mesoporous manganese phthalocyanine-based materials for electrochemical water oxidation via tailored templating

Supplementary files

Article information

Article type
Communication
Submitted
06 dek 2017
Accepted
08 fev 2018
First published
22 fev 2018

Catal. Sci. Technol., 2018,8, 1517-1521

Mesoporous manganese phthalocyanine-based materials for electrochemical water oxidation via tailored templating

C. Broicher, J. Artz, S. Palkovits, H. Antoni, M. Drögeler, D. M. Morales, C. Stampfer and R. Palkovits, Catal. Sci. Technol., 2018, 8, 1517 DOI: 10.1039/C7CY02484C

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