Issue 9, 2017

Monodispersed sub-5.0 nm PtCu nanoalloys as enhanced bifunctional electrocatalysts for oxygen reduction reaction and ethanol oxidation reaction

Abstract

The development of effective electrocatalysts with enhanced activity and stability for both the anode and the cathode reaction in fuel cells still remains a challenge. Here, we report a one-pot route to prepare monodispersed, uniform sub-5.0 nm PtCu alloy polyhedra with a narrow size distribution. These PtCu alloy polyhedra exhibit enhanced electrocatalytic activity for both cathode and anode reactions as compared to the commercial Pt/C catalyst under alkaline conditions. The specific activity and mass activity on Pt68Cu32 nanoalloys are 15 and 2.8 times that on Pt/C catalyst toward oxygen reduction reaction (ORR), respectively. And the peak current density and mass activity on Pt68Cu32 nanoalloys are 11.8 and 2.12 times that on Pt/C catalyst toward ethanol oxidation reaction (EOR), respectively. Furthermore, the as-synthesized Pt68Cu32 nanoalloys have much higher stability than commercial Pt/C black for both ORR and EOR. These experimental results show an effective approach to the development of monodispersed, sub-5.0 nm PtCu nanoalloys as bifunctional electrocatalysts for both the cathode and the anode reaction in fuel cells.

Graphical abstract: Monodispersed sub-5.0 nm PtCu nanoalloys as enhanced bifunctional electrocatalysts for oxygen reduction reaction and ethanol oxidation reaction

Supplementary files

Article information

Article type
Communication
Submitted
09 yan 2017
Accepted
10 fev 2017
First published
10 fev 2017

Nanoscale, 2017,9, 2963-2968

Monodispersed sub-5.0 nm PtCu nanoalloys as enhanced bifunctional electrocatalysts for oxygen reduction reaction and ethanol oxidation reaction

T. Liu, K. Wang, Q. Yuan, Z. Shen, Y. Wang, Q. Zhang and X. Wang, Nanoscale, 2017, 9, 2963 DOI: 10.1039/C7NR00193B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements