Issue 21, 2014

9,9′-Spirobifluorene and 4-phenyl-9,9′-spirobifluorene: pure hydrocarbon small molecules as hosts for efficient green and blue PhOLEDs

Abstract

We report herein a new pure hydrocarbon material, 4-phenyl-9,9′-spirobifluorene (4-Ph-SBF), with a high triplet energy level (ET: 2.77 eV) as a host for blue phosphorescent organic light-emitting diodes (PhOLEDs). Structural, thermal, electrochemical and photophysical properties have been investigated in detail and compared to its constituting building block 9,9′-spirobifluorene (SBF) in order to precisely study the influence of the incorporation of a phenyl unit in C4. A surprising out of plane deformation of the fluorene ring and a highly twisted structure have been notably found for 4-Ph-SBF due to the substitution in C4. As both 4-Ph-SBF and SBF possess a high triplet energy level (2.77/2.87 eV resp.), they have been successfully used as host materials for green and blue PhOLEDs. The performance of blue PhOLEDs, ca. 20 cd A−1, appears to be among the highest reported for pure hydrocarbon derivatives.

Graphical abstract: 9,9′-Spirobifluorene and 4-phenyl-9,9′-spirobifluorene: pure hydrocarbon small molecules as hosts for efficient green and blue PhOLEDs

Supplementary files

Article information

Article type
Paper
Submitted
24 yan 2014
Accepted
28 fev 2014
First published
04 mar 2014

J. Mater. Chem. C, 2014,2, 4156-4166

Author version available

9,9′-Spirobifluorene and 4-phenyl-9,9′-spirobifluorene: pure hydrocarbon small molecules as hosts for efficient green and blue PhOLEDs

S. Thiery, D. Tondelier, C. Declairieux, G. Seo, B. Geffroy, O. Jeannin, J. Rault-Berthelot, R. Métivier and C. Poriel, J. Mater. Chem. C, 2014, 2, 4156 DOI: 10.1039/C4TC00171K

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