Issue 25, 2010
From the journal:

Chemical Communications

Unusual magnetic properties of a two-coordinate heteroleptic linear cobalt(ii) complex†

Chengbao Ni,a   Troy A. Stich,a   Gary J. Longb  and  Philip P. Power*a  

* Corresponding authors

a Department of Chemistry, University of California, One Shields Avenue, Davis, USA
E-mail: pppower@ucdavis.edu
Fax: +1 530-752-8995
Tel: +1 530-752-6910

b Department of Chemistry, Missouri University of Science and Technology, University of Missouri, Rolla, Missouri 65409-0010, USA

Abstract

The synthesis and characterization of two-coordinate cobalt(II) complexes CoAr′2 (1) and Ar′CoN(SiMe3)2 (2) (Ar′ = C6H3-2,6-(C6H3-2,6-iPr2)2) are reported. The magnetic data for 2 show that it has an unexpectedly high μeff of 5.65 μB whereas the bent complex 1 has a significantly lower moment.

Graphical abstract: Unusual magnetic properties of a two-coordinate heteroleptic linear cobalt(ii) complex

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Article information

DOI
https://doi.org/10.1039/C001483D
Article type
Communication
Submitted
22 yan 2010
Accepted
15 apr 2010
First published
20 may 2010

Chem. Commun., 2010,46, 4466-4468

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Unusual magnetic properties of a two-coordinate heteroleptic linear cobalt(II) complex

C. Ni, T. A. Stich, G. J. Long and P. P. Power, Chem. Commun., 2010, 46, 4466 DOI: 10.1039/C001483D

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