Issue 33, 2008
From the journal:

Dalton Transactions

Recent developments in the chemistry of low valent Group 14 hydrides†

Eric Rivarda  and  Philip P. Power*a  

* Corresponding authors

a Department of Chemistry, University of California, Davis, One Shields Ave., Davis, California, USA
E-mail: pppower@ucdavis.edu

Abstract

This Perspective discusses the synthesis and reactivity of low valent Group 14 hydrides of germanium and tin. The use of hindered terphenyl ligands has facilitated the isolation of a number of unusual new main group hydride structural types (each predicted by computational work), and has culminated in the use of these species as precursors to new cluster archetypes.

Graphical abstract: Recent developments in the chemistry of low valent Group 14 hydrides

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Article information

DOI
https://doi.org/10.1039/B801400K
Article type
Perspective
Submitted
25 yan 2008
Accepted
03 mar 2008
First published
24 iyl 2008

Dalton Trans., 2008, 4336-4343

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Recent developments in the chemistry of low valent Group 14 hydrides

E. Rivard and P. P. Power, Dalton Trans., 2008, 4336 DOI: 10.1039/B801400K

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