Issue 32, 2005

Enantiomerically pure P-chiral phosphinoselenoic chlorides: inversion of configuration at the P-chirogenic center in the synthesis and reaction of these substances

Abstract

Reaction of diastereomerically pure phosphinoselenoic acid salts with oxalyl chloride leads to enantiomerically pure P-chiral phosphinoselenoic chlorides with inversion of configuration at phosphorus; one of these chlorides is converted to a phosphinoselenothioic acid salt with a high degree of enantioselectivity.

Graphical abstract: Enantiomerically pure P-chiral phosphinoselenoic chlorides: inversion of configuration at the P-chirogenic center in the synthesis and reaction of these substances

Article information

Article type
Communication
Submitted
01 iyn 2005
Accepted
23 iyn 2005
First published
13 iyl 2005

Chem. Commun., 2005, 4077-4079

Enantiomerically pure P-chiral phosphinoselenoic chlorides: inversion of configuration at the P-chirogenic center in the synthesis and reaction of these substances

T. Kimura and T. Murai, Chem. Commun., 2005, 4077 DOI: 10.1039/B507755A

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