Issue 51, 2002

Pillared clay mimics from dicarboxylic acids and flexible diamines

Abstract

Three dicarboxylic acids3,5-pyrazoledicarboxylic acid, 3,5-pyridinedicarboxylic acid and isophthalic acid – are examined for their ability to participate in lamellar hydrogen-bonded networks upon reaction with alkyl diamines. The use of flexible diamines stems from a desire to mimic the structure and eventually the intercalative abilities of naturally occurring clays. Six structures are reported, with the carbon chain length varying from 3 to 12, and the relative ability of each of the diacids (in combination with flexible diamines) to construct clay-like materials is discussed.

Article information

Article type
Paper
Submitted
01 mar 2002
Accepted
24 apr 2002
First published
16 iyl 2002

CrystEngComm, 2002,4, 282-287

Pillared clay mimics from dicarboxylic acids and flexible diamines

A. M. Beatty, C. M. Schneider, A. E. Simpson and J. L. Zaher, CrystEngComm, 2002, 4, 282 DOI: 10.1039/B202193P

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