Boron-Enabled Stereoselective Synthesis of Polysubstituted Housanes

Hao Fang, Aimara García-Camacho, Ho Seong Hwang, Atthawut Sudsamart, Constantin G. Daniliuc, Oleksandr O. Grygorenko, Ignacio Funes-Ardoiz and John J. Molloy

J. Am. Chem. Soc., 2025, 147, 47730
DOI: 10.1021/jacs.5c17624

Visible-Light-Induced Radical [4 + 1] Annulation of Diazosulfonium Triflates with Cyclopropenes: Direct Synthesis of Benzofulvenes

Xue-Cen Xu, Jie Wang, Yue Gong and Yu-Long Zhao

Org. Lett., 2026, 28, 2655
DOI: 10.1021/acs.orglett.6c00047

Synthesis of Bicyclo[2.1.0]pentanes and Vinylcyclopropanes Using Palladium Carbenes: Ligand-Controlled Carbene Reactivity

Isaiah K. Eckart-Frank, Emily S. Arnold, Liam P. Murphy and Sidney M. Wilkerson-Hill

J. Am. Chem. Soc., 2025, 147, 33923
DOI: 10.1021/jacs.5c10617

Cyclopropenes in Photochemical Reactions

David Suárez‐García, Darío Coto and Rubén Vicente

Chemistry A European J, 2026, 32
DOI: 10.1002/chem.202503281

Divergent housane synthesis via intramolecular [2 + 2] cycloaddition of 1,4-dienes

Fuhao Zhang, Julius Domack, Niklas Hölter, Constantin G. Daniliuc and Frank Glorius

Nat. Synth, 2026
DOI: 10.1038/s44160-026-00997-7

Stereocontrolled Synthesis of Polysubstituted Housanes via gem-Bismetalated Cyclopropanes

Noam Orbach, Rahul Suresh and Ilan Marek

J. Am. Chem. Soc., 2026, 148, 12502
DOI: 10.1021/jacs.6c02374

Diastereoselective Synthesis of Housanes via the Carbocupration of Cyclopropenes

Clement Tanguy, Vladyslav Smyrnov, Matthew D. Wodrich and Jerome Waser

J. Am. Chem. Soc., 2026, 148, 15265
DOI: 10.1021/jacs.6c03013

Smallest Bicycles in Medicinal Chemistry: Where Are We Now?

Vladimir Kubyshkin and Pavel K. Mykhailiuk

Chem. Rev., 2026, 126, 3829
DOI: 10.1021/acs.chemrev.5c00779