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Stochastic Bullvalene Architecture Modulates Structural Rigidity in π‐Rich Macromolecules

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Ambimodal Pericyclic Rearrangements of Dialkenyl-Bullvalenes Give Tetrahydro-1,8-ethenoheptalenes

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Bullvalene “Ball Joint” Fluxionality Modulates Mechanics and Dynamic Fragility in Polymer Glass

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Exploring the Versatility of 7‐Alkynylcycloheptatriene Scaffolds Under π‐Acid Catalysis

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A Shapeshifting Roadmap for Polycyclic Skeletal Evolution

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Modulating Escape Channels of Cycloheptatrienyl Rhodium Carbenes To Form Semibullvalene

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Can density functional theory ‘Cope’ with highly fluxional shapeshifting molecules?

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Reversible Restrain and Release of the Dynamic Valence Isomerization in a Shape‐shifting Bullvalene by Complex Formation

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Connecting Molecular and Supramolecular Shapeshifting by the Ostwald’s Nucleation Stages of a Star Giant Molecule

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Molecular Ball Joints: Mechanochemical Perturbation of Bullvalene Hardy–Cope Rearrangements in Polymer Networks

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The Journey to Fluorescent Bullvalenes: Pitfalls and Prospects

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Taming Shapeshifting Anions: Total Synthesis of Ocellatusone C

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Silver-Catalyzed Unusual Cyclization and Skeletal Rearrangement to Selectively Synthesize 2D Benzo[a]fluorenones and 3D Barbaralone Rings

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Nucleophilic Dearomatization of Activated Pyridines Using Vinyl Sulfoxonium Ylides: Application to the Synthesis of Bis-Heterocycles

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Shapeshifting radicals

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Shape-shifters among water clusters

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Guest‐Dependent Isomer Convergence of a Permanently Fluxional Coordination Cage

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Bullvalene‐Containing Molecular Glasses

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Mechanical Taming of Hardy–Cope Rearrangements

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ACS Cent. Sci., 2026
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Steering the Shape‐shifting of Bullvalene‐PdII Complexes Through Steric and Geometric Strain

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Steering the Shape‐shifting of Bullvalene‐PdII Complexes Through Steric and Geometric Strain

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Shapeshifting Ligands Mask Lewis Acidity of Dicationic Palladium(II)

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Bullvalene‐Containing Molecular Glasses

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