Davide Arena, Ümit İşci, Mélanie Onofre, Christophe Nguyen, Zeynel Şahin, Ester Verde-Sesto, Amaia Iturrospe, Arantxa Arbe, Magali Gary-Bobo, José A. Pomposo and Fabienne Dumoulin

Mater. Adv., 2025, 6, 148
DOI: 10.1039/D4MA00524D

Bio-proton coupled semiconductor/metal-complex hybrid photoelectrocatalytic interface for efficient CO2 reduction

Jibo Liu, Chenyan Guo, Xiaojun Hu and Guohua Zhao

Green Chem., 2019, 21, 339
DOI: 10.1039/C8GC03066A

Multiple C–C bond formation upon electrocatalytic reduction of CO2 by an iron-based molecular macrocycle

Si-Thanh Dong, Chen Xu and Benedikt Lassalle-Kaiser

Chem. Sci., 2023, 14, 550
DOI: 10.1039/D2SC04729B

Electrocatalytic reduction of carbon dioxide: opportunities with heterogeneous molecular catalysts

Libo Sun, Vikas Reddu, Adrian C. Fisher and Xin Wang

Energy Environ. Sci., 2020, 13, 374
DOI: 10.1039/C9EE03660A

Facile synthesis of polymerized cobalt phthalocyanines for highly efficient CO2 reduction

Jiacheng Chen, Jiayu Li, Weiliang Liu, Xiaohua Ma, Jing Xu, Minghui Zhu and Yi-Fan Han

Green Chem., 2019, 21, 6056
DOI: 10.1039/C9GC02705J

Electron-withdrawing pyridine-functionalized g-C3N4-coordinated cobalt phthalocyanine for enhanced photocatalytic CO2 reduction

Xuehua Zhang, Chunlei Su, Rui Shi, Mingming Li, Lili Fu, Rongji Liu, Yong Chen, Bin Li and Guangjin Zhang

Ind. Chem. Mater., 2026
DOI: 10.1039/D5IM00296F

Anion exchange-induced single-molecule dispersion of cobalt porphyrins in a cationic porous organic polymer for enhanced electrochemical CO2 reduction via secondary-coordination sphere interactions

Jia-Kang Tang, Chen-Yuan Zhu, Tian-Wen Jiang, Lei Wei, Hui Wang, Ke Yu, Chun-Lei Yang, Yue-Biao Zhang, Chen Chen, Zhan-Ting Li, Dan-Wei Zhang and Li-Ming Zhang

J. Mater. Chem. A, 2020, 8, 18677
DOI: 10.1039/D0TA07068H

Furfural electrovalorisation using single-atom molecular catalysts

Zamaan Mukadam, Sihang Liu, Angus Pedersen, Jesús Barrio, Sarah Fearn, Saurav Ch. Sarma, Maria-Magdalena Titirici, Soren B. Scott, Ifan E. L. Stephens, Karen Chan and Stefano Mezzavilla

Energy Environ. Sci., 2023, 16, 2934
DOI: 10.1039/D3EE00551H

Exploring attached-buffer effects and Gibbs–Donnan equilibria in ionomeric energy-transduction materials

Lillian K. Hensleigh, Daiki Nishiori, Ian D. Peterson and Gary F. Moore

Chem. Commun., 2026, 62, 4744
DOI: 10.1039/D5CC05614D

Metals in polymers: hybridization enables new functions

Zichao Wei, Hanyi Duan, Gengsheng Weng and Jie He

J. Mater. Chem. C, 2020, 8, 15956
DOI: 10.1039/D0TC03810E

Controllable dispersion of cobalt phthalocyanine molecules on graphene oxide for enhanced electrocatalytic reduction of CO2 to CO

Weifeng Huang, Junqiang Li, Xiao Xu, Aihui Cao, Ying He, Miao Sun and Longtian Kang

New J. Chem., 2022, 46, 7153
DOI: 10.1039/D1NJ06182H

Recent advances in electrocatalysis with phthalocyanines

Shaoxuan Yang, Yihuan Yu, Xinjin Gao, Zhengping Zhang and Feng Wang

Chem. Soc. Rev., 2021, 50, 12985
DOI: 10.1039/D0CS01605E

Immobilization strategies for porphyrin-based molecular catalysts for the electroreduction of CO2

Maryam Abdinejad, Keith Tang, Caitlin Dao, Saeed Saedy and Tom Burdyny

J. Mater. Chem. A, 2022, 10, 7626
DOI: 10.1039/D2TA00876A

Molecular catalysis of CO2 reduction: recent advances and perspectives in electrochemical and light-driven processes with selected Fe, Ni and Co aza macrocyclic and polypyridine complexes

E. Boutin, L. Merakeb, B. Ma, B. Boudy, M. Wang, J. Bonin, E. Anxolabéhère-Mallart and M. Robert

Chem. Soc. Rev., 2020, 49, 5772
DOI: 10.1039/D0CS00218F

Improved charge delivery within a covalently ligated cobalt phthalocyanine electrocatalyst for CO2 reduction

Alena S. Kochubei, Aleksei N. Marianov, Oliver J. Conquest, Teng Lu, Yun Liu, Catherine Stampfl and Yijiao Jiang

J. Mater. Chem. A, 2025, 13, 1874
DOI: 10.1039/D4TA03220A

Design of polymer–metal nanocatalyst interfaces for the electrochemical CO2 reduction reaction

Xi Mao, Manthan Sarkar and Jie He

J. Mater. Chem. A, 2026, 14, 11848
DOI: 10.1039/D5TA09312K

Chromogenic detection of xylene isomers and luminogenic chemosensing of o-xylene employing a new macrocyclic cobalt complex: synthesis, and X-ray crystallographic, spectroscopic and computational studies

Bahram Ghanbari, Leila Asadi Mofarrah and Ali Jamjah

New J. Chem., 2022, 46, 20745
DOI: 10.1039/D2NJ04518D

Metal–organic framework-derived indium–copper bimetallic oxide catalysts for selective aqueous electroreduction of CO2

Weiwei Guo, Xiaofu Sun, Chunjun Chen, Dexin Yang, Lu Lu, Youdi Yang and Buxing Han

Green Chem., 2019, 21, 503
DOI: 10.1039/C8GC03261K

Incorporation of redox-inactive cations promotes iron catalyzed aerobic C–H oxidation at mild potentials

Teera Chantarojsiri, Joseph W. Ziller and Jenny Y. Yang

Chem. Sci., 2018, 9, 2567
DOI: 10.1039/C7SC04486K

How does mass transfer influence electrochemical carbon dioxide reduction reaction? A case study of Ni molecular catalyst supported on carbon

Chang Guo, Song Liu, Zhiwen Chen, Bingyu Li, Lixin Chen, Chandra Veer Singh, Bin Liu and Qing Mao

Chem. Commun., 2021, 57, 1384
DOI: 10.1039/D0CC07466G

Regulating nonmetallic species beyond the first coordination shell of single-atom catalysts for high-performance electrocatalysis

Wenpeng Ni, Houjun Chen, Junfeng Zeng, Yan Zhang, Hussein A. Younus, Zhouliangzi Zeng, Minyang Dai, Wei Zhang and Shiguo Zhang

Energy Environ. Sci., 2023, 16, 3679
DOI: 10.1039/D3EE02090H

Artificial photosynthesis: opportunities and challenges of molecular catalysts

Biaobiao Zhang and Licheng Sun

Chem. Soc. Rev., 2019, 48, 2216
DOI: 10.1039/C8CS00897C

In situ encapsulated and well dispersed Co3O4 nanoparticles as efficient and stable electrocatalysts for high-performance CO2 reduction

Hengpan Yang, Xinyao Yu, Jie Shao, Jingxuan Liao, Guodong Li, Qi Hu, Xiaoyao Chai, Qianling Zhang, Jianhong Liu and Chuanxin He

J. Mater. Chem. A, 2020, 8, 15675
DOI: 10.1039/D0TA03770B

Enzyme-mimicking redox-active vitamin B12 functionalized MWCNT catalyst for nearly 100% faradaic efficiency in electrochemical CO2 reduction

Yashly Yesudas K., Mani Balamurugan, Ki Tae Nam, Buvaneswari Gopal and Annamalai Senthil Kumar

J. Mater. Chem. A, 2024, 12, 31135
DOI: 10.1039/D4TA04145C

Group 6 transition metal-based molecular complexes for sustainable catalytic CO2activation

B. Rajeshwaree, Afsar Ali, Ab Qayoom Mir, Jagrit Grover, Goutam Kumar Lahiri, Arnab Dutta and Debabrata Maiti

Catal. Sci. Technol., 2022, 12, 390
DOI: 10.1039/D1CY01378E

Transition metal-based catalysts for the electrochemical CO2reduction: from atoms and molecules to nanostructured materials

Federico Franco, Clara Rettenmaier, Hyo Sang Jeon and Beatriz Roldan Cuenya

Chem. Soc. Rev., 2020, 49, 6884
DOI: 10.1039/D0CS00835D

Polymeric coatings for applications in electrocatalytic and photoelectrosynthetic fuel production

B. L. Wadsworth, D. Khusnutdinova and G. F. Moore

J. Mater. Chem. A, 2018, 6, 21654
DOI: 10.1039/C8TA05805A

Enhanced CO2 electroreduction via interaction of dangling S bonds and Co sites in cobalt phthalocyanine/ZnIn2S4 hybrids

Chunjun Chen, Xiaofu Sun, Dexin Yang, Lu Lu, Haihong Wu, Lirong Zheng, Pengfei An, Jing Zhang and Buxing Han

Chem. Sci., 2019, 10, 1659
DOI: 10.1039/C8SC03986K

Curvature-induced electronic tuning of molecular catalysts for CO2 reduction

Pengfei Tian, Bo Zhang, Jiacheng Chen, Jing Zhang, Libei Huang, Ruquan Ye, Bo Bao and Minghui Zhu

Catal. Sci. Technol., 2021, 11, 2491
DOI: 10.1039/D0CY01589J

Electrochemically substituted metal phthalocyanines, e-MPc (M = Co, Ni), as highly active and selective catalysts for CO2reduction

Yi Cheng, Jean-Pierre Veder, Lars Thomsen, Shiyong Zhao, Martin Saunders, Raffaella Demichelis, Chang Liu, Roland De Marco and San Ping Jiang

J. Mater. Chem. A, 2018, 6, 1370
DOI: 10.1039/C7TA09208C

Graphite conjugated nickel phthalocyanine for efficient CO2 electroreduction and Zn–CO2 batteries

Jingwei Han, Qiang Xu, Fengkun Tian, Hai Sun, Yuanyuan Qi, Guodong Zhang, Jun-Sheng Qin and Heng Rao

Chem. Sci., 2024, 15, 15670
DOI: 10.1039/D4SC02682A

Enhancing CO2 Reduction Efficiency on Cobalt Phthalocyanine via Axial Ligation

Hongxing Kang, Aaliyah Staples‐West, Audrey Washington, Chris Turchiano, Andrew Cooksy, Jier Huang and Jing Gu

ChemCatChem, 2023, 15
DOI: 10.1002/cctc.202300576

Covalent grafting of cobalt aminoporphyrin-based electrocatalyst onto carbon nanotubes for excellent activity in CO2 reduction

Shengshen Gu, Aleksei N. Marianov and Yijiao Jiang

Applied Catalysis B: Environmental, 2022, 300, 120750
DOI: 10.1016/j.apcatb.2021.120750

Emerging Carbon‐Based Heterogeneous Catalysts for Electrochemical Reduction of Carbon Dioxide into Value‐Added Chemicals

Jingjie Wu, Tiva Sharifi, Ying Gao, Tianyu Zhang and Pulickel M. Ajayan

Advanced Materials, 2019, 31
DOI: 10.1002/adma.201804257

The Influence of pH and Electrolyte Concentration on Fractional Protonation and CO2 Reduction Activity in Polymer-Encapsulated Cobalt Phthalocyanine

Taylor L. Soucy, William S. Dean, Kevin E. Rivera Cruz, Jonah B. Eisenberg, Lirong Shi and Charles C. L. McCrory

J. Phys. Chem. C, 2023, 127, 14041
DOI: 10.1021/acs.jpcc.3c01490

Cathode gas electrode modified with heterogeneous polymeric metal phthalocyanine for achieving high current density for CO2 electroreduction

Shanhe Gong, Wenbo Wang, Xu Han, Haotian Wang, Guilong Wang, Xuexue Wang, Jimin Xie, Dewei Rao, Chundu Wu, Jun Liu, Shouyan Shao, Minghui Zhu and Xiaomeng Lv

Chem Catalysis, 2024, 4, 100848
DOI: 10.1016/j.checat.2023.100848

Polyvinylpyridine-based electrodes: sensors and electrochemical applications

Ghobad Behzadi pour, Hamed Nazarpour fard, Leila Fekri aval and Parisa Esmaili

Ionics, 2020, 26, 549
DOI: 10.1007/s11581-019-03302-z

Cooperation of Two Metal Centers in a CO2 Electroreduction Catalyst: Flexible Electron Manipulation and Adaptive Coordination on a Dinuclear Cobalt Complex

Yunyi Pan, Masaki Donoshita, Yohei Kametani, Yoshihito Shiota, Shu‐Qi Wu, Osamu Sato and Miho Yamauchi

Advanced Science, 2025, 12
DOI: 10.1002/advs.202508361

First principles investigation of cobalt-phthalocyanine active site tuning via atomic linker immobilization for CO2 electroreduction

Oliver J. Conquest, Tanglaw Roman, Aleksei Marianov, Alena Kochubei, Yijiao Jiang and Catherine Stampfl

Journal of Catalysis, 2023, 422, 43
DOI: 10.1016/j.jcat.2023.04.001

Shallow Rate-Redox Potential Scaling in Aqueous Molecular Oxygen Reduction Electrocatalysis Across a Family of Iron Macrocycles

Travis Marshall-Roth, Liang Liu, Vennela Mannava, Deiaa M. Harraz, Brian J. Cook, R. Morris Bullock and Yogesh Surendranath

ACS Catal., 2024, 14, 18590
DOI: 10.1021/acscatal.4c06561

An Iron Porphyrin Complex with Pendant Pyridine Substituents Facilitates Electrocatalytic CO2 Reduction via Second Coordination Sphere Effects

Anthony R. Ramuglia, Vishal Budhija, Khoa H. Ly, Michael Marquardt, Matthias Schwalbe and Inez M. Weidinger

ChemCatChem, 2021, 13, 3934
DOI: 10.1002/cctc.202100625

The effect of extended conjugation on electrocatalytic CO2 reduction by molecular catalysts and macromolecular structures

Weixuan Nie, Drew E. Tarnopol and Charles C.L. McCrory

Current Opinion in Electrochemistry, 2021, 28, 100716
DOI: 10.1016/j.coelec.2021.100716

Light-Driven CO2 Reduction by Co-Cytochrome b562

Rafael Alcala-Torano, Nicholas Halloran, Noah Gwerder, Dayn J. Sommer and Giovanna Ghirlanda

Front. Mol. Biosci., 2021, 8
DOI: 10.3389/fmolb.2021.609654

Understanding the Effects of Electrolyzer Geometry and Flow Conditions on Methanol Formation via Gas-Fed Electrochemical CO2 Reduction

Libo Yao, Rachel Silcox, Kevin E. Rivera-Cruz, Jianping Bai, Charles C. L. McCrory, Rohini Bala Chandran and Nirala Singh

ACS Catal., 2025, 15, 15162
DOI: 10.1021/acscatal.5c04558

Effects of Substrate and Polymer Encapsulation on CO2 Electroreduction by Immobilized Indium(III) Protoporphyrin

Yuvraj Y. Birdja, Rafaël E. Vos, Tim A. Wezendonk, Lin Jiang, Freek Kapteijn and Marc T. M. Koper

ACS Catal., 2018, 8, 4420
DOI: 10.1021/acscatal.7b03386

Iron Porphyrins Embedded into a Supramolecular Porous Organic Cage for Electrochemical CO2 Reduction in Water

Peter T. Smith, Bahiru Punja Benke, Zhi Cao, Younghoon Kim, Eva M. Nichols, Kimoon Kim and Christopher J. Chang

Angewandte Chemie, 2018, 130, 9832
DOI: 10.1002/ange.201803873

Computational Modeling of Electrocatalysts for CO2 Reduction: Probing the Role of Primary, Secondary, and Outer Coordination Spheres

Christina M. Zeng and Julien A. Panetier

Acc. Chem. Res., 2025, 58, 342
DOI: 10.1021/acs.accounts.4c00631

Heterogenization of Molecular Electrocatalytic Active Sites through Reticular Chemistry

Minseok Kim, Jaekyung Yi, Seong‐Hyeon Park and Sarah S. Park

Advanced Materials, 2023, 35
DOI: 10.1002/adma.202203791

Recent Trends, Benchmarking, and Challenges of Electrochemical Reduction of CO2 by Molecular Catalysts

Kamal Elouarzaki, Vishvak Kannan, Vishal Jose, Harshjyot Singh Sabharwal and Jong‐Min Lee

Advanced Energy Materials, 2019, 9
DOI: 10.1002/aenm.201900090

A “Goldilocks Zone” in Bilayer Cobalt Phthalocyanine: Optimizing Confinement for Efficient CO2RR

Longlei Yin, Dongdong Qi, Tianyu Wang and Jianzhuang Jiang

Catalysts, 2026, 16, 328
DOI: 10.3390/catal16040328

Structural tuning of heterogeneous molecular catalysts for electrochemical energy conversion

Jiong Wang, Shuo Dou and Xin Wang

Sci. Adv., 2021, 7
DOI: 10.1126/sciadv.abf3989

Amine axial ligand-coordinated cobalt phthalocyanine-based catalyst for flow-type membraneless hydrogen peroxide fuel cell or enzymatic biofuel cell

Heeyeon An, Hyewon Jeon, Jungyeon Ji, Yongchai Kwon and Yongjin Chung

Journal of Energy Chemistry, 2021, 58, 463
DOI: 10.1016/j.jechem.2020.10.042

Rational Design of Polymers for Selective CO2 Reduction Catalysis

Jane J. Leung, Julian A. Vigil, Julien Warnan, Esther Edwardes Moore and Erwin Reisner

Angew Chem Int Ed, 2019, 58, 7697
DOI: 10.1002/anie.201902218

Phthalocyanine and porphyrin catalysts for electrocatalytic reduction of carbon dioxide: Progress in regulation strategies and applications

Jian Zhao, Honghong Lyu, Zhiqiang Wang, Chunlu Ma, Shuna Jia, Wenwen Kong and Boxiong Shen

Separation and Purification Technology, 2023, 312, 123404
DOI: 10.1016/j.seppur.2023.123404

Electrochemical Reduction of CO2 Using Group VII Metal Catalysts

Jacob A. Barrett, Christopher J. Miller and Clifford P. Kubiak

Trends in Chemistry, 2021, 3, 176
DOI: 10.1016/j.trechm.2020.12.009

Vitamin B12‐Immobilized Graphene Oxide for Efficient Electrocatalytic Carbon Dioxide Reduction Reaction

Natarajan Saravanan, Mani Balamurugan, K. S. Shalini Devi, Ki Tae Nam and Annamalai Senthil Kumar

ChemSusChem, 2020, 13, 5620
DOI: 10.1002/cssc.202001378

Dual single-cobalt atom-based carbon electrocatalysts for efficient CO2-to-syngas conversion with industrial current densities

Wenpeng Ni, Zhixiao Liu, Xiaoguang Guo, Yan Zhang, Chao Ma, Yijie Deng and Shiguo Zhang

Applied Catalysis B: Environmental, 2021, 291, 120092
DOI: 10.1016/j.apcatb.2021.120092

Charged Macromolecular Rhenium Bipyridine Catalysts with Tunable CO2 Reduction Potentials

Swagat Sahu, Po Ling Cheung, Charles W. Machan, Steven A. Chabolla, Clifford P. Kubiak and Nathan C. Gianneschi

Chemistry A European J, 2017, 23, 8619
DOI: 10.1002/chem.201701901

Advances in Metal Phthalocyanine based Carbon Composites for Electrocatalytic CO2 Reduction

Zijun Yue, Caixia Ou, Nengwen Ding, Lihong Tao, Jianjun Zhao and Jun Chen

ChemCatChem, 2020, 12, 6103
DOI: 10.1002/cctc.202001126

Single-Point Linkage Engineering in Conjugated Phthalocyanine-Based Covalent Organic Frameworks for Electrochemical CO2 Reduction

Wenchang Chen, Yi Zhang, Mingyu Yang, Chao Yang and Zheng Meng

Nano-Micro Lett., 2025, 17
DOI: 10.1007/s40820-025-01754-9

Molecular Catalysts Boost the Rate of Electrolytic CO2 Reduction

Kristian Torbensen, Dorian Joulié, Shaoxuan Ren, Min Wang, Danielle Salvatore, Curtis P. Berlinguette and Marc Robert

ACS Energy Lett., 2020, 5, 1512
DOI: 10.1021/acsenergylett.0c00536

Enhanced electrocatalytic activity of iron amino porphyrins using a flow cell for reduction of CO2 to CO

Maryam Abdinejad, Caitlin Dao, Xiao-An Zhang and Heinz Bernhard Kraatz

Journal of Energy Chemistry, 2021, 58, 162
DOI: 10.1016/j.jechem.2020.09.039

Electrochemistry of Polymeric Cobaloxime-Containing Assemblies in Organic and Aqueous Solvents

Brian L. Wadsworth, Daiki Nishiori, Nghi P. Nguyen, Edgar A. Reyes Cruz and Gary F. Moore

ECS J. Solid State Sci. Technol., 2020, 9, 061018
DOI: 10.1149/2162-8777/aba1ff

Heterogeneous electrocatalytic reduction of carbon dioxide with transition metal complexes

Ariel Friedman and Lior Elbaz

Journal of Catalysis, 2021, 395, 23
DOI: 10.1016/j.jcat.2020.12.004

Improved NH3 Uptake of a Macromolecule–Metal Complex Constructed with Dual Polymeric Ligands and M(II)

Xiaoyan Luo, Renhui Ling, Runjia Xing, Yibang Liu, Jiahui Wan, Mingxing Li and Congmin Wang

ACS Appl. Mater. Interfaces, 2024, 16, 6495
DOI: 10.1021/acsami.3c16465

Elucidating influence of the existence formation of anchored cobalt phthalocyanine on electrocatalytic CO2-to-CO conversion

Shanhe Gong, Wenbo Wang, Xinxin Xiao, Jun Liu, Chundu Wu and Xiaomeng Lv

Nano Energy, 2021, 84, 105904
DOI: 10.1016/j.nanoen.2021.105904

Bioinspired and biomolecular catalysts for energy conversion and storage

Alison A. Salamatian and Kara L. Bren

FEBS Letters, 2023, 597, 174
DOI: 10.1002/1873-3468.14533

Stable Dioxin‐Linked Metallophthalocyanine Covalent Organic Frameworks (COFs) as Photo‐Coupled Electrocatalysts for CO2Reduction

Meng Lu, Mi Zhang, Chun‐Guang Liu, Jiang Liu, Lin‐Jie Shang, Min Wang, Jia‐Nan Chang, Shun‐Li Li and Ya‐Qian Lan

Angew Chem Int Ed, 2021, 60, 4864
DOI: 10.1002/anie.202011722

Cobalt-nitrogen-carbon sites on carbon aerogels for enhanced electrocatalytic CO2 activity

Bo Zhang, Shanhe Gong, Guilong Wang, Chundu Wu, Guolan Zhao and Xiaomeng Lv

Applied Surface Science, 2023, 630, 157437
DOI: 10.1016/j.apsusc.2023.157437

Molecular electrocatalysts can mediate fast, selective CO 2 reduction in a flow cell

Shaoxuan Ren, Dorian Joulié, Danielle Salvatore, Kristian Torbensen, Min Wang, Marc Robert and Curtis P. Berlinguette

Science, 2019, 365, 367
DOI: 10.1126/science.aax4608

Heterogeneous molecular catalysts for electrocatalytic CO2 reduction

Nathan Corbin, Joy Zeng, Kindle Williams and Karthish Manthiram

Nano Res., 2019, 12, 2093
DOI: 10.1007/s12274-019-2403-y

Electrochemical Reduction of CO2 to CO by a Co‐N‐C Electrocatalyst and PEM Reactor at Ambient Conditions

Hitoshi Ogihara, Tomomi Maezuru, Yuji Ogishima and Ichiro Yamanaka

ChemistrySelect, 2016, 1, 5533
DOI: 10.1002/slct.201601082

Revealing the hidden performance of metal phthalocyanines for CO2 reduction electrocatalysis by hybridization with carbon nanotubes

Zhan Jiang, Yang Wang, Xiao Zhang, Hongzhi Zheng, Xiaojun Wang and Yongye Liang

Nano Res., 2019, 12, 2330
DOI: 10.1007/s12274-019-2455-z

Highly Efficient Carbon Dioxide Electroreduction via DNA-Directed Catalyst Immobilization

Gang Fan, Nathan Corbin, Minju Chung, Thomas M. Gill, Evan B. Moore, Amruta A. Karbelkar and Ariel L. Furst

JACS Au, 2024, 4, 1413
DOI: 10.1021/jacsau.3c00823

Structural and interfacial engineering of well-defined metal-organic ensembles for electrocatalytic carbon dioxide reduction

Fenglei Lyu, Wei Hua, Huirong Wu, Hao Sun, Zhao Deng and Yang Peng

Chinese Journal of Catalysis, 2022, 43, 1417
DOI: 10.1016/S1872-2067(21)63980-3

Modulating the mechanism of electrocatalytic CO2 reduction by cobalt phthalocyanine through polymer coordination and encapsulation

Yingshuo Liu and Charles C. L. McCrory

Nat Commun, 2019, 10
DOI: 10.1038/s41467-019-09626-8

Hydrophobic Copper Interfaces Boost Electroreduction of Carbon Dioxide to Ethylene in Water

Hong-Qing Liang, Siqi Zhao, Xin-Ming Hu, Marcel Ceccato, Troels Skrydstrup and Kim Daasbjerg

ACS Catal., 2021, 11, 958
DOI: 10.1021/acscatal.0c03766

Effects of Axial Functional Groups on Heterogeneous Molecular Catalysts for Electrocatalytic CO2 Reduction

Libo Sun, Vikas Reddu, Tan Su, Xinqi Chen, Tian Wu, Wei Dai, Adrian C. Fisher and Xin Wang

Small Structures, 2021, 2
DOI: 10.1002/sstr.202100093

Kinetics of the Trans Effect in Ruthenium Complexes Provide Insight into the Factors That Control Activity and Stability in CO2 Electroreduction

Sergio Gonell, Eric A. Assaf, Kyle D. Duffee, Cynthia K. Schauer and Alexander J. M. Miller

J. Am. Chem. Soc., 2020, 142, 8980
DOI: 10.1021/jacs.0c02912

Mitigating Cobalt Phthalocyanine Aggregation in Electrocatalyst Films through Codeposition with an Axially Coordinating Polymer

William S. Dean, Taylor L. Soucy, Kevin E. Rivera‐Cruz, Leila L. Filien, Bradley D. Terry and Charles C. L. McCrory

Small, 2025, 21
DOI: 10.1002/smll.202402293

Nitrogen-containing polymers as a platform for CO2 electroreduction

Sathish Ponnurangam, Irina V. Chernyshova and Ponisseril Somasundaran

Advances in Colloid and Interface Science, 2017, 244, 184
DOI: 10.1016/j.cis.2016.09.002

Synthetic Organic Design for Solar Fuel Systems

Julien Warnan and Erwin Reisner

Angew Chem Int Ed, 2020, 59, 17344
DOI: 10.1002/anie.202006013

Towards molecular understanding of local chemical environment effects in electro- and photocatalytic CO2 reduction

Andreas Wagner, Constantin D. Sahm and Erwin Reisner

Nat Catal, 2020, 3, 775
DOI: 10.1038/s41929-020-00512-x

Electropolymerization of poly-5,10,15,20-tetrakis(p-aminophenyl)porphyrin in different deposition modes and solvents

Mariya V. Tesakova, Oskar I. Koifman and Vladimir I. Parfenyuk

J. Porphyrins Phthalocyanines, 2018, 22, 632
DOI: 10.1142/S1088424618500864

Recent advances on electrocatalytic CO2 reduction to resources: Target products, reaction pathways and typical catalysts

Yaru Lei, Zheng Wang, Ai Bao, Xiaolong Tang, Xiubing Huang, Honghong Yi, Shunzheng Zhao, Ting Sun, Junyi Wang and Fengyu Gao

Chemical Engineering Journal, 2023, 453, 139663
DOI: 10.1016/j.cej.2022.139663

Conductive phthalocyanine-based metal-organic framework as a highly efficient electrocatalyst for carbon dioxide reduction reaction

Meng-Di Zhang, Duan-Hui Si, Jun-Dong Yi, Qi Yin, Yuan-Biao Huang and Rong Cao

Sci. China Chem., 2021, 64, 1332
DOI: 10.1007/s11426-021-1022-3

Ternary heterostructural CoO/CN/Ni catalyst for promoted CO2 electroreduction to methanol

Liwen Wang, Yida Xu, Teng Chen, Dali Wei, Xuefeng Guo, Luming Peng, Nianhua Xue, Yan Zhu, Mengning Ding and Weiping Ding

Journal of Catalysis, 2021, 393, 83
DOI: 10.1016/j.jcat.2020.11.012

Free-Standing Single-Atom Catalyst-Based Electrodes for CO2 Reduction

M. Nur Hossain, Lei Zhang, Roberto Neagu and Enoch Rassachack

Electrochem. Energy Rev., 2024, 7
DOI: 10.1007/s41918-023-00193-7

Chemical Modifications of Ag Catalyst Surfaces with Imidazolium Ionomers Modulate H2 Evolution Rates during Electrochemical CO2 Reduction

David M. Koshy, Sneha A. Akhade, Adam Shugar, Kabir Abiose, Jingwei Shi, Siwei Liang, James S. Oakdale, Stephen E. Weitzner, Joel B. Varley, Eric B. Duoss, Sarah E. Baker, Christopher Hahn, Zhenan Bao and Thomas F. Jaramillo

J. Am. Chem. Soc., 2021, 143, 14712
DOI: 10.1021/jacs.1c06212

Recent advances in the rational designing of metalloporphyrinoid-based CO2 reduction catalysts: From molecular structural tuning to the application in catalysis

Beatriu Domingo-Tafalla, Tamal Chatterjee and Emilio Palomares

J. Porphyrins Phthalocyanines, 2023, 27, 23
DOI: 10.1142/S1088424623300033

Electrocatalytic CO2 to CO and Methanol Conversion Using a Molecular Cobalt Corrole Complex

Afridi Zamader, Ajeet Singh, Bishnubasu Giri, Marcello Caruso, W. Ryan Osterloh, Nicolas Desbois, Claude P. Gros and Marc Robert

ACS Catal., 2025, 15, 11093
DOI: 10.1021/acscatal.5c02857

Iron Porphyrins Embedded into a Supramolecular Porous Organic Cage for Electrochemical CO2 Reduction in Water

Peter T. Smith, Bahiru Punja Benke, Zhi Cao, Younghoon Kim, Eva M. Nichols, Kimoon Kim and Christopher J. Chang

Angew Chem Int Ed, 2018, 57, 9684
DOI: 10.1002/anie.201803873

Metal-Coordinated Polymer–Inorganic Hybrids: Synthesis, Properties, and Application

Shaghayegh Abtahi, Nayanathara Hendeniya, Sharif Tasnim Mahmud, Gabriel Mogbojuri, Chizoba Livina Iheme and Boyce Chang

Polymers, 2025, 17, 136
DOI: 10.3390/polym17020136

A Porphyrin/Graphene Framework: A Highly Efficient and Robust Electrocatalyst for Carbon Dioxide Reduction

Jaecheol Choi, Pawel Wagner, Rouhollah Jalili, Jeonghun Kim, Douglas R. MacFarlane, Gordon G. Wallace and David L. Officer

Advanced Energy Materials, 2018, 8
DOI: 10.1002/aenm.201801280

Covalently Grafting Cobalt Porphyrin onto Carbon Nanotubes for Efficient CO2 Electroreduction

Minghui Zhu, Jiacheng Chen, Libei Huang, Ruquan Ye, Jing Xu and Yi‐Fan Han

Angew Chem Int Ed, 2019, 58, 6595
DOI: 10.1002/anie.201900499

Conjugated nickel phthalocyanine polymer selectively catalyzes CO2-to-CO conversion in a wide operating potential window

Shuting Wei, Haiyuan Zou, Weifeng Rong, Fuxiang Zhang, Yongfei Ji and LeLe Duan

Applied Catalysis B: Environmental, 2021, 284, 119739
DOI: 10.1016/j.apcatb.2020.119739

Pre‐Activation of CO2 at Cobalt Phthalocyanine‐Mg(OH)2 Interface for Enhanced Turnover Rate

Fenglei Lyu, Bingyun Ma, Xulan Xie, Daqi Song, Yuebin Lian, Hao Yang, Wei Hua, Hao Sun, Jun Zhong, Zhao Deng, Tao Cheng and Yang Peng

Adv Funct Materials, 2023, 33
DOI: 10.1002/adfm.202214609

High-performance CoII-phthalocyanine-based polymer for practical heterogeneous electrochemical reduction of carbon dioxide

Jirapong Luangchaiyaporn, Dominik Wielend, Dmytro Solonenko, Hathaichanok Seelajaroen, Jacek Gasiorowski, Manuel Monecke, Georgeta Salvan, Dietrich R.T. Zahn, Niyazi Serdar Sariciftci and Patchanita Thamyongkit

Electrochimica Acta, 2021, 367, 137506
DOI: 10.1016/j.electacta.2020.137506

Translating Catalyst–Polymer Composites from Liquid to Gas-Fed CO2 Electrolysis: A CoPc-P4VP Case Study

Libo Yao, Claire Yin, Kevin E. Rivera-Cruz, Charles C. L. McCrory and Nirala Singh

ACS Appl. Mater. Interfaces, 2023, 15, 31438
DOI: 10.1021/acsami.3c04085

Tuning the Metal Electronic Structure of Anchored Cobalt Phthalocyanine via Dual‐Regulator for Efficient CO2 Electroreduction and Zn–CO2 Batteries

Shanhe Gong, Wenbo Wang, Chaonan Zhang, Minghui Zhu, Runqing Lu, Jinjin Ye, Huan Yang, Chundu Wu, Jun Liu, Dewei Rao, Shouyan Shao and Xiaomeng Lv

Adv Funct Materials, 2022, 32
DOI: 10.1002/adfm.202110649

Heterogeneous carbon dioxide reduction reaction by cobalt complexes of 4′,4′′′-disubstituted derivatives of quinquepyridine immobilized on carbon black

Vikas Reddu, Libo Sun, Shuo Duo, Xinqi Chen, Tian Wu, Wei Dai and Xin Wang

Electrochimica Acta, 2021, 380, 138224
DOI: 10.1016/j.electacta.2021.138224

Reordering d Orbital Energies of Single‐Site Catalysts for CO2 Electroreduction

Jianyu Han, Pengfei An, Shuhu Liu, Xiaofei Zhang, Dawei Wang, Yi Yuan, Jun Guo, Xueying Qiu, Ke Hou, Lin Shi, Yin Zhang, Shenlong Zhao, Chang Long and Zhiyong Tang

Angewandte Chemie, 2019, 131, 12841
DOI: 10.1002/ange.201907399

Re(tBu-bpy)(CO)3Cl Supported on Multi-Walled Carbon Nanotubes Selectively Reduces CO2 in Water

Almagul Zhanaidarova, Simon C. Jones, Emmanuelle Despagnet-Ayoub, Brian R. Pimentel and Clifford P. Kubiak

J. Am. Chem. Soc., 2019, 141, 17270
DOI: 10.1021/jacs.9b08445

Molecular Engineering of Metal Complexes for Electrocatalytic Carbon Dioxide Reduction: From Adjustment of Intrinsic Activity to Molecular Immobilization

Zhi‐Wen Yang, Jin‐Mei Chen, Li‐Qi Qiu, Wen‐Jun Xie and Liang‐Nian He

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202205301

In-situ growing nickel phthalocyanine supramolecular structure on carbon nanotubes for efficient electrochemical CO2 conversion

Yucheng Jin, Xiaoning Zhan, Yingting Zheng, Hailong Wang, Xiaolin Liu, Baoqiu Yu, Xu Ding, Tianyu Zheng, Kang Wang, Dongdong Qi and Jianzhuang Jiang

Applied Catalysis B: Environmental, 2023, 327, 122446
DOI: 10.1016/j.apcatb.2023.122446

Considering the Influence of Polymer–Catalyst Interactions on the Chemical Microenvironment of Electrocatalysts for the CO2 Reduction Reaction

Taylor L. Soucy, William S. Dean, Jukai Zhou, Kevin E. Rivera Cruz and Charles C. L. McCrory

Acc. Chem. Res., 2022, 55, 252
DOI: 10.1021/acs.accounts.1c00633

Synthesis of a Triangle-Fused Six-Pointed Star and Its Electrocatalytic CO2 Reduction Activity

Guotao Wang, Zi-Xi Zhang, Hao Chen, Yingxue Fu, Kaisong Xiang, Ermeng Han, Tun Wu, Qixia Bai, Pei-Yang Su, Zhujiang Wang, Die Liu, Fenghua Shen, Hui Liu, Zhilong Jiang, Jie Yuan, Yiming Li and Pingshan Wang

Inorg. Chem., 2024, 63, 7442
DOI: 10.1021/acs.inorgchem.4c00550

Recent Progress in (Photo-)-Electrochemical Conversion of CO2 With Metal Porphyrinoid-Systems

Dženeta Dedić, Adrian Dorniak, Uwe Rinner and Wolfgang Schöfberger

Front. Chem., 2021, 9
DOI: 10.3389/fchem.2021.685619

Insight into the Effect of the d-Orbital Energy of Copper Ions in Metal–Organic Frameworks on the Selectivity of Electroreduction of CO2 to CH4

Yuan-Yuan Liu, Hao-Lin Zhu, Zhen-Hua Zhao, Ning-Yu Huang, Pei-Qin Liao and Xiao-Ming Chen

ACS Catal., 2022, 12, 2749
DOI: 10.1021/acscatal.1c04805

Influence of the molecular structure of metal-phthalocyanine on electrocatalytic reactions

Da Sol Jeong, Hyeon Suk Shin and Jieun Yang

Sci. China Mater., 2022, 65, 3324
DOI: 10.1007/s40843-022-2131-1

Molecular Enhancement of Direct Electrolysis of Dilute CO2

Bingyu Chen, Youwen Rong, Xiang Li, Jiaqi Sang, Pengfei Wei, Qingda An, Dunfeng Gao and Guoxiong Wang

ACS Energy Lett., 2024, 9, 911
DOI: 10.1021/acsenergylett.3c02812

Controlled Substrate Transport to Electrocatalyst Active Sites for Enhanced Selectivity in the Carbon Dioxide Reduction Reaction

Yingshuo Liu, Kwan Yee Leung, Samuel E. Michaud, Taylor L. Soucy and Charles C. L. McCrory

Comments on Inorganic Chemistry, 2019, 39, 242
DOI: 10.1080/02603594.2019.1628025

Engineering Metal–Organic Frameworks for the Electrochemical Reduction of CO2: A Minireview

Riming Wang, Freek Kapteijn and Jorge Gascon

Chemistry An Asian Journal, 2019, 14, 3452
DOI: 10.1002/asia.201900710

Electrocatalytic Reduction of CO2 to CH4 and CO in Aqueous Solution Using Pyridine-Porphyrins Immobilized onto Carbon Nanotubes

Maryam Abdinejad, Caitlin Dao, Billy Deng, Filip Dinic, Oleksandr Voznyy, Xiao-an Zhang and Heinz-Bernhard Kraatz

ACS Sustainable Chem. Eng., 2020, 8, 9549
DOI: 10.1021/acssuschemeng.0c02791

Metal‐Terpyridine Complexes in Catalytic Application – A Spotlight on the Last Decade

Andreas Winter and Ulrich S. Schubert

ChemCatChem, 2020, 12, 2890
DOI: 10.1002/cctc.201902290

Electrocatalytic reduction of CO2 to CO over iron phthalocyanine-modified graphene nanocomposites

Xiaoxin Li, Guoliang Chai, Xiao Xu, Jingjing Liu, Zhou Zhong, Aihui Cao, Zhijie Tao, Weifeng You and Longtian Kang

Carbon, 2020, 167, 658
DOI: 10.1016/j.carbon.2020.06.036

Recent Advances in Four‐Coordinated Planar Cobalt Catalysis in Organic Synthesis

Takuya Michiyuki and Kimihiro Komeyama

Asian J Org Chem, 2020, 9, 343
DOI: 10.1002/ajoc.201900625

Electronic Delocalization Regulates the Occupancy and Energy Level of Co 3dz2 Orbitals to Enhance Bifunctional Oxygen Catalytic Activity

Yun‐Long Zhang, Bo Liu, Yun‐Kun Dai, Yun‐Fei Xia, Pan Guo, Yang‐Yang Liu, Fantao Kong, Qianyu Zhang, Lei Zhao and Zhen‐Bo Wang

Adv Funct Materials, 2022, 32
DOI: 10.1002/adfm.202209499

The origins of catalytic selectivity for the electrochemical conversion of carbon dioxide to methanol

Tian Wang, Yating Wang, Yuhang Li and Chunzhong Li

Nano Res., 2024, 17, 5
DOI: 10.1007/s12274-023-5653-7

Strengthening Intermediate Adsorption on a Cobalt Phthalocyanine Assembly by Polymeric Modification for Electrochemical Carbon Dioxide Reduction into Methanol

Poe Ei Phyu Win, Xin Xu, Lilong Zhang, Song Yang, Shibin Ren, Yu Chen and Jiong Wang

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202517033

Highly Efficient and Selective Electrocatalytic CO2-to-CO Conversion by a Non-heme Iron Complex with an In-Plane N4 Ligand in Heterogeneous Aqueous Media

Eman A. Mohamed, Zaki N. Zahran, Yuta Tsubonouchi, Kenji Saito, Tatsuto Yui and Masayuki Yagi

ACS Appl. Energy Mater., 2020, 3, 4114
DOI: 10.1021/acsaem.9b02548

Molecular Nitrogen–Carbon Catalysts, Solid Metal Organic Framework Catalysts, and Solid Metal/Nitrogen‐Doped Carbon (MNC) Catalysts for the Electrochemical CO2 Reduction

Ana Sofia Varela, Wen Ju and Peter Strasser

Advanced Energy Materials, 2018, 8
DOI: 10.1002/aenm.201703614

Linkage Effect in the Heterogenization of Cobalt Complexes by Doped Graphene for Electrocatalytic CO2 Reduction

Jiong Wang, Xiang Huang, Shibo Xi, Jong‐Min Lee, Cheng Wang, Yonghua Du and Xin Wang

Angew Chem Int Ed, 2019, 58, 13532
DOI: 10.1002/anie.201906475

Modulating the spin state of the nickel site through axial phosphorus coordination to enhance CO2 electroreduction

Quanxiao Deng, Dezhong Song, Youzhen Liu, Ruizhi Yin, Chunyan Liu and Jia Huo

Applied Surface Science, 2025, 703, 163407
DOI: 10.1016/j.apsusc.2025.163407

Electronic Configuration Regulation by N‐Doped MXenes Boosting Electrocatalytic Performance of Cobalt Phthalocyanine

Wenlin Zhang, Tingting He, Shimeng Liu, Lu‐Hua Zhang and Fengshou Yu

Eur J Inorg Chem, 2023, 26
DOI: 10.1002/ejic.202200489

Stepwise Construction of Supramolecular A2B4‐Type Miktoarm Star Copolymers with a Cobalt Phthalocyanine Core

Xinhao Zhong, Hsu‐Tzu Cheng, Chu‐Chen Chueh, Masayuki Takeuchi and Junko Aimi

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202403749

Reorganization of Interfacial Water by an Amphiphilic Cationic Surfactant Promotes CO2 Reduction

Zhuo-Qun Zhang, Soumyodip Banerjee, V. Sara Thoi and Anthony Shoji Hall

J. Phys. Chem. Lett., 2020, 11, 5457
DOI: 10.1021/acs.jpclett.0c01334

Cobalt(II) Coordination Polymers Assembled from Unexplored Pyridine-Carboxylic Acids: Structural Diversity and Catalytic Oxidation of Alcohols

Jinzhong Gu, Min Wen, Yan Cai, Zifa Shi, Dmytro S. Nesterov, Marina V. Kirillova and Alexander M. Kirillov

Inorg. Chem., 2019, 58, 5875
DOI: 10.1021/acs.inorgchem.9b00242

Surface-Immobilized Conjugated Polymers Incorporating Rhenium Bipyridine Motifs for Electrocatalytic and Photocatalytic CO2 Reduction

Nicholas M. Orchanian, Lorena E. Hong, John A. Skrainka, Jacques A. Esterhuizen, Damir A. Popov and Smaranda C. Marinescu

ACS Appl. Energy Mater., 2019, 2, 110
DOI: 10.1021/acsaem.8b01745

Mechanistic Elucidations of Highly Dispersed Metalloporphyrin Metal‐Organic Framework Catalysts for CO2Electroreduction

Michael R. Smith, Clare B. Martin, Sonia Arumuganainar, Ari Gilman, Bruce E. Koel and Michele L. Sarazen

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202218208

Electrochemical CO2 Reduction to Methanol by Cobalt Phthalocyanine: Quantifying CO2 and CO Binding Strengths and Their Influence on Methanol Production

Libo Yao, Kevin E. Rivera-Cruz, Paul M. Zimmerman, Nirala Singh and Charles C. L. McCrory

ACS Catal., 2024, 14, 366
DOI: 10.1021/acscatal.3c04957

Strategies for Stabilizing Atomically Dispersed Metal Catalysts

Ruixuan Qin, Pengxin Liu, Gang Fu and Nanfeng Zheng

Small Methods, 2018, 2
DOI: 10.1002/smtd.201700286

Noncovalent Construction of Hangman Cobalt Phthalocyanine for Enhanced Electrochemical Carbon Dioxide Reduction

Ye Zhou, Xiaoyue Duan, Xin Xu, Poe Ei Phyu Win, Shi-Bin Ren and Jiong Wang

Chem. Mater., 2025, 37, 360
DOI: 10.1021/acs.chemmater.4c02697

Two‐dimensional Metal‐organic Frameworks for Electrochemical CO2 Reduction Reaction

Tingting Zhan, Yingbing Zou, Ying Yang, Xiuling Ma, Zhangjing Zhang and Shengchang Xiang

ChemCatChem, 2022, 14
DOI: 10.1002/cctc.202101453

Tetra-(benzo-24-crown-8)-phthalocyanines as a platform for supramolecular ensembles: Synthesis and interaction with viologen

Evgeniya A. Safonova, Jennifer A. Wytko, Jean Weiss, Elena A. Ugolkova, Nikolay N. Efimov, Vadim V. Minin, Yulia G. Gorbunova and Aslan Yu. Tsivadze

J. Porphyrins Phthalocyanines, 2020, 24, 1083
DOI: 10.1142/S1088424620500297

Electrode Integration of Synthetic Hydrogenase as Bioinspired and Noble Metal-Free Cathodes for Hydrogen Evolution

Afridi Zamader, Bertrand Reuillard, Pierre Marcasuzaa, Antoine Bousquet, Laurent Billon, Jose Jorge Espí Gallart, Gustav Berggren and Vincent Artero

ACS Catal., 2023, 13, 1246
DOI: 10.1021/acscatal.2c05175

Single atom-based catalysts for electrochemical CO2 reduction

Qian Sun, Chen Jia, Yong Zhao and Chuan Zhao

Chinese Journal of Catalysis, 2022, 43, 1547
DOI: 10.1016/S1872-2067(21)64000-7

High‐Rate and Selective Conversion of Low‐Concentration Carbon Dioxide to Carbon Monoxide Using a Carbon Nanotube‐Supported Molecular Electrocatalyst

Tzu‐Hsuan Wang, Fitri Nur Indah Sari, Yen‐Peng Cheng, Eunice Estrella De Guzman, Adriana Matamoros‐Veloza, Miller Alonso Camargo‐Valero and Chia‐Yu Lin

Small, 2026, 22
DOI: 10.1002/smll.202512257

Non-peripheral octamethyl-substituted cobalt phthalocyanine nanorods supported on N-doped reduced graphene oxide achieve efficient electrocatalytic CO2 reduction to CO

Minzhang Li, Chunliu Yan, Rajendran Ramachandran, Yangchun Lan, Hao Dai, Haiquan Shan, Xiangchao Meng, Dehu Cui, Fei Wang and Zong-Xiang Xu

Chemical Engineering Journal, 2022, 430, 133050
DOI: 10.1016/j.cej.2021.133050

Photoelectrochemical Reduction of CO2 Promoted by a Molecular Hybrid Made Up of Co(II)Pc on Graphene Oxide under Visible Light Illumination

Neha Nandal, Nilesh R. Manwar, B. Moses Abraham, Praveen K. Khatri and Suman L. Jain

Energy Fuels, 2022, 36, 3760
DOI: 10.1021/acs.energyfuels.2c00096

Fullerene Promotes CO2 Reduction to Methanol by a Cobalt(II) Phthalocyanine Electrocatalyst

Emmanuel Adu Fosu, Mawuli Deegbey and Elena Jakubikova

Inorg. Chem., 2025, 64, 12390
DOI: 10.1021/acs.inorgchem.5c02178

Strengthening Intermediate Adsorption on a Cobalt Phthalocyanine Assembly by Polymeric Modification for Electrochemical Carbon Dioxide Reduction into Methanol

Poe Ei Phyu Win, Xin Xu, Lilong Zhang, Song Yang, Shibin Ren, Yu Chen and Jiong Wang

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202517033

Molecular Engineering of Metal Complexes for Electrocatalytic Carbon Dioxide Reduction: From Adjustment of Intrinsic Activity to Molecular Immobilization

Zhi‐Wen Yang, Jin‐Mei Chen, Li‐Qi Qiu, Wen‐Jun Xie and Liang‐Nian He

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202205301

Structure–Activity Relationships in Coordination Polymer-Based Electrocatalysts for Effective Carbon Dioxide Electroreduction

Siddharth Sharma, Ann Mariella Babu and Anitha Varghese

ACS Appl. Energy Mater., 2026
DOI: 10.1021/acsaem.5c04133

Enhanced Electrochemical Reduction of CO2 to CO upon Immobilization onto Carbon Nanotubes Using an Iron‐Porphyrin Dimer

Maryam Abdinejad, Caitlin Dao, Billy Deng, Maegan E. Sweeney, Fabian Dielmann, Xiao‐an Zhang and Heinz Bernhard Kraatz

ChemistrySelect, 2020, 5, 979
DOI: 10.1002/slct.201904580

Nanostructured Cobalt‐Based Electrocatalysts for CO2Reduction: Recent Progress, Challenges, and Perspectives

Zhangsen Chen, Gaixia Zhang, Lei Du, Yi Zheng, Lixian Sun and Shuhui Sun

Small, 2020, 16
DOI: 10.1002/smll.202004158

Carbon Dioxide Reduction by Iron Hangman Porphyrins

Charles G. Margarit, Christoph Schnedermann, Naomi G. Asimow and Daniel G. Nocera

Organometallics, 2019, 38, 1219
DOI: 10.1021/acs.organomet.8b00334

Cobalt-N4 macrocyclic complexes for heterogeneous electrocatalysis of the CO2 reduction reaction

Zhichao Lin, Zhan Jiang, Yubo Yuan, Huan Li, Hongxuan Wang, Yirong Tang, Chunchen Liu and Yongye Liang

Chinese Journal of Catalysis, 2022, 43, 104
DOI: 10.1016/S1872-2067(21)63880-9

Unlocking the Potential for Methanol Synthesis via Electrochemical CO2 Reduction Using CoPc-Based Molecular Catalysts

Libo Yao, Jie Ding, Xinhai Cai, Lingyue Liu, Nirala Singh, Charles C. L. McCrory and Bin Liu

ACS Nano, 2024, 18, 21623
DOI: 10.1021/acsnano.4c07613

Linkage Effect in the Heterogenization of Cobalt Complexes by Doped Graphene for Electrocatalytic CO2 Reduction

Jiong Wang, Xiang Huang, Shibo Xi, Jong‐Min Lee, Cheng Wang, Yonghua Du and Xin Wang

Angewandte Chemie, 2019, 131, 13666
DOI: 10.1002/ange.201906475

Cobalt-Based Electrocatalysts for Sustainable Nitrate Conversion: Structural Design and Mechanistic Advancements

GuoLiang Chang, Xueqiu Chen, Jing-Jing Lv, Zhijie Kong and Zheng-Jun Wang

Nano-Micro Lett., 2026, 18
DOI: 10.1007/s40820-025-01877-z

Urchin-like Ni@N-doped carbon composites with Ni nanoparticles encapsulated in N-doped carbon nantubes as high-efficient electrocatalyst for oxygen evolution reaction

Hongjie Li, Yi He, Qiangbing Yang, Jizhuang Wang, Siming Yan, Chunlin Chen and Jingyu Chen

Journal of Solid State Chemistry, 2019, 278, 120843
DOI: 10.1016/j.jssc.2019.07.004

Enhancing the Electrochemical CO2 Reduction Activity of Polymer-Encapsulated Cobalt Phthalocyanine Films by Modulating the Loading of Catalysts, Polymers, and Carbon Supports

Taylor L. Soucy, Yingshuo Liu, Jonah B. Eisenberg and Charles C. L. McCrory

ACS Appl. Energy Mater., 2022, 5, 159
DOI: 10.1021/acsaem.1c02689

Recent Advances in Microenvironment Engineering for Selective Electrochemical C–N Coupling

Jianping Bai, Xinhai Cai, Xin Liu, Nirala Singh and Libo Yao

ChemSusChem, 2025, 18
DOI: 10.1002/cssc.202501366

Potential Dependence and Substituent Effect in CO2 Electroreduction on a Cobalt Phthalocyanine Catalyst

Yin-Long Li, Xue-Lian Jiang, Hao Cao, Hong-Yan Zhao, Jun Li and Yang-Gang Wang

ACS Catal., 2024, 14, 9575
DOI: 10.1021/acscatal.3c05089

The Origin of Li2S2 Reduction Mechanism Modulated by Single‐Atom Catalyst for all Solid‐State Li‐S Batteries

Miao He, Yuxing Fan, Shen Liu, Shuying Wang, Tongwei Wu, Dongjiang Chen, Anjun Hu, Chaoyi Yan, Yichao Yan, Jianping Long, Yin Hu, Tianyu Lei, Peng Li and Wei Chen

Advanced Energy Materials, 2025, 15
DOI: 10.1002/aenm.202405642

Recent advances in the rational design of single-atom catalysts for electrochemical CO2 reduction

Huoliang Gu, Jing Wu and Liming Zhang

Nano Res., 2022, 15, 9747
DOI: 10.1007/s12274-022-4270-1

Cobalt phthalocyanine-based conjugated polymer as efficient and exclusive electrocatalyst for CO2 reduction to ethanol

Dong Jiang, Ran Bu, Wei Xia, Yichen Hu, Mengchen Zhou, Enqing Gao, Toru Asahi, Yusuke Yamauchi and Jing Tang

Materials Reports: Energy, 2023, 3, 100176
DOI: 10.1016/j.matre.2023.100176

Contemporary Strategies for Immobilizing Metallophthalocyanines for Electrochemical Transformations of Carbon Dioxide

Scheryn E. Lawson, Daniel B. Leznoff and Jeffrey J. Warren

Molecules, 2023, 28, 5878
DOI: 10.3390/molecules28155878

Noncovalent Integration of a Bioinspired Ni Catalyst to Graphene Acid for Reversible Electrocatalytic Hydrogen Oxidation

Bertrand Reuillard, Matías Blanco, Laura Calvillo, Nathan Coutard, Ahmed Ghedjatti, Pascale Chenevier, Stefano Agnoli, Michal Otyepka, Gaetano Granozzi and Vincent Artero

ACS Appl. Mater. Interfaces, 2020, 12, 5805
DOI: 10.1021/acsami.9b18922

Non‐Covalent Integration of a [FeFe]‐Hydrogenase Mimic to Multiwalled Carbon Nanotubes for Electrocatalytic Hydrogen Evolution

Afridi Zamader, Bertrand Reuillard, Jacques Pécaut, Laurent Billon, Antoine Bousquet, Gustav Berggren and Vincent Artero

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202202260

Carbon Encapsulation of Organic–Inorganic Hybrid Perovskite toward Efficient and Stable Photo‐Electrochemical Carbon Dioxide Reduction

Hefeng Zhang, Yu Chen, Hong Wang, Hui Wang, Weiguang Ma, Xu Zong and Can Li

Advanced Energy Materials, 2020, 10
DOI: 10.1002/aenm.202002105

A Planar, Conjugated N4‐Macrocyclic Cobalt Complex for Heterogeneous Electrocatalytic CO2 Reduction with High Activity

Libo Sun, Zhenfeng Huang, Vikas Reddu, Tan Su, Adrian C. Fisher and Xin Wang

Angewandte Chemie, 2020, 132, 17252
DOI: 10.1002/ange.202007445

Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes

Kristian E. Dalle, Julien Warnan, Jane J. Leung, Bertrand Reuillard, Isabell S. Karmel and Erwin Reisner

Chem. Rev., 2019, 119, 2752
DOI: 10.1021/acs.chemrev.8b00392

Simultaneous Reduction of CO2 and Splitting of H2O by a Single Immobilized Cobalt Phthalocyanine Electrocatalyst

Natalia Morlanés, Kazuhiro Takanabe and Valentin Rodionov

ACS Catal., 2016, 6, 3092
DOI: 10.1021/acscatal.6b00543

Organic–Inorganic Hybrid Nanomaterials for Electrocatalytic CO2 Reduction

Chenhuai Yang, Shuyu Li, Zhicheng Zhang, Haiqing Wang, Huiling Liu, Fei Jiao, Zhenguo Guo, Xiaotao Zhang and Wenping Hu

Small, 2020, 16
DOI: 10.1002/smll.202001847

Advancing the Preparation Strategy of High-Performance Integrated Electrodes for eCO2RR via Sublimation

Hao Zeng, Xiangbin Zou, Liu Han, Muyao Gao, Zhaoyu Chen, Yang Liu, Ming Yang, Bing Li and Ming Liu

ACS Appl. Mater. Interfaces, 2025, 17, 14008
DOI: 10.1021/acsami.4c21322

Highly Selective and Active Electrochemical Reduction of CO2 to CO on a Polymeric Co(II) Phthalocyanine@Graphitic Carbon Nitride Nanosheet–Carbon Nanotube Composite

Ting-Ting Li, Yan Mei, Hongwei Li, Jinjie Qian, Miao Wu and Yue-Qing Zheng

Inorg. Chem., 2020, 59, 14184
DOI: 10.1021/acs.inorgchem.0c01977

G‐quadruplex Nanowires To Direct the Efficiency and Selectivity of Electrocatalytic CO2 Reduction

Lei He, Xiaofu Sun, Hua Zhang and Fangwei Shao

Angew Chem Int Ed, 2018, 57, 12453
DOI: 10.1002/anie.201806652

Cobalt porphyrin immobilized on the TiO2 nanotube electrode for CO2 electroreduction in aqueous solution

Shengshen Gu, Aleksei N. Marianov, Yuxiang Zhu and Yijiao Jiang

Journal of Energy Chemistry, 2021, 55, 219
DOI: 10.1016/j.jechem.2020.06.067

Ligand-regulated Schiff base complexes for efficient electrocatalytic carbon dioxide reduction

Siying Wang, Shuaiqi Wang, Qiangwei Li, Leqing Deng and Lidong Wang

Journal of Catalysis, 2025, 451, 116356
DOI: 10.1016/j.jcat.2025.116356

Enhancing the CO2-to-CO Conversion from 2D Silver Nanoprisms via Superstructure Assembly

Kun Qi, Yang Zhang, Ji Li, Christophe Charmette, Michel Ramonda, Xiaoqiang Cui, Ying Wang, Yupeng Zhang, Huali Wu, Wensen Wang, Xiaolin Zhang and Damien Voiry

ACS Nano, 2021, 15, 7682
DOI: 10.1021/acsnano.1c01281

Selective Reduction of Aqueous Nitrate to Ammonium with an Electropolymerized Chromium Molecular Catalyst

Maiko J. Askari, Jeremy D. Kallick and Charles C. L. McCrory

J. Am. Chem. Soc., 2024, 146, 7439
DOI: 10.1021/jacs.3c12783

Heterogenous Preparations of Solution-Processable Cobalt Phthalocyanines for Carbon Dioxide Reduction Electrocatalysis

Elahe Tajbakhsh, Declan McKearney, Daniel B. Leznoff and Jeffrey J. Warren

Inorganics, 2023, 11, 43
DOI: 10.3390/inorganics11010043

Enhancement Mechanism of CO2RR toward Methanol on a Ball-Milled CoPc-CNT Electrocatalyst: A Covalent Anchoring Strategy

Tianxiang Guo, Xilai Wang, Baijiang Liu and Zijun Men

Energy Fuels, 2025, 39, 9516
DOI: 10.1021/acs.energyfuels.5c00679

Recent Advances in Bonding Regulation of Metalloporphyrin‐Modified Carbon‐Based Catalysts for Accelerating Energy Electrocatalytic Applications

Yang Lu, Wenyan Li, Yiyi Fan, Lei Cheng, Yawen Tang and Hanjun Sun

Small, 2024, 20
DOI: 10.1002/smll.202406180

The effects of cobalt phthalocyanine and polyacrylic acid on the reactivity of hydrogen peroxide oxidation reaction and the performance of hydrogen peroxide fuel cell

Jungyeon Ji, Yongjin Chung and Yongchai Kwon

Journal of Power Sources, 2020, 480, 228860
DOI: 10.1016/j.jpowsour.2020.228860

Reordering d Orbital Energies of Single‐Site Catalysts for CO2 Electroreduction

Jianyu Han, Pengfei An, Shuhu Liu, Xiaofei Zhang, Dawei Wang, Yi Yuan, Jun Guo, Xueying Qiu, Ke Hou, Lin Shi, Yin Zhang, Shenlong Zhao, Chang Long and Zhiyong Tang

Angew Chem Int Ed, 2019, 58, 12711
DOI: 10.1002/anie.201907399

Recent Developments in Metalloporphyrin Electrocatalysts for Reduction of Small Molecules: Strategies for Managing Electron and Proton Transfer Reactions

Rui Zhang and Jeffrey J. Warren

ChemSusChem, 2021, 14, 293
DOI: 10.1002/cssc.202001914

Phthalocyanine-derived catalysts decorated by metallic nanoclusters for enhanced CO2 electroreduction

Jiacheng Chen, Jiayu Li, Jing Xu, Minghui Zhu and Yi-Fan Han

Green Energy & Environment, 2023, 8, 444
DOI: 10.1016/j.gee.2021.05.006

Potential- and Buffer-Dependent Selectivity for the Conversion of CO2 to CO by a Cobalt Porphyrin-Peptide Electrocatalyst in Water

Jose L. Alvarez-Hernandez, Alison A. Salamatian, Ji Won Han and Kara L. Bren

ACS Catal., 2022, 12, 14689
DOI: 10.1021/acscatal.2c03297

A one-dimensional copper(II) coordination polymer incorporating succinate and N,N-diethylethylenediamine ligands: crystallographic analysis, vibrational and surface features, and DFT analysis

Fatih Şen, Sevgi Kansiz and İbrahim Uçar

Acta Crystallogr C Struct Chem, 2017, 73, 517
DOI: 10.1107/S2053229617008452

Water‐Soluble Polymers with Appending Porphyrins as Bioinspired Catalysts for the Hydrogen Evolution Reaction

Lisi Xie, Jia Tian, Yingjie Ouyang, Xinai Guo, Weian Zhang, Ulf‐Peter Apfel, Wei Zhang and Rui Cao

Angew Chem Int Ed, 2020, 59, 15844
DOI: 10.1002/anie.202003836

Elucidating the Reactivity and Mechanism of CO2 Electroreduction at Highly Dispersed Cobalt Phthalocyanine

Minghui Zhu, Ruquan Ye, Kyoungsuk Jin, Nikifar Lazouski and Karthish Manthiram

ACS Energy Lett., 2018, 3, 1381
DOI: 10.1021/acsenergylett.8b00519

Optimizing the Electrocatalytic Selectivity of Carbon Dioxide Reduction Reaction by Regulating the Electronic Structure of Single‐Atom M‐N‐C Materials

Tianmi Tang, Zhenlu Wang and Jingqi Guan

Adv Funct Materials, 2022, 32
DOI: 10.1002/adfm.202111504

High current density microkinetic and electronic structure analysis of CO2 reduction using Co and Fe complexes on gas diffusion electrode

Xiaofei Lu, Busra Dereli, Tatsuya Shinagawa, Mohamed Eddaoudi, Luigi Cavallo and Kazuhiro Takanabe

Chem Catalysis, 2022, 2, 1143
DOI: 10.1016/j.checat.2022.03.010

Manganese acting as a high-performance heterogeneous electrocatalyst in carbon dioxide reduction

Bingxing Zhang, Jianling Zhang, Jinbiao Shi, Dongxing Tan, Lifei Liu, Fanyu Zhang, Cheng Lu, Zhuizhui Su, Xiuniang Tan, Xiuyan Cheng, Buxing Han, Lirong Zheng and Jing Zhang

Nat Commun, 2019, 10
DOI: 10.1038/s41467-019-10854-1

Photoelectrochemical CO2 Reduction by a Molecular Cobalt(II) Catalyst on Planar and Nanostructured Si Surfaces

Da He, Tong Jin, Wei Li, Sebastian Pantovich, Dunwei Wang and Gonghu Li

Chemistry A European J, 2016, 22, 13064
DOI: 10.1002/chem.201603068

Increasing the CO2 Reduction Activity of Cobalt Phthalocyanine by Modulating the σ-Donor Strength of Axially Coordinating Ligands

Kevin E. Rivera Cruz, Yingshuo Liu, Taylor L. Soucy, Paul M. Zimmerman and Charles C. L. McCrory

ACS Catal., 2021, 11, 13203
DOI: 10.1021/acscatal.1c02379

Structure–Activity Relationship of the Polymerized Cobalt Phthalocyanines for Electrocatalytic Carbon Dioxide Reduction

Jiacheng Chen, Minghui Zhu, Jiayu Li, Jing Xu and Yi-Fan Han

J. Phys. Chem. C, 2020, 124, 16501
DOI: 10.1021/acs.jpcc.0c04741

Dramatic Improvement of Homogeneous Carbon Dioxide and Bicarbonate Electroreduction Using a Tetracationic Water-Soluble Cobalt Phthalocyanine

Scheryn E. Lawson, Ryan J. Roberts, Daniel B. Leznoff and Jeffrey J. Warren

J. Am. Chem. Soc., 2024, 146, 22306
DOI: 10.1021/jacs.4c04878

Highly selective and active CO2 reduction electrocatalysts based on cobalt phthalocyanine/carbon nanotube hybrid structures

Xing Zhang, Zishan Wu, Xiao Zhang, Liewu Li, Yanyan Li, Haomin Xu, Xiaoxiao Li, Xiaolu Yu, Zisheng Zhang, Yongye Liang and Hailiang Wang

Nat Commun, 2017, 8
DOI: 10.1038/ncomms14675

Heterogeneous Aqueous CO2 Reduction Using a Pyrene-Modified Rhenium(I) Diimine Complex

Soumalya Sinha, Ana Sonea, William Shen, Samuel S. Hanson and Jeffrey J. Warren

Inorg. Chem., 2019, 58, 10454
DOI: 10.1021/acs.inorgchem.9b01060

Advancing Proton Exchange Membrane Electrolyzers with Molecular Catalysts

Biaobiao Zhang, Lizhou Fan, Ram B. Ambre, Tianqi Liu, Qijun Meng, Brian J.J. Timmer and Licheng Sun

Joule, 2020, 4, 1408
DOI: 10.1016/j.joule.2020.06.001

One‐Pot, Self‐Initiated Polymerization Approach to Functional Poly(4‐Vinylpyridine)s

Isao Yamaguchi and Keigo Hata

Macro Chemistry & Physics, 2025, 226
DOI: 10.1002/macp.202500205

Tuning Product Selectivity for Aqueous CO2 Reduction with a Mn(bipyridine)-pyrene Catalyst Immobilized on a Carbon Nanotube Electrode

Bertrand Reuillard, Khoa H. Ly, Timothy E. Rosser, Moritz F. Kuehnel, Ingo Zebger and Erwin Reisner

J. Am. Chem. Soc., 2017, 139, 14425
DOI: 10.1021/jacs.7b06269

Electron-withdrawing functional ligand promotes CO2 reduction catalysis in single atom catalyst

Xinyi Ren, Song Liu, Huicong Li, Jie Ding, Linghui Liu, Zhichong Kuang, Ling Li, Hongbin Yang, Fuquan Bai, Yanqiang Huang, Tao Zhang and Bin Liu

Sci. China Chem., 2020, 63, 1727
DOI: 10.1007/s11426-020-9847-9

Electrons, Photons, Protons and Earth-Abundant Metal Complexes for Molecular Catalysis of CO2 Reduction

Hiroyuki Takeda, Claudio Cometto, Osamu Ishitani and Marc Robert

ACS Catal., 2017, 7, 70
DOI: 10.1021/acscatal.6b02181

Electrocatalytic CO2 Reduction: from Discrete Molecular Catalysts to Their Integrated Catalytic Materials

Kai Lei and Bao Yu Xia

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202200141

Force Decomposition Analysis: A Method to Decompose Intermolecular Forces into Physically Relevant Component Contributions

Abdulrahman Aldossary, Martí Gimferrer, Yuezhi Mao, Hongxia Hao, Akshaya K. Das, Pedro Salvador, Teresa Head-Gordon and Martin Head-Gordon

J. Phys. Chem. A, 2023, 127, 1760
DOI: 10.1021/acs.jpca.2c08061

Water‐Soluble Polymers with Appending Porphyrins as Bioinspired Catalysts for the Hydrogen Evolution Reaction

Lisi Xie, Jia Tian, Yingjie Ouyang, Xinai Guo, Weian Zhang, Ulf‐Peter Apfel, Wei Zhang and Rui Cao

Angewandte Chemie, 2020, 132, 15978
DOI: 10.1002/ange.202003836

The Active Center of Co–N–C Electrocatalysts for the Selective Reduction of CO2 to CO Using a Nafion-H Electrolyte in the Gas Phase

Hitoshi Ogihara, Tomomi Maezuru, Yuji Ogishima, Yuta Inami, Mayuko Saito, Shoji Iguchi and Ichiro Yamanaka

ACS Omega, 2020, 5, 19453
DOI: 10.1021/acsomega.0c01510

Heterogenization of a macrocyclic cobalt complex for photocatalytic CO2 reduction

Tong Jin, Chao Liu and Gonghu Li

Journal of Coordination Chemistry, 2016, 69, 1748
DOI: 10.1080/00958972.2016.1190452

Transition metal macrocycles for heterogeneous electrochemical CO2 reduction

Fang Lv, Na Han, Yuan Qiu, Xijun Liu, Jun Luo and Yanguang Li

Coordination Chemistry Reviews, 2020, 422, 213435
DOI: 10.1016/j.ccr.2020.213435

Heterogenized Pyridine-Substituted Cobalt(II) Phthalocyanine Yields Reduction of CO2 by Tuning the Electron Affinity of the Co Center

Alberto De Riccardis, Michelle Lee, Roman V. Kazantsev, Alejandro J. Garza, Guosong Zeng, David M. Larson, Ezra L. Clark, Peter Lobaccaro, Paul W. W. Burroughs, Ermelinda Bloise, Joel W. Ager, Alexis T. Bell, Martin Head-Gordon, Giuseppe Mele and Francesca M. Toma

ACS Appl. Mater. Interfaces, 2020, 12, 5251
DOI: 10.1021/acsami.9b18924

Stable Dioxin‐Linked Metallophthalocyanine Covalent Organic Frameworks (COFs) as Photo‐Coupled Electrocatalysts for CO2Reduction

Meng Lu, Mi Zhang, Chun‐Guang Liu, Jiang Liu, Lin‐Jie Shang, Min Wang, Jia‐Nan Chang, Shun‐Li Li and Ya‐Qian Lan

Angewandte Chemie, 2021, 133, 4914
DOI: 10.1002/ange.202011722

Selective CO2 Reduction Catalyzed by Single Cobalt Sites on Carbon Nitride under Visible-Light Irradiation

Peipei Huang, Jiahao Huang, Sebastian A. Pantovich, Alexander D. Carl, Thomas G. Fenton, Christine A. Caputo, Ronald L. Grimm, Anatoly I. Frenkel and Gonghu Li

J. Am. Chem. Soc., 2018, 140, 16042
DOI: 10.1021/jacs.8b10380

A perspective on the electrocatalytic conversion of carbon dioxide to methanol with metallomacrocyclic catalysts

Xinyan Liu, Bo-Quan Li, Bing Ni, Lei Wang and Hong-Jie Peng

Journal of Energy Chemistry, 2022, 64, 263
DOI: 10.1016/j.jechem.2021.04.059

Molecular approach to catalysis of electrochemical reaction in porous films

Cyrille Costentin and Jean-Michel Savéant

Current Opinion in Electrochemistry, 2019, 15, 58
DOI: 10.1016/j.coelec.2019.03.014

Tailoring of Active Sites from Single to Dual Atom Sites for Highly Efficient Electrocatalysis

Hongwei Zhang, Xindie Jin, Jong-Min Lee and Xin Wang

ACS Nano, 2022, 16, 17572
DOI: 10.1021/acsnano.2c06827

Synthetic Organic Design for Solar Fuel Systems

Julien Warnan and Erwin Reisner

Angewandte Chemie, 2020, 132, 17496
DOI: 10.1002/ange.202006013

Covalently Grafting Cobalt Porphyrin onto Carbon Nanotubes for Efficient CO2 Electroreduction

Minghui Zhu, Jiacheng Chen, Libei Huang, Ruquan Ye, Jing Xu and Yi‐Fan Han

Angewandte Chemie, 2019, 131, 6667
DOI: 10.1002/ange.201900499

Chemistry at the Interface: Polymer-Functionalized GaP Semiconductors for Solar Hydrogen Production

Anna M. Beiler, Diana Khusnutdinova, Samuel I. Jacob and Gary F. Moore

Ind. Eng. Chem. Res., 2016, 55, 5306
DOI: 10.1021/acs.iecr.6b00478

Computational Screening of Transition Metal–Phthalocyanines for the Electrochemical Reduction of Carbon Dioxide

Gurpreet Kour, Xin Mao and Aijun Du

J. Phys. Chem. C, 2020, 124, 7708
DOI: 10.1021/acs.jpcc.9b10815

Highly selective and efficient electroreduction of CO2 in water by quaterpyridine derivative‐based molecular catalyst noncovalently tethered to carbon nanotubes

Vikas Reddu, Libo Sun, Xiaogang Li, Huile Jin, Shun Wang and Xin Wang

SmartMat, 2022, 3, 151
DOI: 10.1002/smm2.1081

An industrial perspective on catalysts for low-temperature CO2 electrolysis

Richard I. Masel, Zengcai Liu, Hongzhou Yang, Jerry J. Kaczur, Daniel Carrillo, Shaoxuan Ren, Danielle Salvatore and Curtis P. Berlinguette

Nat. Nanotechnol., 2021, 16, 118
DOI: 10.1038/s41565-020-00823-x

Electroreduction of CO2 Catalyzed by Nickel Imidazolin-2-ylidenamino-Porphyrins in Both Heterogeneous and Homogeneous Molecular Systems

Maryam Abdinejad, Lukas F. B. Wilm, Fabian Dielmann and Heinz Bernhard Kraatz

ACS Sustainable Chem. Eng., 2021, 9, 521
DOI: 10.1021/acssuschemeng.0c07964

Photocatalytic CO2 Reduction by Trigonal-Bipyramidal Cobalt(II) Polypyridyl Complexes: The Nature of Cobalt(I) and Cobalt(0) Complexes upon Their Reactions with CO2, CO, or Proton

Tomoe Shimoda, Takeshi Morishima, Koichi Kodama, Takuji Hirose, Dmitry E. Polyansky, Gerald F. Manbeck, James T. Muckerman and Etsuko Fujita

Inorg. Chem., 2018, 57, 5486
DOI: 10.1021/acs.inorgchem.8b00433

G‐quadruplex Nanowires To Direct the Efficiency and Selectivity of Electrocatalytic CO2 Reduction

Lei He, Xiaofu Sun, Hua Zhang and Fangwei Shao

Angewandte Chemie, 2018, 130, 12633
DOI: 10.1002/ange.201806652

Cobalt phthalocyanine coordinated to pyridine-functionalized carbon nanotubes with enhanced CO2 electroreduction

Minghui Zhu, Jiacheng Chen, Rong Guo, Jing Xu, Xiangchen Fang and Yi-Fan Han

Applied Catalysis B: Environmental, 2019, 251, 112
DOI: 10.1016/j.apcatb.2019.03.047

Mechanistic Elucidations of Highly Dispersed Metalloporphyrin Metal‐Organic Framework Catalysts for CO2Electroreduction

Michael R. Smith, Clare B. Martin, Sonia Arumuganainar, Ari Gilman, Bruce E. Koel and Michele L. Sarazen

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202218208

Polymer-encapsulated metal complex catalysts: An emerging and efficient platform for electrochemical CO2 reduction

Yingshuo Liu, Shuaishuai Lyu, Fuli Wen, Weixuan Nie and Shuqing Wang

Journal of Materials Science & Technology, 2024, 172, 33
DOI: 10.1016/j.jmst.2023.08.002

Molecular catalysis of electrochemical reactions

Cyrille Costentin, Marc Robert and Jean-Michel Savéant

Current Opinion in Electrochemistry, 2017, 2, 26
DOI: 10.1016/j.coelec.2017.02.006

Rational Design of Polymers for Selective CO2 Reduction Catalysis

Jane J. Leung, Julian A. Vigil, Julien Warnan, Esther Edwardes Moore and Erwin Reisner

Angewandte Chemie, 2019, 131, 7779
DOI: 10.1002/ange.201902218

Various polymer-encapsulated diiron compounds as bioinspired [2Fe2S] metallopolymers for modulating electrocatalytic hydrogen evolution

Zhen Guo, Yu-Long Sun, Ting-Rui Xue, Xing-Bin Jing and Pei-Hua Zhao

Electrochimica Acta, 2026, 568, 148824
DOI: 10.1016/j.electacta.2026.148824

Nitrogen-rich carbon nitride inducing electron delocalization of Co-N4 site to enhance electrocatalytic carbon dioxide reduction

Jofrey Jackson Masana, Jiayong Xiao, Hui Zhang, Xiaoying Lu, Ming Qiu and Ying Yu

Applied Catalysis B: Environmental, 2023, 323, 122199
DOI: 10.1016/j.apcatb.2022.122199

Device Fabrication for Water Oxidation, Hydrogen Generation, and CO2 Reduction via Molecular Engineering

Fusheng Li, Hao Yang, Wenlong Li and Licheng Sun

Joule, 2018, 2, 36
DOI: 10.1016/j.joule.2017.10.012

Modulating the coordination environment and metal choice in carbon buckypapers supported metal phthalocyanines for enhanced electrocatalytic carbon dioxide reduction

Beatriz Martínez-Sánchez, Amrita Singh-Morgan, Diego Cazorla-Amorós and Emilia Morallón

Journal of Catalysis, 2024, 437, 115669
DOI: 10.1016/j.jcat.2024.115669

Electrochemical Reduction of CO2 over Heterogeneous Catalysts in Aqueous Solution: Recent Progress and Perspectives

Chang Long, Xiang Li, Jun Guo, Yanan Shi, Shaoqin Liu and Zhiyong Tang

Small Methods, 2019, 3
DOI: 10.1002/smtd.201800369

Influence of Polymer and Support Interactions on the Electrocatalytic Properties of Heterogenized Molecular Complexes

Elizabeth K. Johnson and Charles W. Machan

ChemCatChem, 2026, 18
DOI: 10.1002/cctc.202501488

Functions of bioinspired pyrrole cobalt complexes–recently developed catalytic systems of vitamin B12 related complexes and porphycene complexes–

Taro Koide, Toshikazu Ono, Hisashi Shimakoshi and Yoshio Hisaeda

Coordination Chemistry Reviews, 2022, 470, 214690
DOI: 10.1016/j.ccr.2022.214690

Reduction of CO2 to CO by an Iron Porphyrin Catalyst in the Presence of Oxygen

Biswajit Mondal, Pritha Sen, Atanu Rana, Dibyajyoti Saha, Purusottom Das and Abhishek Dey

ACS Catal., 2019, 9, 3895
DOI: 10.1021/acscatal.9b00529

Three-Dimensional Phthalocyanine Metal-Catecholates for High Electrochemical Carbon Dioxide Reduction

Roc Matheu, Enrique Gutierrez-Puebla, M. Ángeles Monge, Christian S. Diercks, Joohoon Kang, Mathieu S. Prévot, Xiaokun Pei, Nikita Hanikel, Bing Zhang, Peidong Yang and Omar M. Yaghi

J. Am. Chem. Soc., 2019, 141, 17081
DOI: 10.1021/jacs.9b09298

Surface Immobilization of Molecular Electrocatalysts for Energy Conversion

R. Morris Bullock, Atanu K. Das and Aaron M. Appel

Chemistry A European J, 2017, 23, 7626
DOI: 10.1002/chem.201605066

Cobalt Phthalocyanine Cross‐Linked Polypyrrole for Efficient Electroreduction of Low Concentration CO2 To CO

Jin‐Mei Chen, Wen‐Jun Xie, Zhi‐Wen Yang and Liang‐Nian He

ChemSusChem, 2022, 15
DOI: 10.1002/cssc.202201455

CO2 Electroreduction over Metallic Oxide, Carbon-Based, and Molecular Catalysts: A Mini-Review of the Current Advances

Hassan Ait Ahsaine, Mohamed Zbair, Amal BaQais and Madjid Arab

Catalysts, 2022, 12, 450
DOI: 10.3390/catal12050450

A Planar, Conjugated N4‐Macrocyclic Cobalt Complex for Heterogeneous Electrocatalytic CO2 Reduction with High Activity

Libo Sun, Zhenfeng Huang, Vikas Reddu, Tan Su, Adrian C. Fisher and Xin Wang

Angew Chem Int Ed, 2020, 59, 17104
DOI: 10.1002/anie.202007445

Resolve deep-rooted challenges of halide perovskite for sustainable energy development and environmental remediation

Siow Hwa Teo, Chi Huey Ng, Yun Hau Ng, Aminul Islam, Shuzi Hayase and Yun Hin Taufiq-Yap

Nano Energy, 2022, 99, 107401
DOI: 10.1016/j.nanoen.2022.107401