Air stable and efficient rare earth Eu(ii) hydro-tris(pyrazolyl)borate complexes with tunable emission colors

Hao Qi, Zifeng Zhao, Ge Zhan, Boxun Sun, Wenchao Yan, Chengbo Wang, Liding Wang, Zhiwei Liu, Zuqiang Bian and Chunhui Huang

Inorg. Chem. Front., 2020, 7, 4593
DOI: 10.1039/D0QI00762E

Europium(ii) complexes with substituted triethylenetetramine: new emitters to construct efficient deep blue organic light emitting diodes by spin coating

Hao Qi, Tianming Zhong, Peihao Huo, Jiayin Zheng, Zifeng Zhao, Wenchao Yan, Zuqiang Bian and Zhiwei Liu

J. Mater. Chem. C, 2023, 11, 4136
DOI: 10.1039/D2TC05500G

Luminescence thermochromism in novel mixed Eu(ii)–Cu(i) iodide

Vasily A. Ilichev, Liubov I. Silantyeva, Anton F. Rogozhin, Artem N. Yablonskiy, Boris A. Andreev, Roman V. Rumyantsev, Georgy K. Fukin and Mikhail N. Bochkarev

Dalton Trans., 2021, 50, 14244
DOI: 10.1039/D1DT02384E

Reduction chemistry yields stable and soluble divalent lanthanide tris(pyrazolyl)borate complexes

Tajrian Chowdhury, Matthew J. Evans, Martyn P. Coles, Anna G. Bailey, William J. Peveler, Claire Wilson and Joy H. Farnaby

Chem. Commun., 2023, 59, 2134
DOI: 10.1039/D2CC03189B

Stabilization of molecular lanthanide polysulfides by bulky scorpionate ligands

Marcel Kühling, Robert McDonald, Phil Liebing, Liane Hilfert, Michael J. Ferguson, Josef Takats and Frank T. Edelmann

Dalton Trans., 2016, 45, 10118
DOI: 10.1039/C6DT01439A

Fine tuning the steric hindrance of the Eu(ii) tris(pyrazolyl)borate complex for a blue organic light-emitting diode

Wenchao Yan, Yuqin Li, Peihao Huo, Ruoyao Guo, Gang Yu, Zifeng Zhao, Kezhi Wang, Zuqiang Bian and Zhiwei Liu

J. Mater. Chem. C, 2024, 12, 9834
DOI: 10.1039/D4TC01456A

Optical and nonlinear optical properties of Ln(Tp)2, where Ln = La,…,Lu and Tp = tris(pyrazolyl)borate: a DFT+TD-DFT study

Douniazed Hannachi, Mohamed Fahim Haroun, Ahlem Khireddine and Henry Chermette

New J. Chem., 2019, 43, 14377
DOI: 10.1039/C9NJ03232K

Switching on single-molecule magnet properties of homoleptic sandwich tris(pyrazolyl)borate dysprosium(iii) cations via intermolecular dipolar coupling

Dimitris I. Alexandropoulos, Kuduva R. Vignesh, Haomiao Xie and Kim R. Dunbar

Dalton Trans., 2019, 48, 10610
DOI: 10.1039/C9DT00597H

Activation and functionalisation of carbon dioxide by bis-tris(pyrazolyl)borate-supported divalent samarium and trivalent lanthanide silylamide complexes

Tajrian Chowdhury, Claire Wilson and Joy H. Farnaby

Dalton Trans., 2024, 53, 11884
DOI: 10.1039/D4DT01382D

Systematic tuning of the emission colors and redox potential of Eu(ii)-containing cryptates by changing the N/O ratio of cryptands

Wenchao Yan, Tingzhou Li, Zelun Cai, Hao Qi, Ruoyao Guo, Peihao Huo, Zhiwei Liu and Zuqiang Bian

Inorg. Chem. Front., 2022, 9, 4794
DOI: 10.1039/D2QI01216B

Lanthanide Luminescence in Visible-Light-Promoted Photochemical Reactions

Ramiro Barraza and Matthew Allen

Molecules, 2020, 25, 3892
DOI: 10.3390/molecules25173892

Uncoordination mode of к0-Janus scorpionate with La(III) and Ce(III) complexes: Synthesis, characterization, thermolysis and crystal structure determination

Donkupar Kharbani, Snehadrinarayan Khatua, Charlestine Soh and E.K. Rymmai

Journal of Molecular Structure, 2019, 1176, 128
DOI: 10.1016/j.molstruc.2018.08.041

Evaluation of f-element borate chemistry

Mark A. Silver and Thomas E. Albrecht-Schmitt

Coordination Chemistry Reviews, 2016, 323, 36
DOI: 10.1016/j.ccr.2016.02.015

Crystal structures of two ytterbium(III) complexes comprising alkynylamidinate ligands

Sida Wang, Farid M. Sroor, Phil Liebing, Volker Lorenz, Liane Hilfert and Frank T. Edelmann

Acta Crystallogr E Cryst Commun, 2016, 72, 1229
DOI: 10.1107/S2056989016012135

Synthesis and Structure of Alkaline Earth Bis{hydrido-tris(3,5-diisopropyl-pyrazol-1-yl)borate} Complexes: Ae(TpiPr2)2 (Ae = Mg, Ca, Sr, Ba)

Phil Liebing, Nicole Harmgarth, Yi Yang, Robert McDonald, Felix Engelhardt, Marcel Kühling, Frank T. Edelmann and Josef Takats

Inorg. Chem., 2021, 60, 1877
DOI: 10.1021/acs.inorgchem.0c03294

Side-on coordination mode of a pyrazolyl group in the structure of a divalent [Sm{B(3-Mepz)4}2] complex (3-Mepz is 3-methylpyrazol-1-yl)

Yasuhiro Arikawa, Kei-ichiro Inada and Masayoshi Onishi

Acta Crystallogr C Struct Chem, 2016, 72, 838
DOI: 10.1107/S2053229616011578

Luminescence differences between two complexes of divalent europium

Brooke A. Corbin, Jessica L. Hovey, Bishnu Thapa, H. Bernhard Schlegel and Matthew J. Allen

Journal of Organometallic Chemistry, 2018, 857, 88
DOI: 10.1016/j.jorganchem.2017.09.007

Coordination Flexibility in Homoleptic Divalent Lanthanoid (Sm, Eu, Yb) Formamidinates upon Desolvation

Olga Mironova, Taisiya S. Sukhikh, Sergey N. Konchenko and Nikolay A. Pushkarevsky

Inorg. Chem., 2026, 65, 9799
DOI: 10.1021/acs.inorgchem.5c05670

Divalent Tetra- and Penta-phenylcyclopentadienyl Europium and Samarium Sandwich and Half-Sandwich Complexes: Synthesis, Characterization, and Remarkable Luminescence Properties

Rory P. Kelly, Toby D. M. Bell, Rosalind P. Cox, Daisy P. Daniels, Glen B. Deacon, Florian Jaroschik, Peter C. Junk, Xavier F. Le Goff, Gilles Lemercier, Agathe Martinez, Jun Wang and Daniel Werner

Organometallics, 2015, 34, 5624
DOI: 10.1021/acs.organomet.5b00842

Half‐Sandwich Complexes [Cp′4Ln4I8]4 (Ln=Ce, Pr):Emergence of Donor‐Free Organolanthanide Nanowheels

Dennis A. Buschmann, David Schneider, Cäcilia Maichle‐Mössmer and Reiner Anwander

Eur J Inorg Chem, 2022, 2022
DOI: 10.1002/ejic.202100862

Formation and structural characterization of a europium(II) mono(scorpionate) complex and a sterically crowded pyrazabole

Phil Liebing, Marcel Kühling, Josef Takats, Liane Hilfert and Frank T. Edelmann

Acta Crystallogr E Cryst Commun, 2017, 73, 1921
DOI: 10.1107/S2056989017016498

Pressure-Induced Reduction of Dicyanamide by Samarium(II) in a Coordination Polymer

Hannah B. Wineinger, Tyler W. Hines, Kacy N. Mendoza, Thayalan Rajeshkumar, Nicholas B. Beck, Laurent Maron, Joseph M. Sperling and Thomas E. Albrecht

Inorg. Chem., 2026, 65, 7974
DOI: 10.1021/acs.inorgchem.6c00425

Unique EuII Coordination Environments with a Janus Cryptand

Guo-Xia Jin, Matthew D. Bailey and Matthew J. Allen

Inorg. Chem., 2016, 55, 9085
DOI: 10.1021/acs.inorgchem.6b01659

Photoluminescence properties of the “bent sandwich-like” compounds [Eu(Tp iPr2 ) 2 ] and [Yb(Tp iPr2 ) 2 ] – Intermediates between nitride-based phosphors and metallocenes

Markus Suta, Marcel Kühling, Phil Liebing, Frank T. Edelmann and Claudia Wickleder

Journal of Luminescence, 2017, 187, 62
DOI: 10.1016/j.jlumin.2017.02.054

Solution‐Phase Tuning of Emission of Divalent Europium

Sara A. Worku, Swaraj Sangram Sahoo, Matthew J. Allen and Sandeepan Maity

ChemistrySelect, 2023, 8
DOI: 10.1002/slct.202301424

Physicochemical Properties of Near-Linear Lanthanide(II) Bis(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb)

Conrad A. P. Goodwin, Nicholas F. Chilton, Gianni F. Vettese, Eufemio Moreno Pineda, Iain F. Crowe, Joseph W. Ziller, Richard E. P. Winpenny, William J. Evans and David P. Mills

Inorg. Chem., 2016, 55, 10057
DOI: 10.1021/acs.inorgchem.6b00808

Recent Advances in d‐f Transition Lanthanide Complexes for Organic Light‐Emitting Diodes: Insights Into Structure–Luminescence Relationships

Jie Li, Yanbo Zhao, Donghong Yu and Chuanlang Zhan

Laser & Photonics Reviews, 2025, 19
DOI: 10.1002/lpor.202402198

Bright Photoluminescence of [{(Cp)2Ce(μ‐Cl)}2]: A Valuable Technique for the Determination of the Oxidation State of Cerium

Markus Suta, Nicole Harmgarth, Marcel Kühling, Phil Liebing, Frank T. Edelmann and Claudia Wickleder

Chemistry An Asian Journal, 2018, 13, 1038
DOI: 10.1002/asia.201701818

Systematic Tuning of the Optical Properties of Discrete Complexes of EuII in Solution Using Counterions and Solvents

Lina A. Basal, Aravind B. Kajjam, Matthew D. Bailey and Matthew J. Allen

Inorg. Chem., 2020, 59, 9476
DOI: 10.1021/acs.inorgchem.0c01516

Toward Opto-Structural Correlation to Investigate Luminescence Thermometry in an Organometallic Eu(II) Complex

Roberto M. Diaz-Rodriguez, Diogo A. Gálico, Daniel Chartrand, Elizaveta A. Suturina and Muralee Murugesu

J. Am. Chem. Soc., 2022, 144, 912
DOI: 10.1021/jacs.1c11076

Ligand Effects on the Emission Characteristics of Molecular Eu(II) Luminescence Thermometers

Roberto M. Diaz-Rodriguez, Diogo A. Gálico, Daniel Chartrand and Muralee Murugesu

J. Am. Chem. Soc., 2024, 146, 34118
DOI: 10.1021/jacs.4c13805

Tetracyanidoborates of Divalent Eu and Yb 3D Metal–Organic Frameworks with Cubic Structure. Thermochromic Luminescence and Slow Relaxation of Magnetization of Eu[B(CN)4]2

Vasily A. Ilichev, Anton F. Rogozhin, Tatyana V. Balashova, Svetlana K. Polyakova, Nikolay N. Efimov, Pavel N. Vasilev, Elena A. Ugolkova, Eduard Bernhardt, Roman V. Rumyantcev, Georgy K. Fukin and Mikhail N. Bochkarev

Chem. Mater., 2025, 37, 3685
DOI: 10.1021/acs.chemmater.4c03507

Phospholyl and Arsolyl Triple-Decker Sandwich Complexes of Europium(II) and Strontium(II)

Noah Schwarz, Julia Feye, Vanitha R. Naina, Ralf Köppe, Sebastian Gillhuber, Xiaofei Sun and Peter W. Roesky

JACS Au, 2024, 4, 2343
DOI: 10.1021/jacsau.4c00300

The Tripodal Ligand’s 4f Complexes: Use in Molecular Magnetism

Kira E. Vostrikova

Inorganics, 2023, 11, 307
DOI: 10.3390/inorganics11070307

Rare Earth Complexes of Europium(II) and Substituted Bis(pyrazolyl)borates with High Photoluminescence Efficiency

Ruoyao Guo, Zifeng Zhao, Aoben Wu, Yuqin Li, Kezhi Wang, Zuqiang Bian and Zhiwei Liu

Molecules, 2022, 27, 8053
DOI: 10.3390/molecules27228053

Unexpected Findings in a Simple Metathesis Reaction of Europium and Ytterbium Diiodides with Perfluorinated Mercaptobenzothiazolates of Alkali Metals

Liubov I. Silantyeva, Vasily A. Ilichev, Andrey S. Shavyrin, Artem N. Yablonskiy, Roman V. Rumyantcev, Georgy K. Fukin and Mikhail N. Bochkarev

Organometallics, 2020, 39, 2972
DOI: 10.1021/acs.organomet.0c00334