Multistep thermal dehydration behavior of inorganic hydrates is regulated by the thermodynamic phase relationship between hydrates and the physico-geometrical kinetic constraints of the component reactions.
Different reaction pathways of thermal dehydration controlled by the bivariant of temperature and p(H2O) exhibit different kinetic features characterized by different temperature and p(H2O) dependences.
Reaction pathway and kinetics of the multistep thermal dehydration behavior of inorganic hydrates are regulated by atmospheric and self-generated water vapor in a geometrically constrained reaction scheme.
The universal kinetic descriptions over different atmospheric water vapors provide further insights into the kinetics of the thermal dehydration of sodium carbonate monohydrate grains as a compacted composite.
The reaction pathway and kinetics of the thermal dehydration of D-glucose monohydrate are dramatically altered by the melting of the reactant midway through the reaction.