A reliable, colloidal synthesis method of the orthorhombic chalcogenide perovskite, BaZrS3, and related ABS3 nanomaterials (A = Sr, Ba; B = Ti, Zr, Hf): a step forward for earth-abundant, functional materials

Daniel C. Hayes, Shubhanshu Agarwal, Kiruba Catherine Vincent, Izoduwa M. Aimiuwu, Apurva A. Pradhan, Madeleine C. Uible, Suzanne C. Bart and Rakesh Agrawal

Chem. Sci., 2025, 16, 1308
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Solution-phase synthesis of group 3–5 transition metal chalcogenide inorganic nanomaterials

Daniel Zilevu and Sidney E. Creutz

Chem. Commun., 2023, 59, 8779
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Solution-phase synthesis of alloyed Ba(Zr1−xTix)S3 perovskite and non-perovskite nanomaterials

Daniel Zilevu, Kennedi M. Miller, Naira Arrykova, Autumn B. Locke and Sidney E. Creutz

Nanoscale, 2024, 16, 17126
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Emergence of Ruddlesden–Popper phases and other pitfalls for moderate temperature solution deposited chalcogenide perovskites

Apurva A. Pradhan, Shubhanshu Agarwal, Kiruba Catherine Vincent, Daniel C. Hayes, Jonas M. Peterson, Jonathan W. Turnley, Robert M. Spilker, Madeleine C. Uible, Suzanne C. Bart, Libai Huang, Kim Kisslinger and Rakesh Agrawal

Mater. Chem. Front., 2024, 8, 3358
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Moderate temperature sulfurization and selenization of highly stable metal oxides: an opportunity for chalcogenide perovskites

Shubhanshu Agarwal, Jonathan W. Turnley, Apurva A. Pradhan and Rakesh Agrawal

J. Mater. Chem. C, 2023, 11, 15817
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Solution processed metal chalcogenide semiconductors for inorganic thin film photovoltaics

Jonathan W. Turnley and Rakesh Agrawal

Chem. Commun., 2024, 60, 5245
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Numerical investigation of a high-efficiency BaZrxTi1−xS3 chalcogenide perovskite solar cell

Debashish Pal, Abdulkarem H. M. Almawgani, Soumee Das, Amrindra Pal, Md. Ferdous Rahman, Adam R. H. Alhawari and Sagar Bhattarai

New J. Chem., 2024, 48, 2474
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From synthesis to application: a review of BaZrS3 chalcogenide perovskites

Shubhanshu Agarwal, Kiruba Catherine Vincent and Rakesh Agrawal

Nanoscale, 2025, 17, 4250
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Colloidal nanocrystal synthesis of alkaline earth metal sulfides for solution-processed solar cell contact layers

Vincent Mauritz, Katharina E. Dehm, Simon P. Hager and Ryan W. Crisp

Zeitschrift für Kristallographie - Crystalline Materials, 2023, 238, 295
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A Processing Route to Chalcogenide Perovskites Alloys with Tunable Band Gap via Anion Exchange

Kevin Ye, Ida Sadeghi, Michael Xu, Jack Van Sambeek, Tao Cai, Jessica Dong, Rishabh Kothari, James M. LeBeau and R. Jaramillo

Adv Funct Materials, 2024, 34
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Charge Transport and Defects in Sulfur-Deficient Chalcogenide Perovskite BaZrS 3

Garima Aggarwal, Adeem Saeed Mirza, Stefania Riva, Corrado Comparotto, Robert J. W. Frost, Soham Mukherjee, Monica Morales-Masis, Håkan Rensmo and Jonathan Staaf Scragg

PRX Energy, 2025, 4
DOI: 10.1103/t7ns-99dk

Wide‐Bandgap Perovskite‐Inspired Materials: Defect‐Driven Challenges for High‐Performance Optoelectronics

G. Krishnamurthy Grandhi, David Hardy, Mokurala Krishnaiah, Brenda Vargas, Basheer Al‐Anesi, Mahesh P. Suryawanshi, Diego Solis‐Ibarra, Feng Gao, Robert L. Z. Hoye and Paola Vivo

Adv Funct Materials, 2024, 34
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A Low-Temperature Growth Mechanism for Chalcogenide Perovskites

Ruiquan Yang, Jessica Nelson, Calvin Fai, Hasan Arif Yetkin, Chase Werner, Merielle Tervil, Alexander D. Jess, Phillip J. Dale and Charles J. Hages

Chem. Mater., 2023, 35, 4743
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Exploring the potential of powder-to-film processing for proof-of-concept BaZrS3 perovskite solar cells

P. Dallas, K. Gkini, A. Kaltzoglou, L. Givalou, M. Konstantakou, S. Orfanoudakis, N. Boukos, E. Sakellis, P. Tsipas, A. Kalafatis, A.G. Karydas, A. Lagogiannis, P. Falaras, V. Psycharis and T. Stergiopoulos

Materials Today Communications, 2024, 39, 108608
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Synthesis of BaZrS3 and BaHfS3 Chalcogenide Perovskite Films Using Single‐Phase Molecular Precursors at Moderate Temperatures

Apurva A. Pradhan, Madeleine C. Uible, Shubhanshu Agarwal, Jonathan W. Turnley, Shriya Khandelwal, Jonas M. Peterson, Daria D. Blach, Ryan N. Swope, Libai Huang, Suzanne C. Bart and Rakesh Agrawal

Angewandte Chemie, 2023, 135
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Engineering BaHfS3 with Zr alloying to improve solar cell performance: Insights from SCAPS-1D simulations

Dhineshkumar Srinivasan, Aruna-Devi Rasu Chettiar and Latha Marasamy

Materials Science and Engineering: B, 2025, 315, 118126
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Emerging class of SrZrS3 chalcogenide perovskite solar cells: Conductive MOFs as HTLs - A game changer?

Evangeline Linda, Aruna-Devi Rasu Chettiar and Latha Marasamy

Solar Energy Materials and Solar Cells, 2024, 278, 113204
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Quantitative Scales for Haliphilicity of Metals: Tailoring the Halide Affinity of Alkaline Earth Metals to Synthesize Chalcogenide Perovskite BaMS3 (M = Zr, and Hf) and Cu2BaSnS4 Compounds

Shubhanshu Agarwal, Kiruba Catherine Vincent and Rakesh Agrawal

ACS Appl. Energy Mater., 2024, 7, 10584
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Emerging BaZrS3 and Ba(Zr,Ti)S3 Chalcogenide Perovskite Solar Cells: A Numerical Approach Toward Device Engineering and Unlocking Efficiency

Eupsy Navis Vincent Mercy, Dhineshkumar Srinivasan and Latha Marasamy

ACS Omega, 2024, 9, 4359
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Scrutinizing the untapped potential of emerging ABSe3 (A = Ca, Ba; B = Zr, Hf) chalcogenide perovskites solar cells

Dhineshkumar Srinivasan, Aruna-Devi Rasu Chettiar, Eupsy Navis Vincent Mercy and Latha Marasamy

Sci Rep, 2025, 15
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Synthesis of BaZrS3 and BaHfS3 Chalcogenide Perovskite Films Using Single‐Phase Molecular Precursors at Moderate Temperatures

Apurva A. Pradhan, Madeleine C. Uible, Shubhanshu Agarwal, Jonathan W. Turnley, Shriya Khandelwal, Jonas M. Peterson, Daria D. Blach, Ryan N. Swope, Libai Huang, Suzanne C. Bart and Rakesh Agrawal

Angew Chem Int Ed, 2023, 62
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A simple synthetic approach to BaZrS3, BaHfS3, and their solid solutions

Lorenza Romagnoli, Andrea Ciccioli, Phillip J. Dale, Hasan Arif Yetkin, Riccardo Panetta and Alessandro Latini

J Am Ceram Soc., 2024, 107, 698
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Chalcogenide perovskites: enticing prospects across a wide range of compositions and optoelectronic properties for stable photodetector devices

Shilpa Mariam Samuel, Sadasivan Shaji, David Avellaneda Avellaneda and Bindu Krishnan

Nano Ex., 2025, 6, 015002
DOI: 10.1088/2632-959X/ad9b40

Boosting the efficiency of BaZrS3 solar cells with inorganic delafossite HTLs: A promising alternative to Spiro-OMeTAD

Dhineshkumar Srinivasan, Aruna-Devi Rasu Chettiar, Saravanan Rajendran, Hichem Bencherif, P. Sasikumar, Jeyakumar Ramanujam and Latha Marasamy

Inorganic Chemistry Communications, 2025, 180, 114997
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Chalcogenide Perovskite, An Emerging Photovoltaic Material: Current Status and Future Perspectives

Rakshita Raj, Riya Singh and Mridula Guin

ChemistrySelect, 2023, 8
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Recent progress in chalcogenide perovskites: toward low-temperature solution processing

Jaewook Lee and Wooseok Yang

Ceramist, 2023, 26, 17
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Photoconductive Effects in Single Crystals of BaZrS3

Boyang Zhao, Huandong Chen, Ragib Ahsan, Fei Hou, Eric R. Hoglund, Shantanu Singh, Maruda Shanmugasundaram, Huan Zhao, Andrey V. Krayev, Han Htoon, Patrick E. Hopkins, Jan Seidel, Rehan Kapadia and Jayakanth Ravichandran

ACS Photonics, 2024, 11, 1109
DOI: 10.1021/acsphotonics.3c01563

Liquid Flux–Assisted Mechanism for Modest Temperature Synthesis of Large‐Grain BaZrS3 and BaHfS3 Chalcogenide Perovskites

Kiruba Catherine Vincent, Shubhanshu Agarwal, Jonathan W. Turnley and Rakesh Agrawal

Adv Energy and Sustain Res, 2023, 4
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Advances in chalcogenide perovskites: Fundamentals and applications

Yanbing Han, Xiaosheng Fang and Zhifeng Shi

Applied Physics Reviews, 2024, 11
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Atomic structure of self-buffered BaZr(S, Se)3 epitaxial thin film interfaces

Michael Xu, Kevin Ye, Ida Sadeghi, R. Jaramillo and James M. LeBeau

Journal of Vacuum Science & Technology A, 2024, 42
DOI: 10.1116/6.0004010

Breaking Barriers in Chalcogenide Perovskite Synthesis: A Generalized Framework for Fabrication of BaMS3 (M═Ti, Zr, Hf) Materials

Shubhanshu Agarwal, Kiruba Catherine Vincent, Jonathan W. Turnley, Daniel C. Hayes, Madeleine C. Uible, Inés Durán, Alison Sofia Mesa Canizales, Shriya Khandelwal, Isabel Panicker, Zion Andoh, Robert M. Spilker, Qiushi Ma, Libai Huang, Sooyeon Hwang, Kim Kisslinger, Simon Svatek, Elisa Antolin, Suzanne C. Bart and Rakesh Agrawal

Adv Funct Materials, 2024, 34
DOI: 10.1002/adfm.202405416

Challenges and Advances in Low‐Temperature Synthesis of Lead‐Free BaZrS3 Chalcogenide Perovskite for Optoelectronics

Abhishek Swarnkar and Ujjal K. Gautam

Advanced Sustainable Systems, 2025
DOI: 10.1002/adsu.202500234