Radical-mediated C–N bond activation in 3,5-diamino-4-nitro-1H-pyrazole towards high-energy and insensitive energetic materials

Zhiwei Zeng, Yuji Liu, Wei Huang, Jean'ne M. Shreeve and Yongxing Tang

J. Mater. Chem. A, 2022, 10, 8268
DOI: 10.1039/D2TA01146H

A multi-fused heat-resistant energetic compound constructed by hydrogen bonds

Yong Hu, Wen-Shuai Dong, Zu-Jia Lu, Han Zhang and Jian-Guo Zhang

Chem. Commun., 2023, 59, 9864
DOI: 10.1039/D3CC02504G

Site-selective electrochemical synthesis of nitrogen-enriched bis-pyrazole derivatives: a sustainable approach for N–N versus NN bond formation

Lei Liu, Wengzhe Huang, Ye Yuan, Lu Lu, Yongxing Tang and Wei Huang

Green Chem., 2025, 27, 3727
DOI: 10.1039/D4GC06597B

Isolation and reactivity of heteroleptic magnesium 1,3-benzazaphospholide complexes

Chengfu Pi and Jie Zhou

Dalton Trans., 2026, 55, 2673
DOI: 10.1039/D5DT03010B

Facile synthesis of bicyclic heat-resistant energetic materials via a C–N coupling strategy

Xiu’e Jiang, Mingren Fan, Ruihui Wang, Yi Wang and Qinghua Zhang

Chem. Commun., 2025, 61, 9924
DOI: 10.1039/D5CC02076J

Advancing energy safety via stepwise nucleophilic substitution on tetrazine

Jatinder Singh, Richard J. Staples and Jean'ne M. Shreeve

J. Mater. Chem. A, 2024, 12, 30548
DOI: 10.1039/D4TA06039C

NHC-catalyzed enantioselective radical reactions of enal and pyridinium salt: mechanism and origin of regio- and stereoselectivities

Kuohong Chen, Jiaming Zhang, Qianqian Shi, Lili Han, Dongmin Fu, Donghui Wei and Yanyan Zhu

Catal. Sci. Technol., 2023, 13, 5259
DOI: 10.1039/D3CY00791J

Connecting Energetic Nitropyrazole and Nitrobenzene Moieties with C−C Bonds using Suzuki Cross‐Coupling Reaction: A Novel Route to Thermally Stable Energetic Materials

Krishna Pandey, Prachi Bhatia, Pritam Dolui, Vikas D. Ghule and Dheeraj Kumar

Asian J Org Chem, 2022, 11
DOI: 10.1002/ajoc.202200543

Density functional theory study on the structure and energy properties of high-energy–density materials based on trinitrophenyl azacyclic compounds

Xinyue Zhang, Jiaming Guo and Xinhua Peng

J Mol Model, 2026, 32
DOI: 10.1007/s00894-026-06651-5

Synthetic chemistry of energetic materials: Evolution, current trends, and AI-driven future

Zhi-wei Zeng, Yong-xing Tang, Hong-wei Yang and Guang-bin Cheng

Energetic Materials Frontiers, 2025, 6, 267
DOI: 10.1016/j.enmf.2025.09.001

Trinitromethyl Energetic Groups Enhance High Heats of Detonation

Peng Chen, Hui Dou, Jinya Zhang, Chunlin He and Siping Pang

ACS Appl. Mater. Interfaces, 2023, 15, 4144
DOI: 10.1021/acsami.2c21047

Selective enrichment and determination of polychlorinated biphenyls in milk by solid-phase microextraction using molecularly imprinted phenolic resin fiber coating

Shuo Wang, Pengfei Li, Yehong Han, Haiyan Liu and Hongyuan Yan

Analytica Chimica Acta, 2022, 1227, 340328
DOI: 10.1016/j.aca.2022.340328

Transferring the available fused cyclic scaffolds for high—throughput combinatorial design of highly energetic materials via database mining

Linyuan Wen, Tao Yu, Weipeng Lai, Maochang Liu, Bozhou Wang, Jinwen Shi and Yingzhe Liu

Fuel, 2022, 324, 124591
DOI: 10.1016/j.fuel.2022.124591

Tailoring Azo-Bridged Nitropyrazoles: Enhancing Energy Thresholds through Complete Functionalization

Wen-Shuai Dong, Meiqi Xu, Qamar-un-Nisa Tariq, Zu-jia Lu, Qiyao Yu and Jian-Guo Zhang

J. Org. Chem., 2025, 90, 4537
DOI: 10.1021/acs.joc.4c02896

Intramolecular Hydrogen Bonds Assisted Construction of Planar Tricyclic Structures for Insensitive and Highly Thermostable Energetic Materials

Yubing Liu, Jie Li, Jinxiong Cai, Xun Zhang, Lu Hu, Siping Pang and Chunlin He

IJMS, 2024, 25, 3910
DOI: 10.3390/ijms25073910

NN bridged pyrazoles from nitrogen‐centered radicals: A comparative study of spin densities, molecular structures, and reactivities

Zhiwei Zeng, Wei Huang, Yuji Liu and Yongxing Tang

Journal of Heterocyclic Chem, 2024, 61, 93
DOI: 10.1002/jhet.4745

Synthesis of Energetic Material 4-Nitro-3,5-bis(trinitromethyl)-1H-pyrazole via [4 + 1] Cycloaddition

Wentong Tu, Tao Yu, Linyuan Wen, Qiurong Li, Hongyao Xu and Yingzhe Liu

Org. Lett., 2026, 28, 1656
DOI: 10.1021/acs.orglett.5c05140

Energetic Materials Photolysis Footprint in High-Order Harmonic Generation

Xinyue Xie, Weiwei Yu, Yao Xiao, Siyang Wang and Zhe Song

J. Phys. Chem. A, 2025, 129, 518
DOI: 10.1021/acs.jpca.4c07302

Synthesis and characterization of energetic molecules based on pyrimidine rings: Selection and verification of computational-assisted synthesis pathways

Yuteng Cao, Siwei Song, Junhao Shi, Ziwu Cai, Wen Qian, Tianlin Liu, Qinghua Zhang, Yu Liu and Wenquan Zhang

Chemical Engineering Science, 2023, 282, 119281
DOI: 10.1016/j.ces.2023.119281

Strategies for molecular construction and performance regulation of heat-resistant energetic materials: An overview

Jing Zhang, Bojun Tan, Qian Zhang, Shaoli Chen, Yongxing Tang and Ning Liu

Progress in Natural Science: Materials International, 2024, 34, 1132
DOI: 10.1016/j.pnsc.2024.09.008

Integration of 1,2,3-Triazine N-Oxide and 2,4,6-Trinitroaniline Moieties for the Design of Heat-Resistant Energetic Compounds

Wen-Hao Cui, Hao-Ran Xu, Zhiwen Ye and Ying He

Org. Lett., 2025, 27, 2635
DOI: 10.1021/acs.orglett.5c00305

Construction of Symmetric Energetic Compounds with Lower Sensitivity via Integration of Flexible Chains

Meiqi Xu, Wen-Shuai Dong, Zu-jia Lu, Qamar-un-Nisa Tariq, Zhimin Li, Qiyao Yu and Jian-Guo Zhang

Crystal Growth & Design, 2025, 25, 1355
DOI: 10.1021/acs.cgd.4c01217