Development and application of ordered membrane electrode assemblies for water electrolysis

Nian Hua, Chuanyan Zhang, Wenjie Zhang, Xinyun Yao and Huidong Qian

Chem. Commun., 2025, 61, 232
DOI: 10.1039/D4CC05300A

Engineering 3D-printed carbon structures with atomic layer deposition coatings as photoelectrocatalysts for water splitting

Siowwoon Ng, Michela Sanna, Edurne Redondo and Martin Pumera

J. Mater. Chem. A, 2024, 12, 396
DOI: 10.1039/D3TA04460B

Advanced manufacturing for electrosynthesis of fuels and chemicals from CO2

Daniel Corral, Jeremy T. Feaster, Sadaf Sobhani, Joshua R. DeOtte, Dong Un Lee, Andrew A. Wong, Julie Hamilton, Victor A. Beck, Amitava Sarkar, Christopher Hahn, Thomas F. Jaramillo, Sarah E. Baker and Eric B. Duoss

Energy Environ. Sci., 2021, 14, 3064
DOI: 10.1039/D0EE03679J

3D-printing for electrolytic processes and electrochemical flow systems

Adriano Ambrosi, Raymond Rong Sheng Shi and Richard D. Webster

J. Mater. Chem. A, 2020, 8, 21902
DOI: 10.1039/D0TA07939A

Performance of 3d Electrodes Fabricated From Tib2/graphene/carbon Nanofiber Composites in Hydrogen Evolution Reaction

Sevgi Ates and Evrim Baran Aydin

SSRN Journal, 2023
DOI: 10.2139/ssrn.4662149

Efficient and Highly Stable 3D-Printed NiFe and NiCo Bifunctional Electrodes for Practical HER and OER

Jeoffrey Tourneur, Loïc Joanny, Loïc Perrin, Stéphane Paul and Bruno Fabre

ACS Appl. Eng. Mater., 2023, 1, 2676
DOI: 10.1021/acsaenm.3c00417

Fabrication and characterization of Nickel-coated 3D printed electrodes for enhanced oxygen evolution reaction in acidic media at various temperatures

Bulut Hüner, Nesrin Demir and Mehmet Fatih Kaya

Fuel, 2024, 366, 131172
DOI: 10.1016/j.fuel.2024.131172

Fabrication of 3D‐printed graphene/polylactic acid and carbon nanofiber/polylactic acid electrodes: New solvent‐free electrochemical activation method for hydrogen evolution reactions

Sevgi Ateş and Evrim Baran Aydın

J of Applied Polymer Sci, 2023, 140
DOI: 10.1002/app.54348

Long-term performance of PEM water electrolysis cells with 3D printed electrodes and low catalyst loading

B. Sánchez Batalla, A. Laube, A. Hofer, S. Zallmann, C. Körner, T. Struckmann, J. Bachmann and C. Weidlich

International Journal of Hydrogen Energy, 2024, 59, 480
DOI: 10.1016/j.ijhydene.2024.01.364

3D-Printed Hierarchically Micro–Nano-structured NiFe Catalysts for the Stable and Efficient Oxygen Evolution Reaction

Bo Zhou, Yang Tang, Zhiwei Jiao, Pingyu Wan, Qing Hu and Xiao Jin Yang

ACS Appl. Nano Mater., 2023, 6, 4602
DOI: 10.1021/acsanm.3c00070

Electrochemical Reduction of Carbon Dioxide on 3D Printed Electrodes

Eva Vaněčková, Milan Bouša, Violetta Shestivska, Jiří Kubišta, Pavel Moreno‐García, Peter Broekmann, Motiar Rahaman, Martin Zlámal, Jan Heyda, Milan Bernauer, Táňa Sebechlebská and Viliam Kolivoška

ChemElectroChem, 2021, 8, 2137
DOI: 10.1002/celc.202100261

Exceptional Performance of 3D Additive Manufactured NiFe Phosphite Oxyhydroxide Hollow Tubular Lattice Plastic Electrode for Large‐Current‐Density Water Oxidization

Liping Ding, Lin Zhang, Gaoyuan Li, Shuyan Chen, Han Yan, Haibiao Tu, Jianmin Su, Qi Li, Yanfeng Tang and Yanqing Wang

Energy & Environ Materials, 2024, 7
DOI: 10.1002/eem2.12740

Water Splitting: From Electrode to Green Energy System

Xiao Li, Lili Zhao, Jiayuan Yu, Xiaoyan Liu, Xiaoli Zhang, Hong Liu and Weijia Zhou

Nano-Micro Lett., 2020, 12
DOI: 10.1007/s40820-020-00469-3

A Scientist’s Guide to Buying a 3D Printer: How to Choose the Right Printer for Your Laboratory

Joshua J. Tully and Gabriel N. Meloni

Anal. Chem., 2020, 92, 14853
DOI: 10.1021/acs.analchem.0c03299

Additive manufacturing: New paradigm for developing water splitting systems

S. Mojabi, N. Afsahi and N. Naseri

International Journal of Hydrogen Energy, 2024, 49, 116
DOI: 10.1016/j.ijhydene.2023.07.023

Toward a Diverse Next-Generation Energy Workforce: Teaching Artificial Photosynthesis and Electrochemistry in Elementary Schools through Active Learning

Brooke Soobrian, Alex J. King, Justin C. Bui, Adam Z. Weber, Alexis T. Bell and Frances A. Houle

J. Chem. Educ., 2023, 100, 2686
DOI: 10.1021/acs.jchemed.3c00085

3D printed electrochemical devices for bio-chemical sensing: A review

Abhinav Sharma, Hendrik Faber, Ajit Khosla and Thomas D. Anthopoulos

Materials Science and Engineering: R: Reports, 2023, 156, 100754
DOI: 10.1016/j.mser.2023.100754

Advances in Designing 3D‐Printed Systems for CO2 Reduction

Akshay Kumar K. Padinjareveetil and Martin Pumera

Adv Materials Inter, 2023, 10
DOI: 10.1002/admi.202201734

3D printer fabrication of boron doped Cu-MWCNT/PLA electrodes: Investigation of its efficiency in electrocatalytic hydrogen production

Evrim Baran Aydin and Sevgi Ateş

Diamond and Related Materials, 2024, 150, 111720
DOI: 10.1016/j.diamond.2024.111720

Recent Development of Electrodes Construction for HER in Electrocatalytic Water Splitting

Asif Mahmood, Mingxuan Du, Kaige Tian and Junqing Yan

ChemSusChem, 2024, 17
DOI: 10.1002/cssc.202400847

Hydrogen generation in additively manufactured membraneless microfluidic electrolysis cell: Performance evaluation and accelerated stress testing

Biswajit Samir De, Aditya Singh, Ram Ji Dixit, Neeraj Khare, Anastasia Elias and Suddhasatwa Basu

Chemical Engineering Journal, 2023, 452, 139433
DOI: 10.1016/j.cej.2022.139433

3D Printing of Next‐generation Electrochemical Energy Storage Devices: from Multiscale to Multimaterial

Xi Xu, Yong Hao Tan, Jun Ding and Cao Guan

Energy & Environ Materials, 2022, 5, 427
DOI: 10.1002/eem2.12175

Technologies and prospects for decoupled and membraneless water electrolysis

Guilin Ruan, Fiona Todman, Gilad Yogev, Rotem Arad, Tom Smolinka, Jens Oluf Jensen, Mark D. Symes and Avner Rothschild

Nat. Rev. Clean Technol., 2025, 1, 380
DOI: 10.1038/s44359-025-00061-1

A brief introduction of electrode fabrication for proton exchange membrane water electrolyzers

Xinlong Lin, Justin Zhu Yeow Seow and Zhichuan J Xu

J. Phys. Energy, 2023, 5, 034003
DOI: 10.1088/2515-7655/acccb1

Highly Durable Additively Manufactured Membrane-Free Electrolyzer

Matthew J. Whittingham, Eric M. Brack, James Waggett, Robert D. Crapnell, Craig E. Banks and Samuel J. Rowley-Neale

ACS Omega, 2025, 10, 23089
DOI: 10.1021/acsomega.5c01163

3D‐Printing to Mitigate COVID‐19 Pandemic

Kandambath Padinjareveetil Akshay Kumar and Martin Pumera

Adv Funct Materials, 2021, 31
DOI: 10.1002/adfm.202100450

3D-printed NiFe-layered double hydroxide pyramid electrodes for enhanced electrocatalytic oxygen evolution reaction

Jinhyuck Ahn, Yoo Sei Park, Sanghyeon Lee, Juchan Yang, Jaeyeon Pyo, Jooyoung Lee, Geul Han Kim, Sung Mook Choi and Seung Kwon Seol

Sci Rep, 2022, 12
DOI: 10.1038/s41598-021-04347-9

Production and New Green Activation of Conductive 3D-Printed Cu/PLA Electrode: Its Performance in Hydrogen Evolution Reactions in Alkaline Media

Halil Ekici, Sevgi Ateş and Evrim Baran Aydın

International Journal of Chemistry and Technology, 2024, 8, 32
DOI: 10.32571/ijct.1375421

Resin 3D printing enables accessible electrochemical cell design

Nicholas B. Watkins, Cyrus J.B.M. Fiori, Florian M. Grass, Jonas C. Peters, John M. Gregoire, Alexis T. Bell, Julia R. Greer, Max A. Saccone and Justin C. Bui

Chem Catalysis, 2024, 4, 101120
DOI: 10.1016/j.checat.2024.101120

Modeling 3D hybrid battery-electrolyzer nickel electrodes

Robin Möller-Gulland, J. Ruud van Ommen and Fokko M. Mulder

Cell Reports Physical Science, 2025, 6, 102545
DOI: 10.1016/j.xcrp.2025.102545

Proton Exchange Membrane Electrolysis Revisited: Advancements, Challenges, and Two-Phase Transport Insights in Materials and Modelling

Ali Bayat, Prodip K. Das, Goutam Saha and Suvash C. Saha

Eng, 2025, 6, 72
DOI: 10.3390/eng6040072

Tubular PEM electrolysis cells with a 3D-printed oxygen electrode and ALD catalyst coating

A. Laube, B. Sánchez Batalla, C. Weidlich, A. Hofer, J. Bachmann, S. Zallmann, C. Körner, S. Fischer, A. Chica and T. Struckmann

International Journal of Hydrogen Energy, 2024, 49, 437
DOI: 10.1016/j.ijhydene.2023.08.084

Flexible and wearable electrochemical sensors for health and safety monitoring

Dan Tao, Chun Xie, Nicole Jaffrezic-Renault and Zhenzhong Guo

Talanta, 2025, 291, 127863
DOI: 10.1016/j.talanta.2025.127863

A review on additive manufacturing and materials for catalytic applications: Milestones, key concepts, advances and perspectives

O.H. Laguna, P.F. Lietor, F.J. Iglesias Godino and F.A. Corpas-Iglesias

Materials & Design, 2021, 208, 109927
DOI: 10.1016/j.matdes.2021.109927

Microfluidics for Electrochemical Energy Conversion

Omar A. Ibrahim, Marina Navarro-Segarra, Pardis Sadeghi, Neus Sabaté, Juan Pablo Esquivel and Erik Kjeang

Chem. Rev., 2022, 122, 7236
DOI: 10.1021/acs.chemrev.1c00499

Practically applicable water oxidation electrodes from 3D-printed Ti6Al4V scaffolds with surface nanostructuration and iridium catalyst coating

André Hofer, Sebastian Wachter, Dirk Döhler, Armin Laube, Beatriz Sánchez Batalla, Zongwen Fu, Claudia Weidlich, Thorsten Struckmann, Carolin Körner and Julien Bachmann

Electrochimica Acta, 2022, 417, 140308
DOI: 10.1016/j.electacta.2022.140308

Periodic Porous 3D Electrodes Mitigate Gas Bubble Traffic during Alkaline Water Electrolysis at High Current Densities

Tianyi Kou, Shanwen Wang, Rongpei Shi, Tao Zhang, Samuel Chiovoloni, Jennifer Q. Lu, Wen Chen, Marcus A. Worsley, Brandon C. Wood, Sarah E. Baker, Eric B. Duoss, Rui Wu, Cheng Zhu and Yat Li

Advanced Energy Materials, 2020, 10
DOI: 10.1002/aenm.202002955

3D printed optimized electrodes for electrochemical flow reactors

Jonathan T. Davis, Buddhinie S. Jayathilake, Swetha Chandrasekaran, Jonathan J. Wong, Joshua R. Deotte, Sarah E. Baker, Victor A. Beck, Eric B. Duoss, Marcus A. Worsley and Tiras Y. Lin

Sci Rep, 2024, 14
DOI: 10.1038/s41598-024-71765-w

A minireview on 3D printing for electrochemical water splitting electrodes and cells

Yanran Xun, Kaixi Zhang, Win Jonhson and Jun Ding

APL Materials, 2023, 11
DOI: 10.1063/5.0138178

3D nickel electrodes for hybrid battery and electrolysis devices

Robin Möller-Gulland and Fokko M. Mulder

Cell Reports Physical Science, 2024, 5, 102286
DOI: 10.1016/j.xcrp.2024.102286

Review—The Design, Performance and Continuing Development of Electrochemical Reactors for Clean Electrosynthesis

Samuel C. Perry, Carlos Ponce de León and Frank C. Walsh

J. Electrochem. Soc., 2020, 167, 155525
DOI: 10.1149/1945-7111/abc58e

Hierarchical monolithic carbon with high transfer performance for hydrogen evolution reaction

Yazhang Lin, Weijie Zhu and Yunhua Li

Journal of Energy Chemistry, 2022, 73, 41
DOI: 10.1016/j.jechem.2022.05.019

Flow control for bubble management in a membrane-free electrolyser

Bo Yang, Mehdi Jafarian, Navid Freidoonimehr and Maziar Arjomandi

International Journal of Multiphase Flow, 2024, 174, 104770
DOI: 10.1016/j.ijmultiphaseflow.2024.104770

Review of next generation hydrogen production from offshore wind using water electrolysis

Daniel Niblett, Mostafa Delpisheh, Shanmugam Ramakrishnan and Mohamed Mamlouk

Journal of Power Sources, 2024, 592, 233904
DOI: 10.1016/j.jpowsour.2023.233904

Additive manufacturing 3D customizable low-cost superwetting polyacrylate-based hierarchically micro-nanoporous lattice anode for energy-saving large-current-density water splitting application

Lin Zhang, Gaoyuan Li, Han Yan, Shuyan Chen, Haibiao Tu, Jianmin Su, Mingle Qiu, Shuaishuai Zhao, Tongming Sun, Qi Li, Liping Ding and Yanqing Wang

Composites Part B: Engineering, 2022, 245, 110189
DOI: 10.1016/j.compositesb.2022.110189

Reversible alteration of 3D printed polymer properties via infiltration of alumina by atomic layer deposition

Atilla C. Varga and Seán T. Barry

Journal of Vacuum Science & Technology A, 2023, 41
DOI: 10.1116/6.0002397

Gas Crossover Regulation by Porosity‐Controlled Glass Sheet Achieves Pure Hydrogen Production by Buffered Water Electrolysis at Neutral pH

Takahiro Naito, Tatsuya Shinagawa, Takeshi Nishimoto and Kazuhiro Takanabe

ChemSusChem, 2022, 15
DOI: 10.1002/cssc.202102294

Recent developments in membraneless electrolysis

Alessandro Manzotti, Matthew J. Robson and Francesco Ciucci

Current Opinion in Green and Sustainable Chemistry, 2023, 40, 100765
DOI: 10.1016/j.cogsc.2023.100765

Bubble size distribution and electrode coverage at porous nickel electrodes in a novel 3-electrode flow-through cell

Hannes Rox, Aleksandr Bashkatov, Xuegeng Yang, Stefan Loos, Gerd Mutschke, Gunter Gerbeth and Kerstin Eckert

International Journal of Hydrogen Energy, 2023, 48, 2892
DOI: 10.1016/j.ijhydene.2022.10.165

Recent decoupling and coupling strategies for water splitting

Chenglin Zhong, Ming Song, Qingwen Zhou and Xuemei Li

Nano Futures, 2021, 5, 042001
DOI: 10.1088/2399-1984/ac1db9

Optimization of Three-Dimensional-Printed Catalytic Electrodes for Alkaline Water Electrolysis Guided by the Experimental Design Methodology

Jeoffrey Tourneur, Loïc Perrin, Stéphane Paul and Bruno Fabre

Energy Fuels, 2024, 38, 6346
DOI: 10.1021/acs.energyfuels.4c00478

Toward single-step production of functional electrochemical devices using 3D printing: Progress, challenges, and opportunities

Glen D. O'Neil

Current Opinion in Electrochemistry, 2020, 20, 60
DOI: 10.1016/j.coelec.2020.02.023

Topology Optimization of 3D Flow Fields for Flow Batteries

Tiras Y. Lin, Sarah E. Baker, Eric B. Duoss and Victor A. Beck

J. Electrochem. Soc., 2022, 169, 050540
DOI: 10.1149/1945-7111/ac716d

WhY shape matters: Hydrodynamics of a Y-shaped membraneless electrolyzer

Karl Schoppmann, Hannes Rox, Erik Frense, Frank Rüdiger, Xuegeng Yang, Kerstin Eckert and Jochen Fröhlich

Chemical Engineering Journal, 2025, 507, 160040
DOI: 10.1016/j.cej.2025.160040

A Review of Inorganic Photoelectrode Developments and Reactor Scale‐Up Challenges for Solar Hydrogen Production

Benjamin Moss, Oytun Babacan, Andreas Kafizas and Anna Hankin

Advanced Energy Materials, 2021, 11
DOI: 10.1002/aenm.202003286

3D printing of metal-based materials for renewable energy applications

Shahryar Mooraj, Zhen Qi, Cheng Zhu, Jie Ren, Siyuan Peng, Liang Liu, Shengbiao Zhang, Shuai Feng, Fanyue Kong, Yanfang Liu, Eric B. Duoss, Sarah Baker and Wen Chen

Nano Res., 2021, 14, 2105
DOI: 10.1007/s12274-020-3230-x

An Overview of Various Additive Manufacturing Technologies and Materials for Electrochemical Energy Conversion Applications

Bulut Hüner, Murat Kıstı, Süleyman Uysal, İlayda Nur Uzgören, Emre Özdoğan, Yakup Ogün Süzen, Nesrin Demir and Mehmet Fatih Kaya

ACS Omega, 2022, 7, 40638
DOI: 10.1021/acsomega.2c05096

Recent review and evaluation of green hydrogen production via water electrolysis for a sustainable and clean energy society

N.S. Hassan, A.A. Jalil, S. Rajendran, N.F. Khusnun, M.B. Bahari, A. Johari, M.J. Kamaruddin and M. Ismail

International Journal of Hydrogen Energy, 2024, 52, 420
DOI: 10.1016/j.ijhydene.2023.09.068

Significance of 3D printing for a sustainable environment

M. Garg, R. Rani, V.K. Meena and S. Singh

Materials Today Sustainability, 2023, 23, 100419
DOI: 10.1016/j.mtsust.2023.100419

Effect of heat and bubble mass transfer on the efficiency of alkaline electrolysis hydrogen production

Nian Xu, Bingbing Qiu, Zucun Rui, Tianxiang Ji, Zilong Liu and Huaqiang Chu

Nano Res., 2024, 17, 9345
DOI: 10.1007/s12274-024-6922-9

3D Printing of Graphene Aerogel Microspheres to Architect High‐Performance Electrodes for Hydrogen Evolution Reaction

Yu Cheng, Zhanhua Wang, Marino Lavorgna, Lirong He and Hesheng Xia

Small, 2025, 21
DOI: 10.1002/smll.202408869

Continuum Modeling of Porous Electrodes for Electrochemical Synthesis

Justin C. Bui, Eric W. Lees, Lalit M. Pant, Iryna V. Zenyuk, Alexis T. Bell and Adam Z. Weber

Chem. Rev., 2022, 122, 11022
DOI: 10.1021/acs.chemrev.1c00901

Research progress on membraneless water electrolysis for hydrogen production

Juan Wu, Yang Wang, Junyi Yang, Xuefei Wang and Erqiang Wang

Sci. Sin.-Chim, 2025, 55, 433
DOI: 10.1360/SSC-2024-0247

Thermal oxidation–electroreduction modified 3D NiCu for efficient alkaline hydrogen evolution reaction

Bo Zhou, Hanjun Hu, Zhiwei Jiao, Yang Tang, Pingyu Wan, Qipeng Yuan, Qing Hu and Xiao Jin Yang

International Journal of Hydrogen Energy, 2021, 46, 22292
DOI: 10.1016/j.ijhydene.2021.04.090

Electric conductivity measurements employing 3D printed electrodes and cells

F. Vivaldi, T. Sebechlebská, E. Vaněčková, D. Biagini, A. Bonini and V. Kolivoška

Analytica Chimica Acta, 2022, 1203, 339600
DOI: 10.1016/j.aca.2022.339600

Advancements in hydrogen energy research with the assistance of computational chemistry

Alexander V. Vorontsov and Panagiotis G. Smirniotis

International Journal of Hydrogen Energy, 2023, 48, 14978
DOI: 10.1016/j.ijhydene.2022.12.356

Spatially engineered local electric field for enhanced water electrolysis

Yingjie Ji, Xia Liu, Dewei Wang, Shiyu Wang, Shuyun Yao, Zishan Hou, Jiangzhou Xie, Zhiyu Yang and Yi-Ming Yan

Journal of Power Sources, 2024, 615, 235083
DOI: 10.1016/j.jpowsour.2024.235083

Microfabrication of the Ammonia Plasma-Activated Nickel Nitride–Nickel Thin Film for Overall Water Splitting in the Microfluidic Membraneless Electrolyzer

Biswajit S. De, Pawan Kumar, Neeraj Khare, Jing-Li Luo, Anastasia Elias and Suddhasatwa Basu

ACS Appl. Energy Mater., 2021, 4, 9639
DOI: 10.1021/acsaem.1c01772