Base-stabilized formally zero-valent mono and diatomic molecular main-group compounds

Ravi Yadav, Soumen Sinhababu, Ritu Yadav and Subrata Kundu

Dalton Trans., 2022, 51, 2170
DOI: 10.1039/D1DT03569J

Hydrophosphination of boron–boron multiple bonds

Tom E. Stennett, Arumugam Jayaraman, Tobias Brückner, Lea Schneider and Holger Braunschweig

Chem. Sci., 2020, 11, 1335
DOI: 10.1039/C9SC05908C

Hydrosilylation of BB triple bonds: catalyst- and reductant-free construction of B–Si bonds and B2Si heterocycles

Tobias Brückner, Dario Duwe, Felipe Fantuzzi, Merlin Heß, Rian D. Dewhurst, Krzysztof Radacki and Holger Braunschweig

Chem. Commun., 2024, 60, 3259
DOI: 10.1039/D4CC00141A

A Discrete Trialane with a Near-Linear Al3 Axis

Debabrata Dhara, Lukas Endres, Aritra Roy, Rian D. Dewhurst, Rüdiger Bertermann, Felipe Fantuzzi and Holger Braunschweig

J. Am. Chem. Soc., 2024, 146, 33536
DOI: 10.1021/jacs.4c10967

Herstellung von Boranaloga von Enaminen über Hydroaminierung einer Bor‐Bor‐Dreifachbindung

Tobias Brückner, Merlin Heß, Tom E. Stennett, Anna Rempel and Holger Braunschweig

Angewandte Chemie, 2021, 133, 747
DOI: 10.1002/ange.202012101

Counterintuitive Chemistry: Carbene Stabilization of Zero-Oxidation State Main Group Species

Yuzhong Wang and Gregory H. Robinson

J. Am. Chem. Soc., 2023, 145, 5592
DOI: 10.1021/jacs.2c13574

Synthesis of a Linear Tetraboron Cation via Deprotonation of a Nonsupported Dimeric Hydroborylborenium Ion

Yizhao Huang, Zhen Hua Li and Huadong Wang

Angew Chem Int Ed, 2025
DOI: 10.1002/anie.202512223

Ge=B‐π‐Bindung: Synthese und reversible [2+2]‐Cycloaddition von Germaborenen

Dominik Raiser, Christian P. Sindlinger, Hartmut Schubert and Lars Wesemann

Angewandte Chemie, 2020, 132, 3175
DOI: 10.1002/ange.201914608

Metallfreie intermolekulare C‐H‐Borylierung von N‐Heterocyclen an B‐B‐Mehrfachbindungen

Tobias Brückner, Benedikt Ritschel, J. Oscar C. Jiménez‐Halla, Felipe Fantuzzi, Dario Duwe, Christian Markl, Rian D. Dewhurst, Maximilian Dietz and Holger Braunschweig

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202213284

Synthesis of a Linear Tetraboron Cation via Deprotonation of a Nonsupported Dimeric Hydroborylborenium Ion

Yizhao Huang, Zhen Hua Li and Huadong Wang

Angewandte Chemie, 2025
DOI: 10.1002/ange.202512223

A N-Phosphinoamidinato NHC-Diborene Catalyst for Hydroboration

Jun Fan, Jian-Qiang Mah, Ming-Chung Yang, Ming-Der Su and Cheuk-Wai So

J. Am. Chem. Soc., 2021, 143, 4993
DOI: 10.1021/jacs.0c12627

Metal‐Free Intermolecular C−H Borylation of N‐Heterocycles at B−B Multiple Bonds

Tobias Brückner, Benedikt Ritschel, J. Oscar C. Jiménez‐Halla, Felipe Fantuzzi, Dario Duwe, Christian Markl, Rian D. Dewhurst, Maximilian Dietz and Holger Braunschweig

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202213284

Bonding and stability of elusive silaboryne (SiB) and germaboryne (GeB) with donor base ligands

Sujit Das, Kavita Devi, Sonam Suthar and Kartik Chandra Mondal

J Comput Chem, 2023, 44, 1673
DOI: 10.1002/jcc.27118

Tetrakis(N-heterocyclic Carbene)-Diboron(0): Double Single-Electron-Transfer Reactivity

Jun Fan, An-Ping Koh, Jingsong Zhou, Zheng-Feng Zhang, Chi-Shiun Wu, Richard D. Webster, Ming-Der Su and Cheuk-Wai So

J. Am. Chem. Soc., 2023, 145, 11669
DOI: 10.1021/jacs.3c01801

Electron‐Precise Dicationic Tetraboranes: Syntheses, Structures and Rearrangement to an Alkylidene Borate‐Borenium Zwitterion and a 1,3‐Azaborinine

Wei Lu, Nicola Hensiek, Koushik Saha, Rian D. Dewhurst, Marcel Härterich, Conor Pranckevicius, Stephan Hagspiel, Maximilian Dietz, Ivo Krummenacher and Holger Braunschweig

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202300644

Ge=B π‐Bonding: Synthesis and Reversible [2+2] Cycloaddition of Germaborenes

Dominik Raiser, Christian P. Sindlinger, Hartmut Schubert and Lars Wesemann

Angew Chem Int Ed, 2020, 59, 3151
DOI: 10.1002/anie.201914608

Synthesis of Boron Analogues of Enamines via Hydroamination of a Boron−Boron Triple Bond

Tobias Brückner, Merlin Heß, Tom E. Stennett, Anna Rempel and Holger Braunschweig

Angew Chem Int Ed, 2021, 60, 736
DOI: 10.1002/anie.202012101

Chemistry of Dicationic Diboranes

Anna Widera, Erik Filbeck and Hans‐Jörg Himmel

Eur J Inorg Chem, 2020, 2020, 3017
DOI: 10.1002/ejic.202000483

Single and Double Hydroboration of B–B Triple Bonds and Convergent Routes to a Cationic Tetraborane

Tobias Brückner, Tom E. Stennett, Merlin Heß and Holger Braunschweig

J. Am. Chem. Soc., 2019, 141, 14898
DOI: 10.1021/jacs.9b07991

From the discovery of field ionization to field desorption and liquid injection field desorption/ionization-mass spectrometry—A journey from principles and applications to a glimpse into the future

Jürgen H Gross

Eur J Mass Spectrom (Chichester), 2020, 26, 241
DOI: 10.1177/1469066720939399