A d10 Ag(i) amine–borane σ-complex and comparison with a d8 Rh(i) analogue: structures on the η1 to η2:η2 continuum

Alice Johnson, Antonio J. Martínez-Martínez, Stuart A. Macgregor and Andrew S. Weller

Dalton Trans., 2019, 48, 9776
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Catalytic dehydrocoupling of amine-boranes and amines into diaminoboranes: isolation of a Pt(ii), Shimoi-type, η1-BH complex

Marta Roselló-Merino, Raquel J. Rama, Josefina Díez and Salvador Conejero

Chem. Commun., 2016, 52, 8389
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Exploring the mechanism of the hydroboration of alkenes by amine–boranes catalysed by [Rh(xantphos)]+

Heather C. Johnson, Rebecca Torry-Harris, Laura Ortega, Robin Theron, J. Scott McIndoe and Andrew S. Weller

Catal. Sci. Technol., 2014, 4, 3486
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The role of neutral Rh(PONOP)H, free NMe2H, boronium and ammonium salts in the dehydrocoupling of dimethylamine-borane using the cationic pincer [Rh(PONOP)(η2-H2)]+ catalyst

E. Anastasia K. Spearing-Ewyn, Nicholas A. Beattie, Annie L. Colebatch, Antonio J. Martinez-Martinez, Andrew Docker, Timothy M. Boyd, Gregg Baillie, Rachel Reed, Stuart A. Macgregor and Andrew S. Weller

Dalton Trans., 2019, 48, 14724
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Variable coordination modes and catalytic dehydrogenation of B-phenyl amine–boranes

Amit Kumar, Isobel K. Priest, Thomas N. Hooper and Andrew S. Weller

Dalton Trans., 2016, 45, 6183
DOI: 10.1039/C6DT00197A

Dehydropolymerization of H3B·NMeH2 Mediated by Cationic Iridium(III) Precatalysts Bearing κ3-iPr-PNRP Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism

Claire N. Brodie, Lia Sotorrios, Timothy M. Boyd, Stuart A. Macgregor and Andrew S. Weller

ACS Catal., 2022, 12, 13050
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A General, Rhodium‐Catalyzed, Synthesis of Deuterated Boranes and N‐Methyl Polyaminoboranes

Annie L. Colebatch, Benjamin W. Hawkey Gilder, George R. Whittell, Nicola L. Oldroyd, Ian Manners and Andrew S. Weller

Chemistry A European J, 2018, 24, 5450
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Catalytic Dehydrocoupling of Amine–Boranes using Cationic Zirconium(IV)–Phosphine Frustrated Lewis Pairs

Owen J. Metters, Stephanie R. Flynn, Christiana K. Dowds, Hazel A. Sparkes, Ian Manners and Duncan F. Wass

ACS Catal., 2016, 6, 6601
DOI: 10.1021/acscatal.6b02211

Metathesis by Partner Interchange in σ‐Bond Ligands: Expanding Applications of the σ‐CAM Mechanism

Robin N. Perutz, Sylviane Sabo‐Etienne and Andrew S. Weller

Angewandte Chemie, 2022, 134
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The Synthesis, Characterization and Dehydrogenation of Sigma‐Complexes of BN‐Cyclohexanes

Amit Kumar, Jacob S. A. Ishibashi, Thomas N. Hooper, Tanya C. Mikulas, David A. Dixon, Shih‐Yuan Liu and Andrew S. Weller

Chemistry A European J, 2016, 22, 310
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Phospholylmethano P-chirogenic-phosphine-borane as P-(η2-BH3)-chelating ligands of rhodium (I): Synthesis, characterization and asymmetric hydrogenation

Christine Salomon-Bertrand, Jérôme Bayardon, Hugo Lauréano, Sylvain Jugé, Jean-Claude Daran and Maryse Gouygou

Journal of Organometallic Chemistry, 2021, 938, 121753
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The [Rh(Xantphos)]+ catalyzed hydroboration of diphenylacetylene using trimethylamine-borane

Maximilian Dietz, Alice Johnson, Antonio Martínez-Martínez and Andrew S. Weller

Inorganica Chimica Acta, 2019, 491, 9
DOI: 10.1016/j.ica.2019.03.032

Metathesis by Partner Interchange in σ‐Bond Ligands: Expanding Applications of the σ‐CAM Mechanism

Robin N. Perutz, Sylviane Sabo‐Etienne and Andrew S. Weller

Angew Chem Int Ed, 2022, 61
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Mechanistic Studies of the Dehydrocoupling and Dehydropolymerization of Amine–Boranes Using a [Rh(Xantphos)]+ Catalyst

Heather C. Johnson, Erin M. Leitao, George R. Whittell, Ian Manners, Guy C. Lloyd-Jones and Andrew S. Weller

J. Am. Chem. Soc., 2014, 136, 9078
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Agostic interaction versus small molecule binding in [RuH(CO)(PPhNiPrPPh)]BAr4F complex

Kamla D. Netam, Apurba Kumar Pal, Munirathinam Nethaji and Balaji R. Jagirdar

Journal of Organometallic Chemistry, 2023, 992, 122693
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Approaches to Sigma Complexes via Displacement of Agostic Interactions: An Experimental and Theoretical Investigation

A. Ramaraj, K. Hari Krishna Reddy, Helena Keil, Regine Herbst-Irmer, Dietmar Stalke, Eluvathingal D. Jemmis and Balaji R. Jagirdar

Organometallics, 2017, 36, 2736
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On-Demand Metal-to-Metal Electron Donation during Zr–Ru Heterodinuclear-Catalyzed Amine–Borane Dehydrogenation

Jugal Kumawat and Daniel H. Ess

ACS Catal., 2024, 14, 16947
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Ammonia–Borane and Amine–Borane Dehydrogenation Mediated by Complex Metal Hydrides

Andrea Rossin and Maurizio Peruzzini

Chem. Rev., 2016, 116, 8848
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Dehydropolymerization of H3B·NMeH2 To Form Polyaminoboranes Using [Rh(Xantphos-alkyl)] Catalysts

Gemma M. Adams, Annie L. Colebatch, Joseph T. Skornia, Alasdair I. McKay, Heather C. Johnson, Guy C. Lloyd−Jones, Stuart A. Macgregor, Nicholas A. Beattie and Andrew S. Weller

J. Am. Chem. Soc., 2018, 140, 1481
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A New Perspective on Borane Chemistry: The Nucleophilicity of the B−H Bonding Pair Electrons

Qianyi Zhao, Rian D. Dewhurst, Holger Braunschweig and Xuenian Chen

Angew Chem Int Ed, 2019, 58, 3268
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(BB)-Carboryne Complex of Ruthenium: Synthesis by Double B–H Activation at a Single Metal Center

Bennett J. Eleazer, Mark D. Smith, Alexey A. Popov and Dmitry V. Peryshkov

J. Am. Chem. Soc., 2016, 138, 10531
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Experimental and Quantum Mechanical Study of Nucleophilic Substitution Reactions of meta- and para-Substituted Benzyl Bromides with Benzylamine in Methanol: Synergy Between Experiment and Theory

Rachuru Sanjeev, Ramavath Ravi, Vandanapu Jagannadham and Adam A. Skelton

Aust. J. Chem., 2017, 70, 90
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Polyhydrides of Platinum Group Metals: Nonclassical Interactions and σ-Bond Activation Reactions

Miguel A. Esteruelas, Ana M. López and Montserrat Oliván