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In this paper, the synthesis of a novel tetra-phenol π-extended dihydrophenazine is reported. The obtained derivative presents marked reducing properties in the excited state and was exploited as an organo-photocatalyst in dehalogenation and C–C bond formation reactions. These results underline the great potential of functionalized π-extended dihydrophenazines as organo-photocatalysts.

Graphical abstract: Synthesis of a novel tetra-phenol π-extended phenazine and its application as an organo-photocatalyst

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