A highly efficient low-valence tungsten-catalyzed deoxygenative reduction of tertiary amides to amines with pinacolborane (HBPin) is developed. This protocol uses commercially available W(CO)6 as a catalyst in a solution of hexane under the irradiation of visible light without other additives, and the TON is up to 2000.
B. Cheng, J. Xv, X. Ren, Y. Li, X. Ji and Z. Lu, Org. Chem. Front., 2025, 12, 3306 DOI: 10.1039/D4QO02340D
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
