Issue 10, 2019

Surface water treatment by UV/H2O2 with subsequent soil aquifer treatment: impact on micropollutants, dissolved organic matter and biological activity

Abstract

Because organic micropollutants (MP) are frequently detected in river waters that are used as drinking water sources, combining a relatively cost-efficient natural treatment with upstream advanced oxidation processes (AOP) appears promising for their efficient abatement. Such a multi-barrier system can be integrated in drinking water production schemes to minimize risks from potentially hazardous MPs. This study investigates the impact of an UV/H2O2 AOP before soil aquifer treatment (SAT) on the abatement of selected MPs (EDTA, acesulfame, iopamidol, iomeprol, metformin, 1H-benzotriazole, iopromide), dissolved organic matter (DOM) (apparent molecular size distribution, specific UV absorbance at 254 nm – SUVA) and microbial parameters (intact cell count, cell-bound ATP). A pilot plant consisting of an AOP (0.5 m3 h−1, 4 mg L−1 H2O2, 6000 J m−2) and two parallel soil columns (filtration velocity: 1 m d−1, column height: 1 m) was continuously operated over a period of 15 months with Rhine river water pre-treated with rapid sand filtration. The investigations revealed a shift towards longer retention times of the humic substances peak in LC analysis of DOM, lower SUVA and higher biodegradability of DOM after UV/H2O2 treatment. In addition, an overall higher abatement of all investigated MPs by the combined treatment was observed (AOP with subsequent SAT) compared to either process alone. This observation could be explained by an addition of the single treatment effects. The strong primary disinfection effect of the AOP was detectable along the first meter of infiltration, but did not lead to any change in the column performance (i.e., similar abatement of dissolved organic matter).

Graphical abstract: Surface water treatment by UV/H2O2 with subsequent soil aquifer treatment: impact on micropollutants, dissolved organic matter and biological activity

Supplementary files

Article information

Article type
Paper
Submitted
28 জুন 2019
Accepted
14 আগষ্ট 2019
First published
22 আগষ্ট 2019

Environ. Sci.: Water Res. Technol., 2019,5, 1709-1722

Surface water treatment by UV/H2O2 with subsequent soil aquifer treatment: impact on micropollutants, dissolved organic matter and biological activity

R. Wünsch, J. Plattner, D. Cayon, F. Eugster, J. Gebhardt, R. Wülser, U. von Gunten and T. Wintgens, Environ. Sci.: Water Res. Technol., 2019, 5, 1709 DOI: 10.1039/C9EW00547A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements