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Abstract | Cited by

The first family of hybrid mononuclear organic–inorganic lanthanoid complexes is reported, based on [PW11O39]7− and 1,10-phenanthroline ligands. This hybrid approach causes a dramatic improvement of the relaxation time (×1000) with a decrease of the optimal field while maintaining the Ueff of the inorganic analogues.

Graphical abstract: Hybrid organic–inorganic mononuclear lanthanoid single ion magnets

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