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Abstract | Cited by

We demonstrate that polymer-grafted metal nanoparticles of various shapes and dimensions self-assemble into arrays of string-like superstructures upon phase separation within a matrix polymer. Interparticle orientation within these nanocomposites can be dictated by the chain length of the grafted polymer.

Graphical abstract: Designer nanojunctions: orienting shaped nanoparticles within polymer thin-film nanocomposites

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