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Abstract | Cited by

By introducing SO2 as the sulfur source, the synthesis of an extensive family of cluster endohedral fullerenes Sc2S@C2n (n = 40–50) was demonstrated and a new isomer of Sc2S@C82 (Cs : 6) was isolated and characterized by spectroscopic and electrochemical methods for the first time.

Graphical abstract: Synthesis of a new endohedral fullerene family, Sc2S@C2n (n = 40–50) by the introduction of SO2

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