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Halo-perfluoroalkoxylation of gem-difluoroalkenes with short-lived alkali metal perfluoroalkoxides in triglyme

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Silver-catalyzed regioselective direct dichlorotrifluoromethoxylation of terminal alkynes

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4-Trifluoromethoxy proline: synthesis of stereoisomers and lipophilicity study

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Synthesis of α-trifluoromethoxy-sulfide through the Pummerer rearrangement

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Org. Biomol. Chem., 2025, 23, 6127
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Silver-mediated intermolecular ortho-trifluoromethoxylation of pyridyl-arenes

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New synthetic approaches for the construction of difluoromethylated architectures

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Org. Biomol. Chem., 2025, 23, 3029
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O-Trifluoromethylation of ketones: an alternative straightforward route to alkenyl trifluoromethyl ethers

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Strategic advances in C–OCF3 bond transformations

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Synthesis of Ngai Reagent and Longer Carbon Chain Variants for Perfluoroalkoxylations

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Nitrogen-Based Organofluorine Functional Molecules: Synthesis and Applications

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Chem. Rev., 2025, 125, 4603
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Mechanochemical trifluoromethoxylation of aryltrimethylammonium triflates, aryldiazonium tetrafluoroborates, and aryl pinacolboranes

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From mortars to mills: mechanochemistry as a tool for efficient organic transformations

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Cobalt‐Catalyzed Enantioselective Hydrotrifluoromethoxylation of Aromatic Alkenes

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Angew Chem Int Ed, 2025, 64
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Cobalt‐Catalyzed Enantioselective Hydrotrifluoromethoxylation of Aromatic Alkenes

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Recent Advances on Catalytic Asymmetric Synthesis of Molecules Bearing a Fluorine-Containing Stereogenic Carbon Center (2015–2024)

Subarna Jyoti Kalita, Jing Qi, Lu Xiao, Debarshi Saha, Yi-Yong Huang and Norio Shibata

Chem. Rev., 2025, 125, 8477
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Photocatalyst-Regulated Trifluoromethoxylation of Aryl Halides under Silver Promotion

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Review and Theoretical Analysis of Fluorinated Radicals in Direct CAr−H Functionalization of (Hetero)arenes

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Recent Progress on Methods for the Preparation of Mono/Di/Trifluoromethoxylation Reagents

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Fluorinated building blocks in drug design: new pathways and targets

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Phenylseleno trifluoromethoxylation of alkenes

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Synthetic Access to Persulfuranyl Scaffolds via Direct and Indirect Methods

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Dual-Functional Group Transfer Reagents for Dihalogenation Reactions

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Recent advances in direct 1,2-bis-trifluoro-methylation, -methoxylation, -methylthiolation, and –methylselenylation of unsaturated hydrocarbons

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A mild and practical approach to N-CF3 secondary amines via oxidative fluorination of isocyanides

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Catalyst‐Free Trifluoromethoxylation of Silyl Enol Ethers and Allyl Silanes with Bis(trifluoromethyl)peroxide

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Fluoroalkoxylating Reagents in Organic Synthesis: Recent Advances

Mingxi Chen and Quande Wang

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Visible-Light Photoredox-Induced and Copper-Catalyzed Trifluoromethoxylation of Diaryliodonium Tetrafluoroborates

Jinjin Li, Mingxin Zhao, Qingyun Huang and Pingping Tang

J. Org. Chem., 2026, 91, 3031
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Catalyst‐Free Trifluoromethoxylation of Silyl Enol Ethers and Allyl Silanes with Bis(trifluoromethyl)peroxide

Lilian M. Maas, Carlo Fasting, Patrick Voßnacker, Niklas Limberg, Paul Golz, Carsten Müller, Sebastian Riedel and Matthew N. Hopkinson

Angewandte Chemie, 2024, 136
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N-Halosuccinimide enables cascade oxidative trifluorination and halogenative cyclization of tryptamine-derived isocyanides

Jun-Yunzi Wu, Long-Ling Huang, Jia-Luo Fu, Jia-Yi Li, Shuang Lin, Shuang Yang, Zhi-Shu Huang, Honggen Wang and Qingjiang Li

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A journey into trifluoromethylchalcogenation: some reagents from Lyon

Thierry Billard

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2-Trifluoromethoxyacetic acid – Synthesis and characterization

Thorsten Meier, Sabine Lorenzen, Tanja Knuplez, Tobias Preitschopf, Karsten Koppe, Peter Barthen, Rüdiger Bertermann, Michael Schulte, Nikolai Ignat‘ev and Maik Finze

Journal of Fluorine Chemistry, 2025, 282, 110396
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Review and Theoretical Analysis of Fluorinated Radicals in Direct CAr−H Functionalization of (Hetero)arenes

Anthony J. Fernandes, Rahul Giri, Kendall N. Houk and Dmitry Katayev

Angewandte Chemie, 2024, 136
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Silver-Catalyzed 1,3-Ditrifluoromethoxylation and 1,3-Fluorotrifluoromethoxylation of Arylcyclopropanes

Fan Zhou, Lei Fang, Yafeng Si, Qingyun Huang and Pingping Tang

Org. Lett., 2026, 28, 224
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Photoredox Catalytic Hydropentafluorosulfanylation of Alkynes by Sulfur Hexafluoride

Max Flügge, Sven Klehenz, Silas Leidenheimer, David Rombach and Hans-Achim Wagenknecht

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