Merging strain-release and copper catalysis: the selective ring-opening cross-coupling of 1,2-oxazetidines with boronic acids

Ji-Hang Xu, Zi-Kui Liu, Yan-Liu Tang, Yang Gao and Xiao-Qiang Hu

Chem. Commun., 2022, 58, 4180
DOI: 10.1039/D2CC00461E

Facile, general allylation of unactivated alkyl halides via electrochemically enabled radical-polar crossover

Haifeng Chen and Magnus Rueping

Chem. Sci., 2025, 16, 6317
DOI: 10.1039/D4SC07923J

Photo/electro-catalytic stereo/enantioselective cross aza-pinacol coupling: synthesis of chiral amino alcohols

Padmanava Barik, Subhasmita Sahoo, Usharani Das and Santosh Kumar Nanda

Chem. Commun., 2025, 61, 11581
DOI: 10.1039/D5CC03477A

Copper-catalyzed remote double functionalization of allenynes

Yulong Song, Chunling Fu, Jian Zheng and Shengming Ma

Chem. Sci., 2024, 15, 7789
DOI: 10.1039/D4SC00034J

Implementation of micelle-enabled C(sp2)–C(sp3) cross-electrophile coupling in pharmaceutical synthesis

Bin Wu, Ning Ye, Kangming Zhao, Min Shi, Jiayu Liao, Jing Zhang, Wei Chen, Xianzhong Li, Yufeng Han, Margery Cortes-Clerget, Morgan Louis Regnier, Michael Parmentier, Christian Mathes, Florian Rampf and Fabrice Gallou

Chem. Commun., 2024, 60, 2349
DOI: 10.1039/D3CC05916B

Copper-catalyzed thiocarbonylation and thiolation of alkyl iodides

Qingqiang Tian, Rongjing Sun and Yahui Li

Org. Biomol. Chem., 2022, 20, 1186
DOI: 10.1039/D2OB00008C

Cobalt-catalyzed cross-coupling reactions of aryl- and alkylaluminum derivatives with (hetero)aryl and alkyl bromides

Giuseppe Dilauro, Francesco Messa, Fabio Bona, Serena Perrone and Antonio Salomone

Chem. Commun., 2021, 57, 10564
DOI: 10.1039/D1CC04002B

Recent advances in the tandem copper-catalyzed Ullmann–GoldbergN-arylation–cyclization strategies

Jyoti M. Honnanayakanavar, Owk Obulesu and Surisetti Suresh

Org. Biomol. Chem., 2022, 20, 2993
DOI: 10.1039/D2OB00082B

Micelle enabled C(sp2)–C(sp3) cross-electrophile coupling in water via synergistic nickel and copper catalysis

Ning Ye, Bin Wu, Kangming Zhao, Xiaobin Ge, Yu Zheng, Xiaodong Shen, Lei Shi, Margery Cortes-Clerget, Morgan Louis Regnier, Michael Parmentier and Fabrice Gallou

Chem. Commun., 2021, 57, 7629
DOI: 10.1039/D1CC02885E

Facile preparation of organosilanes from benzylboronates and gem-diborylalkanes mediated by KOtBu

Man Tang, Wenyan Zhu, Huaxing Sun, Jing Wang, Su Jing, Minyan Wang, Zhuangzhi Shi and Jiefeng Hu

Chem. Sci., 2023, 14, 7355
DOI: 10.1039/D3SC02461J

Visible light-induced manganese-catalyzed aminocarbonylation of alkyl iodides under atmospheric pressure at room temperature

Yan-Hua Zhao, Xing-Wei Gu and Xiao-Feng Wu

Org. Chem. Front., 2024, 11, 442
DOI: 10.1039/D3QO01688A

Consecutive 2-azidoallylation/click cycloaddition of active methylene for synthesis of functionalized hepta-1,6-dienes with a bis-1,2,3-triazole scaffold

Zhenhua Liu, Huimin Chen, Xingxing Gan, Lianxiao Wang, Ping Lin, Jiayi Li, Xiuxiu Huang, Rongbiao Tian, Xuan Liu, Wen Gao and Bo Tang

Org. Chem. Front., 2022, 9, 6926
DOI: 10.1039/D2QO01118B

Catalyst-controlled regioselective Sonogashira coupling of 9-substituted-6-chloro-2,8-diiodopurines

Gibae Kim, Grim Lee, Gyudong Kim, Yeonseong Seo, Dnyandev B. Jarhad and Lak Shin Jeong

Org. Chem. Front., 2022, 9, 5536
DOI: 10.1039/D2QO00823H

A photocatalytic traceless C–N bond formation/cleavage strategy enabling the use of (α-chiral) alkyl aldehydes as deoxygenative (chiral) alkyl radical equivalents

Hanyang Bao, Limeng Zheng, Qian Liu, Mingfeng Han, Ya Li, Miao Bao, Yuanqiang Li, Pucha Yan and Yunkui Liu

Org. Chem. Front., 2023, 10, 5551
DOI: 10.1039/D3QO01059G

Electromagnetic milling promoted mechanochemical copper-catalyzed C–O coupling reaction for diaryl ether formation

Zhaoxuan Zeng, Zhe Tian, Zhihan Zhang, Hongzhen Sun, Qing Liu, Lizhi Zhang, Fachao Yan, Zengdian Zhao and Hui Liu

Org. Chem. Front., 2025, 12, 1528
DOI: 10.1039/D4QO01909A

Radical coupling reactions of hydrazinesviaphotochemical and electrochemical strategies

Yilin Kong, Kangning Wei and Guobing Yan

Org. Chem. Front., 2022, 9, 6114
DOI: 10.1039/D2QO01348G

Unleashing the potentiality of metals: synergistic catalysis with light and electricity

Zhengjia Shen, Jia-Lin Tu and Binbin Huang

Org. Chem. Front., 2024, 11, 4024
DOI: 10.1039/D4QO00797B

Visible-light harvesting 2D copper-cluster-based MOFs as efficient ROS generators for selective oxidation of amines

Huilin Huang, Qiong Yang, Kun Yao, Wenchao Geng and Xu Jing

Dalton Trans., 2025, 54, 6015
DOI: 10.1039/D5DT00120J

Phosphination of aryl/alkyl bromides via Mn-mediated reductive C–P coupling

Likun Dong, Bing Zhong, Yu-Shan Zhang, Jin-Dong Yang and Jin-Pei Cheng

Chem. Commun., 2024, 60, 12549
DOI: 10.1039/D4CC04750H

Redox-enabled cooperative catalysis by activating secondary alcohols using low-valent Zn complexes

Arup Samanta, Amit Chaubey, Debjyoti Pal, Krishna Majhi and Dipankar Srimani

Chem. Commun., 2024, 60, 10398
DOI: 10.1039/D4CC03407D

A general copper catalytic system for cross-coupling of aryl iodides with chlorosilanes under reductive conditions

Liping Qiu, Yiqi Liu, Han Chen, Lijuan Song and Weilong Xie

Chem. Sci., 2025, 16, 9454
DOI: 10.1039/D5SC01304F

Metalated covalent organic frameworks: from synthetic strategies to diverse applications

Qun Guan, Le-Le Zhou and Yu-Bin Dong

Chem. Soc. Rev., 2022, 51, 6307
DOI: 10.1039/D1CS00983D

Copper-catalyzed Sonogashira reactions: advances and perspectives since 2014

Koduvarathodi Vadakkethil Arundhathi, Palemkunnummal Vaishnavi, Thaipparambil Aneeja and Gopinathan Anilkumar

RSC Adv., 2023, 13, 4823
DOI: 10.1039/D2RA07685C

Copper-catalyzed amidoalkylation of amines via C–C bond cleavage from cyclic oxaziridines

Xin-Xin Liu, Shaohong Wang, Yuan Zhang, Fan Yang, Hong-Jie Miao, Peng-Chen Ma, Li-Na Guo and Pin Gao

Green Chem., 2025, 27, 9882
DOI: 10.1039/D5GC03001C

Theoretical study of copper hydride complexes catalyzing terminal alkyne hydroalkylation for C(sp2)–C(sp3) bond formation

Hui Li and Taiming Bai

Dalton Trans., 2024, 53, 153
DOI: 10.1039/D3DT03514J

Multiligand-enabled, copper-catalyzed Hiyama coupling of arylsilanes with unactivated secondary alkyl halides: reaction development and mechanistic insights

Jiajing Zhou, Zhiqiang Zhang, Yan Cao and Weilong Xie

Chem. Sci., 2025, 16, 5109
DOI: 10.1039/D4SC07441F

Ruthenium pincer complex-catalyzed heterocycle compatible alkoxycarbonylation of alkyl iodides: substrate keeps the catalyst active

Han-Jun Ai, Yang Yuan and Xiao-Feng Wu

Chem. Sci., 2022, 13, 2481
DOI: 10.1039/D1SC06581E

Recent advances in the photocatalytic cleavage of C–C and C–N bonds associated with amines and their derivatives

Qibo Ni, Yan Zhou, Lang Chen and Yunkui Liu

Org. Chem. Front., 2025, 12, 975
DOI: 10.1039/D4QO02038C

Heterogeneous copper-catalyzed synthesis of diaryl sulfones

Xinchi Gong, Zhengqi Shen, Ganghu Wang, Lingling Qu and Chunyin Zhu

Org. Biomol. Chem., 2021, 19, 10662
DOI: 10.1039/D1OB01830B

Tandem copper catalyzed regioselective N-arylation–amidation: synthesis of angularly fused dihydroimidazoquinazolinones and the anticancer agent TIC10/ONC201

Jyoti M. Honnanayakanavar, Jagadeesh Babu Nanubolu and Surisetti Suresh

Org. Biomol. Chem., 2021, 19, 8497
DOI: 10.1039/D1OB01561C

Asymmetric oxidative rearrangement of indoles enabled by dual catalysis with in situ generated acyl hypoiodite and chiral phosphoric acid

Haowei Gao, Xihui Yang and Lei Shi

Org. Chem. Front., 2025, 12, 3848
DOI: 10.1039/D5QO00302D

Nickel-catalyzed formation of quaternary carbon centers using tertiary alkyl electrophiles

Weichao Xue, Xiao Jia, Xuan Wang, Xianghua Tao, Zhigang Yin and Hegui Gong

Chem. Soc. Rev., 2021, 50, 4162
DOI: 10.1039/D0CS01107J

Insights into the mechanism of 3d transition-metal-catalyzed directed C(sp3)–H bond functionalization reactions

Andrés García-Viada, Juan C. Carretero, Javier Adrio and Nuria Rodríguez

Chem. Soc. Rev., 2025, 54, 4353
DOI: 10.1039/D4CS00657G

Photocatalytic applications of covalent organic frameworks: synthesis, characterization, and utility

Jared G. Doremus, Bertha Lotsi, Aadarsh Sharma and Psaras L. McGrier

Nanoscale, 2024, 16, 21619
DOI: 10.1039/D4NR03204G

Visible-light-driven C(sp3)–H alkylation of heterobenzylic amines via electron donor–acceptor complexes

Yumei Huo, Beibei Chen, Zhaoqing Xu, Xiaoyu Ren, Rupeng Qi and Chao Wang

Org. Chem. Front., 2024, 11, 205
DOI: 10.1039/D3QO01765F

Modular dehydrogenative cross-nucleophile coupling for direct construction of tetrasubstituted carbons

Peng Wang, Qiang Wang, Meng Wang, Liang Wang, Lubin Xu, Xiong-Li Liu, Fangzhi Hu and Shuai-Shuai Li

Org. Chem. Front., 2025, 12, 448
DOI: 10.1039/D4QO01641F

Covalent organic frameworks as heterogeneous photocatalysts for cross-coupling reactions

Avanti Chakraborty, Monojit Roy, Akhtar Alam, Debashis Adhikari and Pradip Pachfule

Green Chem., 2024, 26, 9619
DOI: 10.1039/D4GC03467H

Cu-mediated vs. Cu-free selective borylation of aryl alkyl sulfones

Mingming Huang, Man Tang, Jiefeng Hu, Stephen A. Westcott, Udo Radius and Todd B. Marder

Chem. Commun., 2022, 58, 395
DOI: 10.1039/D1CC06144E

Photoinduced copper catalyzed nitrogen-to-alkyl radical relay Sonogashira-type coupling of o-alkylbenzamides with alkynes

Yan-fang Zhan, Jia-ming Chen, Xia-xin Sheng, Chao-ying Qiu, Yan Jiang, Sen Yang and Ming Chen

Chem. Commun., 2024, 60, 7906
DOI: 10.1039/D4CC02861A

Copper-catalyzed synthesis of β-boryl cyclopropanesvia1,2-borocyclopropanation of aryl olefins with CO as the C1 source

Hui-Qing Geng and Xiao-Feng Wu

Chem. Sci., 2023, 14, 5638
DOI: 10.1039/D3SC01090B

Recent advances in pincer–nickel catalyzed reactions

Vinay Arora, Himani Narjinari, Pran Gobinda Nandi and Akshai Kumar

Dalton Trans., 2021, 50, 3394
DOI: 10.1039/D0DT03593A

Copper-catalyzed carbonylative multi-component borylamidation of alkenes for synthesizing γ-boryl amides with CO as both methylene and carbonyl sources

Hui-Qing Geng, Yan-Hua Zhao, Peng Yang and Xiao-Feng Wu

Chem. Sci., 2024, 15, 3996
DOI: 10.1039/D4SC00156G

Exploring the reductive CO2 fixation with amines and hydrosilanes using readily available Cu(ii) NHC–phenolate catalyst precursors

Giammarco Meloni, Luca Morgan, David Cappelletti, Matteo Bevilacqua, Claudia Graiff, Piermaria Pinter, Andrea Biffis, Cristina Tubaro and Marco Baron

Dalton Trans., 2024, 53, 18128
DOI: 10.1039/D4DT02936D

Ppm level palladium catalyzed regioselective remote arylation of alkenyl alcohols

Chong Liu, Ling Wang and Haibo Ge

Chem. Sci., 2025, 16, 12449
DOI: 10.1039/D5SC02745D

Application of statistical learning and mechanistic modelling towards mapping the substrate electronic space in a Cu-catalyzed Suzuki–Miyaura coupling

Francisco A. Gómez-Mudarra, Gabriel Aullón and Jesús Jover

Catal. Sci. Technol., 2023, 13, 1381
DOI: 10.1039/D2CY02039D

Carbonylation involving organocopper intermediates

Zhi-Peng Bao and Xiao-Feng Wu

EES Catal., 2025
DOI: 10.1039/D5EY00220F

Copper-Catalyzed Direct Carbonylation of Carbenes toward the Synthesis of Propanedioic Acid Derivatives

Hefei Yang, Zhi-Peng Bao, Le-Cheng Wang and Xiao-Feng Wu

Org. Lett., 2023, 25, 1963
DOI: 10.1021/acs.orglett.3c00506

Ligand‐free CuO nanoparticles catalyzed S‐arylation of heterocyclic thiols using aryl halides

Sudhamoyee Kataky, Ankita Rakshit, Sultana Parveen Ahmed, Bikash Kumar Kalita, Bipul Sarma and Ashim J. Thakur

Applied Organom Chemis, 2024, 38
DOI: 10.1002/aoc.7518

Recent advances in the synthesis of benzimidazolo[2,1-a]isoquinoline-6(5H)-one derivatives from N-methylacryloyl-2-arylbenzimidazoles

Qing-Gang Mei and Qing-Han Li

Tetrahedron, 2024, 160, 134050
DOI: 10.1016/j.tet.2024.134050

Amide and peptide synthesis via nickel-catalyzed cross-electrophile coupling

Xing-Bang Liu, Zhen-Qi Wang, Yan-Jie Yang, Kai Qu and Yuan Huang

Cell Reports Physical Science, 2024, 5, 102248
DOI: 10.1016/j.xcrp.2024.102248

Copper-Catalyzed Reactions of Aryl Halides with N-Nucleophiles and Their Possible Application for Degradation of Halogenated Aromatic Contaminants

Tomáš Weidlich, Martina Špryncová and Alexander Čegan

Catalysts, 2022, 12, 911
DOI: 10.3390/catal12080911

Copper-(Photo)Catalyzed Radical Reactions with Organic Halides

Gwilherm Evano and Cédric Theunissen

Synlett, 2024, 35, 485
DOI: 10.1055/a-2095-5242

Enantioselective Synthesis of α‐Hydroxy Allyl Ketones via BINAP‐CuH‐Catalyzed Hydroacylation

Sundaram Maurya, N. Navaneetha, Prativa Behera, Jagadeesh Babu Nanubolu, Lisa Roy and Rambabu Chegondi

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202420106

Desulfonylative Transformations of Sulfones by Transition-Metal Catalysis, Photocatalysis, and Organocatalysis

Masakazu Nambo, Yuuki Maekawa and Cathleen M. Crudden

ACS Catal., 2022, 12, 3013
DOI: 10.1021/acscatal.1c05608

An overview on copper in industrial chemistry: From ancient pigment to modern catalysis

Mohammad Soleiman-Beigi, Masoud Mohammadi and Homa Kohzadi

Coordination Chemistry Reviews, 2025, 529, 216438
DOI: 10.1016/j.ccr.2025.216438

Nickel-Catalyzed Amination of Alkyl Electrophiles

Qing Wang, Xiangzhang Tao, Shengyang Ni, Yi Pan and Yi Wang

Org. Lett., 2023, 25, 5822
DOI: 10.1021/acs.orglett.3c02082

Recent Progress in the Synthesis of Substituted Benzo[b]furan Derivatives

Zhihao Zhang, Xin Jiang and Qinghan Li

Chinese Journal of Organic Chemistry, 2022, 42, 945
DOI: 10.6023/cjoc202110008

Oxidative addition of an alkyl halide to form a stable Cu(III) product

Yongrui Luo, Yuli Li, Jian Wu, Xiao-Song Xue, John F. Hartwig and Qilong Shen

Science, 2023, 381, 1072
DOI: 10.1126/science.adg9232

Cu-Catalyzed C(sp3) Amination of Unactivated Secondary Alkyl Iodides Promoted by Diaryliodonium Salts

Xin-Yang Lv and Ruben Martin

Org. Lett., 2023, 25, 3750
DOI: 10.1021/acs.orglett.3c01216

Cyclic Diphenylchloronium-Salt-Triggered Coupling of Sulfides with Nucleophiles: Modular Assembly of Pharmaceuticals

Bangxiong Kang, Li Wei, Huanfeng Jiang and Chaorong Qi

Org. Lett., 2025, 27, 3655
DOI: 10.1021/acs.orglett.5c00768

Post-synthetic generation of nanomagnetized tetraaza-copper (II): as a novel heterogeneous catalyst for synthesis of fused N-heterocycles

Ahmed Talal Ali, Ahmed Ibrahim Hamzah, A. H. Shather, Ali Jihad Hemid Al-Athari, Amjad I. Oraibi and Haider Abdulkareem Almashhadani

Res Chem Intermed, 2024, 50, 1371
DOI: 10.1007/s11164-023-05218-w

Photoinduced Copper-Catalyzed Asymmetric C–O Cross-Coupling

Jun Chen, Yu-Jie Liang, Peng-Zi Wang, Guo-Qing Li, Bin Zhang, Hao Qian, Xiao-Die Huan, Wei Guan, Wen-Jing Xiao and Jia-Rong Chen

J. Am. Chem. Soc., 2021, 143, 13382
DOI: 10.1021/jacs.1c06535

Palladium(II) complexes derived from N,N'−diarylthiourea: Structural aspects and applications toward Suzuki-Miyaura coupling reactions

Taruna Singh, Sushil Kumar, Natesan Thirupathi and Pramod Kumar

Journal of Molecular Structure, 2023, 1288, 135797
DOI: 10.1016/j.molstruc.2023.135797

Electrochemically promoted C(sp3)–C(sp2) bond formation via radical/radical anion cross-coupling

Mingchun Wang, Ao Song, Xiupeng Wang, Qingchen Xiong, Zhaopeng Li, Xiangyan Shen, Rongzhou Wang and Hailin Cong

Molecular Catalysis, 2024, 562, 114228
DOI: 10.1016/j.mcat.2024.114228

Catalytically Relevant Organocopper(III) Complexes Formed through Aryl-Radical-Enabled Oxidative Addition

Wenhao Yan, Andrew T. Poore, Lingfeng Yin, Samantha Carter, Yeu-Shiuan Ho, Chao Wang, Stephen C. Yachuw, Yu-Ho Cheng, Jeanette A. Krause, Mu-Jeng Cheng, Shiyu Zhang, Shiliang Tian and Wei Liu

J. Am. Chem. Soc., 2024, 146, 15176
DOI: 10.1021/jacs.4c01668

Ligand‐Controlled Regiodivergent Thiocarbonylation of Alkynes toward Linear and Branched α,β‐Unsaturated Thioesters

Han‐Jun Ai, Wangyang Lu and Xiao‐Feng Wu

Angewandte Chemie, 2021, 133, 17315
DOI: 10.1002/ange.202106079

Novel One-Pot Cyclization Reactions: Synthesis of Pentasubstituted Cyclohexane Derivatives Containing Chiral Carbon Atoms

E. Liu, Z. S. Jin and F. F. Jian

Russ J Org Chem, 2023, 59, 196
DOI: 10.1134/S1070428023010220

Cobalt-Catalyzed Hydroxymethylation of Alkyl Halides with CO as the C1 Source

Yang Yuan, Nai-Xian Sun, Chang-Sheng Wang, Kai Guo and Xiao-Feng Wu

Org. Lett., 2023, 25, 5084
DOI: 10.1021/acs.orglett.3c01811

One-Pot Synthesis of N,N-Diphenyl-2-benzothiazolamines from 1-(2-Iodophenyl)-3-phenylthioureas and Iodobenzenes

Jie Ma, Rong Feng, Hao-Lin Zhou, Er-Jun Hao, Zhen Shi and Zhi-Bing Dong

J. Org. Chem., 2022, 87, 14342
DOI: 10.1021/acs.joc.2c01789

Copper(II)‐Catalyzed Regioselective H/D Exchange Based on Reversible C−H Activation

Yuhang Su, Zhi‐Jiang Jiang, Jiawei Han, Lujie Duan, Jian‐Fei Bai, Jia Chen and Zhanghua Gao

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202403121

Deaminative Arylation and Alkenyaltion of Aliphatic Tertiary Amines with Aryl and Alkenylboronic Acids via Nitrogen Ylides

Jianke Su, Chengbo Li, Xinyuan Hu, Yu Guo and Qiuling Song

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202212740

Transition‐Metal‐Mediated Fluoroalkylation of Carbon Electrophiles through Cross‐Electrophile Couplings

Yun‐Cheng Luo and Xingang Zhang

Chin. J. Chem., 2024, 42, 3499
DOI: 10.1002/cjoc.202400672

One-Pot Construction of β-Selective Quinolines with γ-Quaternary Carbon from Vinylquinolines with Active Ylides via Pd/Sc/Brønsted Acid Co-Catalysis

Longlong Song, Lulu Xiong, Dan Ni, Weixiong Chen, Jian Ji, Jian Xue, Xuwen Chen, Xiang Wu, Xiao He and Shunying Liu

ACS Catal., 2023, 13, 6509
DOI: 10.1021/acscatal.2c05824

One-pot synthesis, anticancer, EGFR and caspases assays of novel fused [1,2,3]triazolo-pyrrolo[2,1-b]quinazolinones

Narahari Udayasree, Ramesh Babu Haridasyam, Rambabu Palabindela, Thupurani Murali Krishna and Sirassu Narsimha

Journal of Molecular Structure, 2025, 1320, 139570
DOI: 10.1016/j.molstruc.2024.139570

Stereospecific Nickel-Catalyzed Reductive Cross-Coupling of Alkyl Tosylate and Allyl Alcohol Electrophiles

Quentin D. Tercenio and Erik J. Alexanian

Org. Lett., 2021, 23, 7215
DOI: 10.1021/acs.orglett.1c02616

Copper‐Catalyzed Carbonylative Cross‐Coupling of Alkyl Iodides and Amines

Johanne Ling, Antoine Bruneau‐Voisine, Guillaume Journot and Gwilherm Evano

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202201356

Modular and Diverse Synthesis of Acrylamides by Palladium‐Catalyzed Hydroaminocarbonylation of Acetylene

Zhusong Cao, Qiang Wang, Helfried Neumann and Matthias Beller

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202410597

Ru(II)‐Protic‐NHC Complex Catalyzed Selective N‐alkylation of Anilines with Primary Alcohols: Mechanistic Insights and Role of Salt Additives

Achena Saha, Shambhu Nath, Ekta Yadav and Amrendra K. Singh

ChemCatChem, 2025, 17
DOI: 10.1002/cctc.202500184

Iodine and Iodide in Reductive Transformations

J. Armando Luján‐Montelongo, Jeferson B. Mateus‐Ruiz and Ricardo M. Valdez‐García

Eur J Org Chem, 2023, 26
DOI: 10.1002/ejoc.202201156

Nickel Metallaphotoredox Buchwald–Hartwig Amination Reactions: A Perspective on Irradiation Light Wavelength

Meiying Kuai, Zihan Jia, Lijie Chen, Shuang Gao and Weiwei Fang

Eur J Org Chem, 2024, 27
DOI: 10.1002/ejoc.202300933

Manganese Salan Complexes as Catalysts for Hydrosilylation of Aldehydes and Ketones

Nora Almutairi, Srikanth Vijjamarri and Guodong Du

Catalysts, 2023, 13, 665
DOI: 10.3390/catal13040665

Nano-architectured polypyrrole based magnetic nanocatalyst for the N- arylation of imidazoles and fused imidazoles

Sumanth Hegde, Sajin Surendran, Ajesh Vijayan and Aatika Nizam

Catalysis Today, 2025, 449, 115180
DOI: 10.1016/j.cattod.2024.115180

Origin of Ligand Effects on Stereoinversion in Pd-Catalyzed Synthesis of Tetrasubstituted Olefins

Lingfei Hu, Han Gao, Yanlei Hu, Xiangying Lv, Yan-Bo Wu and Gang Lu

J. Org. Chem., 2021, 86, 18128
DOI: 10.1021/acs.joc.1c02400

Cuprous Cluster-Based Coordination Sheets as Photocatalytic Regulators to Activate Oxygen, Benzoquinone, and Thianthrenium Salts

Huilin Huang, Xu Jing, Bingwen Zhong, Changgong Meng and Chunying Duan

ACS Appl. Mater. Interfaces, 2021, 13, 58498
DOI: 10.1021/acsami.1c16280

Synergistic Copper‐Aminocatalysis for Direct Tertiary α‐Alkylation of Ketones with Electron‐Deficient Alkanes

Qi‐Chao Shan, You‐Wei Wu, Mu‐Xiang Chen, Xuefei Zhao, Teck‐Peng Loh and Xu‐Hong Hu

Advanced Science, 2024, 11
DOI: 10.1002/advs.202402255

Copper‐Catalyzed Borylative Methylation of Alkyl Iodides with CO as the C1 Source: Advantaged by Faster Reaction of CuH over CuBpin

Fu‐Peng Wu and Xiao‐Feng Wu

Angewandte Chemie, 2021, 133, 11836
DOI: 10.1002/ange.202102197

Kanamycin−Cu(II) Complex Catalyzed Ullmann Amine Synthesis at Room Temperature: A Tool for Mechanistic Insights into Methylene Blue Degradation

Huma Basheer, Sadia Shamsi, Abdul Qadir, Kalicharan Sharma, Chandra S. Azad, Amit Kumar and Imran A. Khan

Eur J Org Chem, 2024, 27
DOI: 10.1002/ejoc.202400328

Iron-catalyzed domino coupling reactions of π-systems

Austin Pounder and William Tam

Beilstein J. Org. Chem., 2021, 17, 2848
DOI: 10.3762/bjoc.17.196

Gold‐Catalyzed Synthesis of Spirocycles: Recent Advances

Somnath Ganguly, Sayantika Bhakta and Tapas Ghosh

ChemistrySelect, 2022, 7
DOI: 10.1002/slct.202201407

Transition-Metal-Free, Reductive Csp2–Csp3 Bond Constructions via Electrochemically Induced Alkyl Radicals

Shuhua Wu, Jiahui Huang, Lulu Kang, Yiyi Zhang and Kedong Yuan

Org. Lett., 2024, 26, 763
DOI: 10.1021/acs.orglett.3c04307

Copper‐Catalyzed Borylative Methylation of Alkyl Iodides with CO as the C1 Source: Advantaged by Faster Reaction of CuH over CuBpin

Fu‐Peng Wu and Xiao‐Feng Wu

Angew Chem Int Ed, 2021, 60, 11730
DOI: 10.1002/anie.202102197

Palladium‐Catalyzed Four‐Component Carbonylation Reactions of Acetylene: Synthesis of β‐Perfluoroalkyl Acrylamides

Zhusong Cao, Qiang Wang, Helfried Neumann and Matthias Beller

Eur J Org Chem, 2024, 27
DOI: 10.1002/ejoc.202400888

Radical‐Mediated C−H Alkylation of Glycine Derivatives: A Straightforward Strategy for Diverse α‐Unnatural Amino Acids

Madala Hari Babu and Jaehoon Sim

Eur J Org Chem, 2022, 2022
DOI: 10.1002/ejoc.202200859

Emerging trends in CO carbonylation

Chang-Sheng Kuai, Yang Yuan and Xiao-Feng Wu

Chem, 2025, 11, 102503
DOI: 10.1016/j.chempr.2025.102503

Arylboronic Acid Catalyzed Dehydrative Mono-/Dialkylation Reactions of β-Ketoacids and Alcohols

Haipeng Hu, Xin Wu, Yuqian Qiu, Cuilin Wang, Wei Wang, Guizhou Yue, Hanguang Wang, Juhua Feng, Guangtu Wang, Hailiang Ni and Ping Zou

Org. Lett., 2022, 24, 832
DOI: 10.1021/acs.orglett.1c04050

Competition between One‐ and Two‐Electron Unimolecular Reactions of Late 3d‐Metal Complexes [(Me3SiCH2)nM]–(M = Fe, Co, Ni, and Cu; n = 2–4)

Torben Kühl, Lisa Hetzel, Christopher J. Stein and Konrad Koszinowski

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202500524

Transition-Metal-Catalyzed C(sp3)–C(sp3) Cross-Coupling to Construct All-Carbon Quaternary Carbon Centers

Qiao Zhang and Shou-Fei Zhu

Synthesis, 2025, 57, 1415
DOI: 10.1055/a-2441-2737

Ni-catalyzed cross-electrophile alkyl-alkyl coupling reactions

Li-Xu You, Lan Tian, Chun-Ling Guo, Shun-Xi Li, Yu-Cheng Liu, Yu-Long Li and Wei Shu

Sci. China Chem., 2025, 68, 3376
DOI: 10.1007/s11426-024-2438-x

Regioselective Carbon‐Halogen Bond Formation in the Reaction of Ag(III)N‐Confused Porphyrin Complex with HCl or HBr

Idrees Sumra, Majeed Irfan, Huowang He, Yihuan Zhang, Fei Hao, Jinhong Lin, Atsuhiro Osuka, Zhuo Zeng and Hua‐Wei Jiang

Eur J Org Chem, 2021, 2021, 4440
DOI: 10.1002/ejoc.202100777

Pd-Catalyzed γ-Acetoxylation of Alkylamides: Structural Influence of Directing Groups

Peng-Yu Liu, Shi-Chen Zhao, Ming-Yuan Zhang, Lijuan Song, Caiping Wang, Fang Yu, Qingtao Meng, Zhiqiang Zhang and Yu-Peng He

J. Org. Chem., 2022, 87, 6378
DOI: 10.1021/acs.joc.2c00085

Enantioselective Synthesis of α‐Hydroxy Allyl Ketones via BINAP‐CuH‐Catalyzed Hydroacylation

Sundaram Maurya, N. Navaneetha, Prativa Behera, Jagadeesh Babu Nanubolu, Lisa Roy and Rambabu Chegondi

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202420106

SET or TET? Iron-catalyzed aminocarbonylation of unactivated alkyl halides with amines, amides, and indoles via a substrate dependent mechanism

Han-Jun Ai, Fengqian Zhao and Xiao-Feng Wu

Chinese Journal of Catalysis, 2023, 47, 121
DOI: 10.1016/S1872-2067(22)64208-6

A Modular Dual‐Catalytic Aryl‐Chlorination of Alkenes

Bo Li, Ala Bunescu, Daniel Drazen, Katherine Rolph, Jean Michalland and Matthew J. Gaunt

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202405939

A General Copper Catalytic System for Suzuki–Miyaura Cross-Coupling of Unactivated Secondary and Primary Alkyl Halides with Arylborons

Yonglei Zhou, Liping Qiu, Jian Li and Weilong Xie

J. Am. Chem. Soc., 2023, 145, 28146
DOI: 10.1021/jacs.3c10628

Harnessing Supported Gold Nanoparticle as a Single‐Electron Transfer Catalyst for Decarboxylative Cross‐Coupling

Hiroki Miura, Kaede Ameyama and Tetsuya Shishido

Adv Synth Catal, 2024, 366, 62
DOI: 10.1002/adsc.202300462

Ligand‐Controlled Regiodivergent Thiocarbonylation of Alkynes toward Linear and Branched α,β‐Unsaturated Thioesters

Han‐Jun Ai, Wangyang Lu and Xiao‐Feng Wu

Angew Chem Int Ed, 2021, 60, 17178
DOI: 10.1002/anie.202106079

Selective C–H Allylic Oxygenation of Cycloalkenes and Terpenoids Photosensitized by [Cu(Xantphos)(neoc)]BF4

Michael G. Kallitsakis, Dimitra K. Gioftsidou, Marina A. Tzani, Panagiotis A. Angaridis, Michael A. Terzidis and Ioannis N. Lykakis

J. Org. Chem., 2021, 86, 13503
DOI: 10.1021/acs.joc.1c01591

Transition-Metal-Catalyzed Transformations for the Synthesis of Marine Drugs

Lucía G. Parte, Sergio Fernández, Eva Sandonís, Javier Guerra and Enol López

Marine Drugs, 2024, 22, 253
DOI: 10.3390/md22060253

ZrO2 Supported Cu Nanoparticles for Sonogashira and Ullmann Coupling Reactions Under Palladium-Free Conditions

Seema P. Patil, Archana S. Rajmane, Sanjay N. Jadhav, Vijaya S. Rajmane, Chandrashekhar V. Rode and Arjun S. Kumbhar

Catal Lett, 2024, 154, 3078
DOI: 10.1007/s10562-023-04513-w

Dinuclear Copper(II) Complexes with N,O Donor Ligands: Partial Ligand Hydrolysis and Alcohol Oxidation Catalysis

Arpita Barma, Aradhita Bhattacharjee and Partha Roy

Eur J Inorg Chem, 2021, 2021, 2284
DOI: 10.1002/ejic.202100263

Room-Temperature Amination of Chloroheteroarenes in Water by a Recyclable Copper(II)-Phosphaadamantanium Sulfonate System

Udaysinh Parmar, Dipesh Somvanshi, Santosh Kori, Aman A. Desai, Rambabu Dandela, Dilip K. Maity and Anant R. Kapdi

J. Org. Chem., 2021, 86, 8900
DOI: 10.1021/acs.joc.1c00845

Modular and Diverse Synthesis of Acrylamides by Palladium‐Catalyzed Hydroaminocarbonylation of Acetylene

Zhusong Cao, Qiang Wang, Helfried Neumann and Matthias Beller

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202410597

A General Light‐Driven Organocatalytic Platform for the Activation of Inert Substrates

Shuo Wu, Florian Schiel and Paolo Melchiorre

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202306364

Catalytic Chemo-, Regio-, Diastereo-, and Enantioselective Bromochlorination of Unsaturated Systems Enabled by Lewis Base-Controlled Chloride Release

Alexandra E. Lubaev, Manjula D. Rathnayake, Favour Eze and Liela Bayeh-Romero

J. Am. Chem. Soc., 2022, 144, 13294
DOI: 10.1021/jacs.2c04588

Control of the Regioselectivity of Alkyne Hydrostannylation by Tuning the Metal Pair of Heterobimetallic Catalysts: A Theoretical Study

JinHui Mi, Suhong Huo, Yanli Zeng, Lingpeng Meng and Xiaoyan Li

Organometallics, 2021, 40, 654
DOI: 10.1021/acs.organomet.0c00721

Transmetalation Reactions Triggered by Electron Transfer between Organocopper Complexes

Olmo Lozano-Lavilla, Pablo Gómez-Orellana, Agustí Lledós and Juan A. Casares

Inorg. Chem., 2021, 60, 11633
DOI: 10.1021/acs.inorgchem.1c01595

Recent Advances in Copper‐Catalyzed Oxidative Cyclization Reactions

Cai Zhang

Asian J Org Chem, 2025, 14
DOI: 10.1002/ajoc.202400529

Regiodivergent Carbonylation of Alkenes: Selective Palladium‐Catalyzed Synthesis of Linear and Branched Selenoesters

Zhusong Cao, Qiang Wang, Helfried Neumann and Matthias Beller

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202313714

Copper-Catalyzed Synthesis of Coumarins. A Mini-Review

Renato Dalpozzo and Raffaella Mancuso

Catalysts, 2021, 11, 1382
DOI: 10.3390/catal11111382

New Cu (I) complexes as catalyst for “click” reaction: An experimental and computational study

Khodayar Gholivand, Mohammad Faraghi, Rahime Eshagi Malekshah, Mohammadreza Jafari, Ali Reza Akbarzadeh, Reza Latifi, Farzaneh Fadaei‐Tirani, Nasrin Fallah and Kaveh Farshadfar

Applied Organom Chemis, 2023, 37
DOI: 10.1002/aoc.6924

DFT Study on the Mechanisms of Iron-Catalyzed Ortho C–H Homoallylation of Aromatic Ketones with Methylenecyclopropanes

Lin Zheng, Xin Wan and Qinghua Ren

Organometallics, 2023, 42, 632
DOI: 10.1021/acs.organomet.2c00110

Crystal structure and Hirshfeld surface analysis of 5,7-diphenyl-1,2,3,5,6,7-hexahydroimidazo[1,2-a]pyridine-6,6,8-tricarbonitrile methanol monosolvate

Farid N. Naghiyev, Gunay Z. Mammadova, Ali N. Khalilov, Zeliha Atioğlu, Mehmet Akkurt, Anzurat A. Akobirshoeva and İbrahim G. Mamedov

Acta Crystallogr E Cryst Commun, 2021, 77, 600
DOI: 10.1107/S2056989021004655

Co(II)‐Catalyzed Oxidation of N,N‐Dimethylaminoethanol: An Efficient Synthesis of Unsymmetrical (2,4‐) and Symmetrical (2,6‐) Diarylpyridines through Annulation of Aromatic Ketones with a Nitrogen Source

Zemin Qin, Ruiqin Zhang, Yongmin Ma and Fanzhu Li

Asian J Org Chem, 2021, 10, 2246
DOI: 10.1002/ajoc.202100353

Hydrochlorination of Alkenes with Hydrochloric Acid

Arnaud Olivier and Daniel S. Müller

Org. Process Res. Dev., 2024, 28, 305
DOI: 10.1021/acs.oprd.3c00418

Oxidative Substitution of Organocopper(II) by a Carbon-Centered Radical

Yuecheng Weng, Yuxuan Jin, Jian Wu, Xuebing Leng, Xiaobing Lou, Fushan Geng, Bingwen Hu, Botao Wu and Qilong Shen

J. Am. Chem. Soc., 2024, 146, 23555
DOI: 10.1021/jacs.4c07552

In-situ formation of nanoparticles from a sulfur-ligated palladacycle: Catalytic performance in Suzuki-Miyaura and Sonogashira reactions

Jolly Kaushal, Sain Singh and Pramod Kumar

Inorganic Chemistry Communications, 2025, 180, 114911
DOI: 10.1016/j.inoche.2025.114911

One‐Step Synthesis of Acylboron Compounds via Copper‐Catalyzed Carbonylative Borylation of Alkyl Halides**

Li‐Jie Cheng, Siling Zhao and Neal P. Mankad

Angewandte Chemie, 2021, 133, 2122
DOI: 10.1002/ange.202012373

C–N cross-coupling organic transformations catalyzed via copper oxide nanoparticles: A review (2016-present)

Prensha Arora, Parveen Kumar, Vijesh Tomar, Mika Sillanpää, Raj Kumar Joshi and Meena Nemiwal

Inorganic Chemistry Communications, 2022, 145, 109982
DOI: 10.1016/j.inoche.2022.109982

Recent Advances in Photochemical Asymmetric Three‐Component Reactions

Haichao Huang, Yu‐Mei Lin and Lei Gong

The Chemical Record, 2023, 23
DOI: 10.1002/tcr.202300275

Copper PN(H)N Complexes: Synthesis of Pincer and Dinuclear Architectures and Base‐Free C (sp3)‐H Amidation Catalyzed by the Dinuclear Complex

Gazal Sabharwal, Khilesh C. Dwivedi and Maravanji S. Balakrishna

Applied Organom Chemis, 2025, 39
DOI: 10.1002/aoc.70322

Recent advances in nickel-catalyzed reductive hydroalkylation and hydroarylation of electronically unbiased alkenes

Xiao-Xu Wang, Xi Lu, Yan Li, Jia-Wang Wang and Yao Fu

Sci. China Chem., 2020, 63, 1586
DOI: 10.1007/s11426-020-9838-x

Photoinduced Copper-Catalyzed Asymmetric C—O Cross-Coupling

Huan Zhou and Xin-Yuan Liu

Chinese Journal of Organic Chemistry, 2021, 41, 4510
DOI: 10.6023/cjoc202100078

CuI in biorenewable basic medium: Three novel and low E-factor Suzuki-Miyaura cross-coupling reactions

Jangam Lakshmidevi, Bandameeda Ramesh Naidu and Katta Venkateswarlu

Molecular Catalysis, 2022, 522, 112237
DOI: 10.1016/j.mcat.2022.112237

Regio- and Stereoselective Installation of Bromide onto Vinyl Sulfonyl Fluorides: Construction of a Class of Versatile Sulfur Fluoride Exchange Hubs

Xu Zhang, Wan-Yin Fang and Hua-Li Qin

Org. Lett., 2022, 24, 4046
DOI: 10.1021/acs.orglett.2c01509

Asymmetric Intermolecular Iodinative Difunctionalization of Allylic Sulfonamides Enabled by Organosulfide Catalysis: Modular Entry to Iodinated Chiral Molecules

Lihao Liao, Xinru Xu, Jieying Ji and Xiaodan Zhao

J. Am. Chem. Soc., 2022, 144, 16490
DOI: 10.1021/jacs.2c05668

Merging Photocatalytic Doubly‐Decarboxylative Csp2−Csp2 Cross‐Coupling for Stereo‐Selective (E)‐α,β‐Unsaturated Ketones Synthesis

Subal Mondal, Siba P. Midya, Soumya Mondal, Suman Das and Pradyut Ghosh

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202303337

Copper-catalysed amination of alkyl iodides enabled by halogen-atom transfer

Bartosz Górski, Anne-Laure Barthelemy, James J. Douglas, Fabio Juliá and Daniele Leonori

Nat Catal, 2021, 4, 623
DOI: 10.1038/s41929-021-00652-8

Tandem Copper(I)‐Catalyzed N‐Arylation–1,4‐Conjugate Addition to Access Tetrahydroacridinones

Jyoti M. Honnanayakanavar, Purna Chandra Behera and Surisetti Suresh

Adv Synth Catal, 2022, 364, 4043
DOI: 10.1002/adsc.202200877

Nickel-Catalyzed Enantioselective Electrochemical Reductive Cross-Coupling of Aryl Aziridines with Alkenyl Bromides

Xia Hu, Iván Cheng-Sánchez, Sergio Cuesta-Galisteo and Cristina Nevado

J. Am. Chem. Soc., 2023, 145, 6270
DOI: 10.1021/jacs.2c12869

CuNPs@Al2O3-cellulose composite for the ligand-free Suzuki cross-coupling reactions in batch and continuous flow process

Seema Patil, Archana Rajmane, Sanjay Jadhav, Chandrashekhar Rode and Arjun Kumbhar

Journal of Organometallic Chemistry, 2024, 1004, 122954
DOI: 10.1016/j.jorganchem.2023.122954

Photoinduced copper-catalyzed dual decarboxylative coupling of α,β-unsaturated carboxylic acids with redox-active esters

Xiao-Yu Lu, Ang Gao, Qi-Le Liu and Ze-Jie Xia

Tetrahedron, 2021, 92, 132259
DOI: 10.1016/j.tet.2021.132259

Regiodivergent Carbonylation of Alkenes: Selective Palladium‐Catalyzed Synthesis of Linear and Branched Selenoesters

Zhusong Cao, Qiang Wang, Helfried Neumann and Matthias Beller

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202313714

Overcoming Copper Reduction Limitation in Asymmetric Substitution: Aryl-Radical-Enabled Enantioconvergent Cyanation of Alkyl Iodides

Su Chen, Decai Ding, Lingfeng Yin, Xiao Wang, Jeanette A. Krause and Wei Liu

J. Am. Chem. Soc., 2024, 146, 31982
DOI: 10.1021/jacs.4c11888

One‐Step Synthesis of Acylboron Compounds via Copper‐Catalyzed Carbonylative Borylation of Alkyl Halides**

Li‐Jie Cheng, Siling Zhao and Neal P. Mankad

Angew Chem Int Ed, 2021, 60, 2094
DOI: 10.1002/anie.202012373

A Modular Dual‐Catalytic Aryl‐Chlorination of Alkenes

Bo Li, Ala Bunescu, Daniel Drazen, Katherine Rolph, Jean Michalland and Matthew J. Gaunt

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202405939

Catalyst- and Additive-Free C(sp3)–H Functionalization of (Thio)barbituric AcidsviaC-5 Dehydrogenative Aza-Coupling Under Ambient Conditions

Goutam Brahmachari, Anindita Bhowmick and Indrajit Karmakar

ACS Omega, 2022, 7, 30051
DOI: 10.1021/acsomega.2c03073

Highly efficient synthesis of arylsulfide derivatives from coupling reaction of aryl titanium reagents with N-aryl thiosuccinimides catalyzed by copper under ligand-free conditions

Zhi-Hao Zhang, Jia-Xia Pu, Xiao-Ying Jia, Jin-Song Hou, Li-Rong Han, Chuan Wu and Qing-Han Li

Journal of Organometallic Chemistry, 2024, 1014, 123192
DOI: 10.1016/j.jorganchem.2024.123192

Solvent‐Dependent C(sp3)−CF3 Reductive Elimination from Neutral Four‐Coordinate Cu(III) Complexes

Yuecheng Weng, Deng Pan, Jian Wu, Xuebing Leng, Xiao‐Song Xue and Qilong Shen

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202403620

Copper‐Catalyzed Difluoromethylation of Alkyl Iodides Enabled by Aryl Radical Activation of Carbon–Iodine Bonds

Aijie Cai, Wenhao Yan, Chao Wang and Wei Liu

Angew Chem Int Ed, 2021, 60, 27070
DOI: 10.1002/anie.202111993

Up-Scale Synthesis of p-(CH2═CH)C6H4CH2CH2CH2Cl and p-ClC6H4SiR3 by CuCN-Catalyzed Coupling Reactions of Grignard Reagents with Organic Halides

Ju Yong Park, Ji Hyeong Ko, Hyun Ju Lee, Jun Hyeong Park, Junseong Lee, Seokpil Sa, Eun Ji Shin and Bun Yeoul Lee

ACS Omega, 2022, 7, 46849
DOI: 10.1021/acsomega.2c05951

Uncovering a CF3 Effect on X‐ray Absorption Energies of [Cu(CF3)4]− and Related Copper Compounds by Using Resonant Diffraction Anomalous Fine Structure (DAFS) Measurements**

Pinar Alayoglu, Tieyan Chang, Connly Yan, Yu‐Sheng Chen and Neal P. Mankad

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202313744

Strategies and Mechanisms of First-Row Transition Metal-Regulated Radical C–H Functionalization

Xinghua Wang, Jing He, Ya-Nan Wang, Zhenyan Zhao, Kui Jiang, Wei Yang, Tao Zhang, Shiqi Jia, Kangbao Zhong, Linbin Niu and Yu Lan

Chem. Rev., 2024, 124, 10192
DOI: 10.1021/acs.chemrev.4c00188

Switchable Direct Oxygenative Arylation of C(sp3)–H Bonds via Electrophotocatalysis

Yan Zhang, Xiang Sun, Ji-Hu Su, Tong Li, Chengbin Du, Kuiliang Li, Qi Sun, Zhenggen Zha and Zhiyong Wang

Org. Lett., 2023, 25, 5067
DOI: 10.1021/acs.orglett.3c01751

Copper‐Catalyzed Difluoromethylation of Alkyl Iodides Enabled by Aryl Radical Activation of Carbon–Iodine Bonds

Aijie Cai, Wenhao Yan, Chao Wang and Wei Liu

Angewandte Chemie, 2021, 133, 27276
DOI: 10.1002/ange.202111993

Revitalizing mitochondrial function and empowering spinal cord recovery using copper-catalyzed Pdots

Bao-Feng Zhao, Fan Wang, Jia-Chen Sun, Jin-Peng Gao, Li-Juan Zhao, Zhao-Liang Shen, Zhi-Peng Li, Yi-Xuan Wang, Yuan Wang, Dan Li and Xi-Fan Mei

Chemical Engineering Journal, 2024, 481, 148264
DOI: 10.1016/j.cej.2023.148264

Pd/GF-Phos-Catalyzed Asymmetric Three-Component Coupling Reaction to Access Chiral Diarylmethyl Alkynes

Guofeng Zhao, Yi Wu, Hai-Hong Wu, Junfeng Yang and Junliang Zhang

J. Am. Chem. Soc., 2021, 143, 17983
DOI: 10.1021/jacs.1c09742

Perimidine‐2‐chalcogenone Ligand‐Supported Palladium(II) Complex: A Potent Catalyst in Suzuki–Miyuara Cross‐Coupling Reaction and Nitroarene Reduction

Priyanka Velmurugan and Tapas Ghatak

ChemistrySelect, 2025, 10
DOI: 10.1002/slct.202405081

Copper(I)‐Catalyzed Acid‐Controlled Divergent Radical Cyclization of 1,6‐Enynes to Access 1‐Indanones and 1H‐Cyclopropa[b] Naphthalene‐2,7‐diones

Elmira Jamshidi, Saideh Rajai‐Daryasarei, Robert Stranger, Alireza Ariafard, Frank Rominger and Saeed Balalaie

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202501015

From Waste to Green Applications: The Use of Recovered Gold and Palladium in Catalysis

Sean McCarthy, Alvin Lee Wei Jie, D. Christopher Braddock, Angela Serpe and James D. E. T. Wilton-Ely

Molecules, 2021, 26, 5217
DOI: 10.3390/molecules26175217

Synthesis, characterization and catalytic study of Schiff base copper(I) complexes for C C and C N coupling reactions

Ashwini S. Patil and Sanjay S. Chavan

Inorganica Chimica Acta, 2025, 575, 122420
DOI: 10.1016/j.ica.2024.122420

Highly efficient synthesis of di-substituted allenes via copper-catalyzed SN2′- substitution reaction of organotitanium reagents with propargyl bromides

Chuan Wu, Li-Rong Han, Jin-Song Hou and Qing-Han Li

Tetrahedron, 2024, 168, 134345
DOI: 10.1016/j.tet.2024.134345

Facile Construction of Quaternary Carbon Centers via Dinuclear Titanium(III)‐Catalyzed Reductive Coupling of Tertiary Chlorides and Activated Olefins

Wanjiao Chen, Huaxi Sun, Jie Jiang and Yong‐Qiang Zhang

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202400829

Recent advances in the synthesis of 1,1-diarylalkanes by transition-metal catalysis

Md. Belal, Zheqi Li, Xiuqiang Lu and Guoyin Yin

Sci. China Chem., 2021, 64, 513
DOI: 10.1007/s11426-020-9910-2

Copper-Catalyzed Carbonylative Coupling of Alkyl Halides

Li-Jie Cheng and Neal P. Mankad

Acc. Chem. Res., 2021, 54, 2261
DOI: 10.1021/acs.accounts.1c00115

Copper-Catalyzed Oxidative C–H Annulation of Quinolines with Dichloroethane toward Benzoquinoliziniums Using an In Situ Activation Strategy

Jinwen Ji, Linfeng Jiang, Zhishuo Wang, Zhengyang Bin, Jingsong You and Yudong Yang

Org. Lett., 2022, 24, 6256
DOI: 10.1021/acs.orglett.2c02342

Sustainable strategies of C–N bond formation via Ullmann coupling employing earth abundant copper catalyst

Gauravi Yashwantrao and Satyajit Saha

Tetrahedron, 2021, 97, 132406
DOI: 10.1016/j.tet.2021.132406

Deaminative Arylation and Alkenyaltion of Aliphatic Tertiary Amines with Aryl and Alkenylboronic Acids via Nitrogen Ylides

Jianke Su, Chengbo Li, Xinyuan Hu, Yu Guo and Qiuling Song

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202212740

Mechanistic insights and computational design of Cu/M bimetallic synergistic catalysts for Suzuki-Miyaura coupling of arylboronic esters with alkyl halides

Xueju Wu, Yanli Zeng, Lingpeng Meng and Xiaoyan Li

Molecular Catalysis, 2023, 541, 113098
DOI: 10.1016/j.mcat.2023.113098

A General Light‐Driven Organocatalytic Platform for the Activation of Inert Substrates

Shuo Wu, Florian Schiel and Paolo Melchiorre

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202306364

Reduction system “vitamin C/glycerol” promoted copper(II)‐catalyzed N‐arylation

Fengtian Wu, Fangming Yan, Ling Wu, Caihong Zhang, Rong Zeng, Yijia Sun, Xiuping Liu, Chunna Cui and Peng Wang

Applied Organom Chemis, 2022, 36
DOI: 10.1002/aoc.6618

Single Electron Transfer-Induced Redox Processes Involving N-(Acyloxy)phthalimides

Sushanta Kumar Parida, Tanumoy Mandal, Sanju Das, Sudhir Kumar Hota, Suman De Sarkar and Sandip Murarka

ACS Catal., 2021, 11, 1640
DOI: 10.1021/acscatal.0c04756

A Radical Strategy for the Alkylation of Amides with Alkyl Halides by Merging Boryl Radical-Mediated Halogen-Atom Transfer and Copper Catalysis

Zhenhua Zhang, Lorenzo Poletti and Daniele Leonori

J. Am. Chem. Soc., 2024, 146, 22424
DOI: 10.1021/jacs.4c05487

MIA-Directed 2-Pyridione-Enabled Selective Ortho-C–H Arylation of Phenylalanine: A Mechanistic Study

Peng-Peng Niu, Peng-Yu Liu, Yue-Ning Meng, Fang Yu and Yu-Peng He

J. Org. Chem., 2021, 86, 3096
DOI: 10.1021/acs.joc.0c02872

Radical Sorting Catalysis via Bimolecular Homolytic Substitution (SH2): Opportunities for C(sp3)–C(sp3) Cross-Coupling Reactions

Iona M. McWhinnie, Robert T. Martin, Jiaxin Xie, Ruizhe Chen, Cesar N. Prieto Kullmer and David W. C. MacMillan

J. Am. Chem. Soc., 2025, 147, 23351
DOI: 10.1021/jacs.5c07367

Modular and Facile Access to Chiral α-Aryl Phosphates via Dual Nickel- and Photoredox-Catalyzed Reductive Cross-Coupling

Hepan Wang, Purui Zheng, Xiaoqiang Wu, Yuqiang Li and Tao XU

J. Am. Chem. Soc., 2022, 144, 3989
DOI: 10.1021/jacs.1c12424

Copper Promoted Synthesis of Tetraalkylgermanes from Germanium Electrophiles and Alkyl Bromides※

Qinghao Xu, Lipu Wei, Zhen Zhang and Bin Xiao

Acta Chimica Sinica, 2022, 80, 428
DOI: 10.6023/A21120608

Konkurrenz zwischen unimolekularen Ein‐ und Zwei‐Elektron‐Reaktionen später 3d‐Metallkomplexe [(Me3SiCH2)nM]– (M = Fe, Co, Ni, Cu; n = 2 – 4)

Torben Kühl, Lisa Hetzel, Christopher J. Stein and Konrad Koszinowski

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202500524

Uncovering a CF3 Effect on X‐ray Absorption Energies of [Cu(CF3)4]− and Related Copper Compounds by Using Resonant Diffraction Anomalous Fine Structure (DAFS) Measurements**

Pinar Alayoglu, Tieyan Chang, Connly Yan, Yu‐Sheng Chen and Neal P. Mankad

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202313744

Formal Transesterification Reaction of But-3-enyl Esters Enabled by a Synergistic Nickel/Zinc Relay

Bingwei Zhou, Long Cai, Zhou Jin and Yuanyuan Hu

Org. Lett., 2025, 27, 1118
DOI: 10.1021/acs.orglett.4c04515

Photoinduced copper-catalysed asymmetric amidation via ligand cooperativity

Caiyou Chen, Jonas C. Peters and Gregory C. Fu

Nature, 2021, 596, 250
DOI: 10.1038/s41586-021-03730-w

Theoretical Study on Photo‐Induced Copper Autoredox Construction of Chiral Amines

Dongmei Tian, Hui Li, Yan Su and Yang Ji

Eur J Inorg Chem, 2024, 27
DOI: 10.1002/ejic.202400168

Copper-catalysed dynamic kinetic asymmetric C−O cross-coupling to access chiral aryl oxime ethers and diaryl ethers

Mei-Ru Zhang, Hao-Ran Wang, Hui-Mei Shan, Long-Long Xi, Chuan-Jun Lu, Xiao-Man Du, Che Sun, Li-Ping Xu and Ren-Rong Liu

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-57804-8

Ligand-Free, Copper-Catalyzed Coupling Reaction of Aryl Aluminum Reagents with N-Aryl Thiosuccinimides

Zhihao Zhang, Xiaoying Jia, Jiaxia Pu, Lirong Han, Jinsong Hou and Qinghan Li

LOC, 2024, 21, 1055
DOI: 10.2174/0115701786298931240408083720

Recent Advances in C(sp3)–C(sp3) Cross-Coupling Chemistry: A Dominant Performance of Nickel Catalysts

Ramagonolla Kranthikumar

Organometallics, 2022, 41, 667
DOI: 10.1021/acs.organomet.2c00032

Copper-Catalyzed C–C Cross-Couplings of Tertiary Alkyl Halides with Anilines Enabled by Cyclopropenimine-Based Ligands

Serim Choi, Yongseok Choi, Yongjae Kim, Jaehoo Lee and Sarah Yunmi Lee

J. Am. Chem. Soc., 2023
DOI: 10.1021/jacs.3c09369

Mechanistic Insights into Oxazolone Synthesis by Bimetallic Au–Pd-Catalyzed Catalysis and Catalyst Design: DFT Investigations

Xueju Wu, Yuanyuan Sun, Yanli Zeng and Xiaoyan Li

J. Org. Chem., 2023, 88, 10693
DOI: 10.1021/acs.joc.3c00751

Computation Study on Copper-Catalyzed Aerobic Intramolecular Aminooxygenative C═C Bond Cleavage to Imides: Different Roles of Mononuclear and Dinuclear Copper Complexes

Yu Li, Guo-Cui Ji, Chen Chao, Siwei Bi and Yuan-Ye Jiang

ACS Catal., 2023, 13, 3815
DOI: 10.1021/acscatal.2c06040

Cobalt Coordination Polymers Offering Hydrogen Bonding Cavities as Efficient Catalysts for Coupling Reactions

Sanya Pachisia, Hina Goyal, Aashish, Gulshan Kumar and Rajeev Gupta

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202301123

Copper-Catalyzed Carbonylation Reactions: A Personal Account

Hui-Qing Geng and Xiao-Feng Wu

Synthesis, 2024, 56, 2595
DOI: 10.1055/s-0042-1751542

Borylation of Stable C(sp3)–O Bonds of Alkyl Esters over Supported Au Catalysts

Masafumi Doi, Hiroki Miura and Tetsuya Shishido

Org. Lett., 2024, 26, 2902
DOI: 10.1021/acs.orglett.4c00225

Copper-Mediated Decarboxylative Coupling between Arylacetic Acids and 1,3-Dicarbonyl Compounds

Yinrong Wu, Kangmei Wen, Jiewen Chen, Jie Shi, Xingang Yao and Xiaodong Tang

Org. Lett., 2021, 23, 7878
DOI: 10.1021/acs.orglett.1c02897

Organocatalytic Electrosynthesis of Cinnolines through Cascade Radical Cyclization and Migration

Chen Cai, Yi Lu, Chengcheng Yuan, Zheng Fang, Xiaobing Yang, Chengkou Liu and Kai Guo

ACS Sustainable Chem. Eng., 2021, 9, 16989
DOI: 10.1021/acssuschemeng.1c05810

Heterogeneous Bifunctional Ni Single-Atom Catalyst on Carbon Nitride for Selective C(sp2)–C(sp3) Coupling

Minjoon Kwak, Youngran Seo, Junhyeok Heo, Jinsol Bok, Sumin Kim, Hyunwoo Choi, Hyeonjeong Son, Ahyun Jeon, Byoung-Hoon Lee, Keunhong Jeong, Taeghwan Hyeon and Dongwon Yoo

ACS Nano, 2025, 19, 29627
DOI: 10.1021/acsnano.5c08946

Transition-Metal-Catalyzed Cross-Coupling Reactions of Grignard Reagents

Kinga Juhász, Ágnes Magyar and Zoltán Hell

Synthesis, 2021, 53, 983
DOI: 10.1055/s-0040-1705986