Recent developments in the synthesis of bio-inspired iron porphyrins for small molecule activation

Sk Amanullah, Paramita Saha and Abhishek Dey

Chem. Commun., 2022, 58, 5808
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Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide

Zuozhong Liang, Hong-Yan Wang, Haoquan Zheng, Wei Zhang and Rui Cao

Chem. Soc. Rev., 2021, 50, 2540
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Effects of tuning the structural symmetry of cobalt porphyrin on electrocatalytic oxygen reduction reactions

Yuqin Wei, Yongdi Liang, Qijie Wu, Zhaoli Xue, Lei Feng, Jianming Zhang and Long Zhao

Dalton Trans., 2023, 52, 14573
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Catalytic reduction of oxygen to water by non-heme iron complexes: exploring the effect of the secondary coordination sphere proton exchanging site

Aakash Santra, Avijit Das, Simarjeet Kaur, Priya Jain, Pravin P. Ingole and Sayantan Paria

Chem. Sci., 2024, 15, 4095
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In situ uncovering the catalytic cycle of electrochemical and chemical oxygen reduction mediated by an iron porphyrin

Xianhao Zhang, Jirui Zhan, Haonan Qin, Jintao Deng, Junjie Liu, Meixian Li, Rui Cao and Yuanhua Shao

Chem. Sci., 2025, 16, 5512
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Peripheral nucleic bases boost H2production by synthetic molecular catalysts in acidic water

Srewashi Das, Chandan Das, Naseer Ahmad Shah, Santanu Ghorai, Piyali Majumder and Arnab Dutta

Chem. Commun., 2023, 59, 7243
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Mn(ii)-aqua-decavanadate: a bifunctional homogeneous electrocatalyst for the hydrogen evolution reaction and the oxygen reduction reaction

Debu Jana, Rachapudi Phebe Florance, Rabin Kumar Poria and Samar K. Das

Inorg. Chem. Front., 2025, 12, 8363
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Iron porphyrin with appended guanidyl group for significantly improved electrocatalytic carbon dioxide reduction activity and selectivity in aqueous solutions

Hongbo Guo, Zuozhong Liang, Kai Guo, Haitao Lei, Yabo Wang, Wei Zhang and Rui Cao

Chinese Journal of Catalysis, 2022, 43, 3089
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Enhanced cobalt porphyrin-catalytic oxygen reduction reactions by introducing benzoyloxy substitutes

Yuqin Wei, Long Zhao, Yongdi Liang, Mingcai Yuan, Qijie Wu, Zhaoli Xue, Xinping Qiu and Jianming Zhang

Chemical Engineering Journal, 2023, 476, 146575
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Steric Effects on the Oxygen Reduction Reaction with Cobalt Porphyrin Atropisomers

Tao Liu, Haonan Qin, Yuhan Xu, Xinyang Peng, Wei Zhang and Rui Cao

ACS Catal., 2024, 14, 6644
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A Single Iron Porphyrin Shows pH Dependent Switch between “Push” and “Pull” Effects in Electrochemical Oxygen Reduction

Sudipta Mukherjee, Abhijit Nayek, Sarmistha Bhunia, Somdatta Ghosh Dey and Abhishek Dey

Inorg. Chem., 2020, 59, 14564
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Crucial Roles of a Pendant Imidazole Ligand of a Cobalt Porphyrin Complex in the Stoichiometric and Catalytic Reduction of Dioxygen

Jindou Yang, Ping Li, Xialiang Li, Lisi Xie, Ni Wang, Haitao Lei, Chaochao Zhang, Wei Zhang, Yong‐Min Lee, Weiqiang Zhang, Rui Cao, Shunichi Fukuzumi and Wonwoo Nam

Angew Chem Int Ed, 2022, 61
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Meso‐substituted Metalloporphyrin‐based Composites for Electrocatalytic Oxygen Reduction Reactions

Rui Yuan, Stennard Leetroy George, Jun Chen, Qilong Wu, Xinping Qiu and Long Zhao

ChemNanoMat, 2023, 9
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Controlling Oxygen Reduction Selectivity through Steric Effects: Electrocatalytic Two‐Electron and Four‐Electron Oxygen Reduction with Cobalt Porphyrin Atropisomers

Bin Lv, Xialiang Li, Kai Guo, Jun Ma, Yanzhi Wang, Haitao Lei, Fang Wang, Xiaotong Jin, Qingxin Zhang, Wei Zhang, Ran Long, Yujie Xiong, Ulf‐Peter Apfel and Rui Cao

Angew Chem Int Ed, 2021, 60, 12742
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Controlling Oxygen Reduction Selectivity through Steric Effects: Electrocatalytic Two‐Electron and Four‐Electron Oxygen Reduction with Cobalt Porphyrin Atropisomers

Bin Lv, Xialiang Li, Kai Guo, Jun Ma, Yanzhi Wang, Haitao Lei, Fang Wang, Xiaotong Jin, Qingxin Zhang, Wei Zhang, Ran Long, Yujie Xiong, Ulf‐Peter Apfel and Rui Cao

Angewandte Chemie, 2021, 133, 12852
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Crucial Roles of a Pendant Imidazole Ligand of a Cobalt Porphyrin Complex in the Stoichiometric and Catalytic Reduction of Dioxygen

Jindou Yang, Ping Li, Xialiang Li, Lisi Xie, Ni Wang, Haitao Lei, Chaochao Zhang, Wei Zhang, Yong‐Min Lee, Weiqiang Zhang, Rui Cao, Shunichi Fukuzumi and Wonwoo Nam

Angewandte Chemie, 2022, 134
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Rational design of adenine appended synthetic cobalt catalysts via click reaction for electrocatalytic hydrogen production

Srewashi Das, Thinles Dolkar, Naseer Ahmad Shah, Sukanta Saha and Arnab Dutta

International Journal of Hydrogen Energy, 2024, 56, 582
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Controlled Modification of Axial Coordination for Transition‐Metal Single‐Atom Electrocatalyst

Xiangjian Liu, Yarong Liu, Wenxiu Yang, Xiao Feng and Bo Wang

Chemistry A European J, 2022, 28
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Second-Sphere Hydrogen-Bond Donors and Acceptors Affect the Rate and Selectivity of Electrochemical Oxygen Reduction by Iron Porphyrins Differently

Arnab Ghatak, Soumya Samanta, Abhijit Nayek, Sudipta Mukherjee, Somdatta Ghosh Dey and Abhishek Dey

Inorg. Chem., 2022, 61, 12931
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Breaking the Scaling Relationship for Oxygen Reduction Reaction Using Molecular Cobalt Complexes

Avijit Das, Aakash Santra, Ankita Kumari, Dibyajyoti Ghosh and Sayantan Paria

J. Am. Chem. Soc., 2025, 147, 6549
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Metal-Dependent Electrocatalytic Oxygen Reduction in Surface-Conjugated Macrocyclic Electrodes

Moumita Ghosh, Roman Ezhov, Sarah E. Braley, Yaroslav Losovyj, Gabriel Bury, Yulia N. Pushkar and Jeremy M. Smith

ACS Appl. Energy Mater., 2024, 7, 6717
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Design Strategies of Non‐Noble Metal‐Based Electrocatalysts for Two‐Electron Oxygen Reduction to Hydrogen Peroxide

Hui Zhao and Zhong‐Yong Yuan

ChemSusChem, 2021, 14, 1616
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Effect of Pendant Distal Residues on the Rate and Selectivity of Electrochemical Oxygen Reduction Reaction Catalyzed by Iron Porphyrin Complexes

Arnab Ghatak, Sarmistha Bhunia and Abhishek Dey

ACS Catal., 2020, 10, 13136
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Elucidation of Factors That Govern the 2e–/2H+ vs 4e–/4H+ Selectivity of Water Oxidation by a Cobalt Corrole

Biswajit Mondal, Samir Chattopadhyay, Subal Dey, Atif Mahammed, Kaustuv Mittra, Atanu Rana, Zeev Gross and Abhishek Dey

J. Am. Chem. Soc., 2020, 142, 21040
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Proton Relay Effects on Oxygen Reduction Reaction Catalyzed by Dinuclear Cobalt Polypyridyl Complexes with OH Groups on Bipyridine Ligands

Hiroaki Arima, Takashi Nakazono and Tohru Wada

Bulletin of the Chemical Society of Japan, 2022, 95, 1100
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Oxygen Reduction by Amide-Ligated Cobalt Complexes: Effect of Hydrogen Bond Acceptor

Zahra Aghaei, Adedamola A. Opalade, Victor W. Day and Timothy A. Jackson

Molecules, 2025, 30, 3274
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Electrocatalytic oxygen reduction reaction with metalloporphyrins

Tao Liu, Qingxin Zhang, Hongbo Guo, Zuozhong Liang and Rui Cao

Sci. Sin.-Chim, 2022, 52, 1306
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Immunosensing of neuron-specific enolase based on dual signal amplification strategy via electrocatalytic oxygen reduction by iron-porphyrin covalent organic framework

Huihui Liang, Ying Luo, Yawen Xiao, Jianhui Xiong, Rongfang Chen, Yonghai Song and Li Wang

Chemical Engineering Journal, 2023, 460, 141740
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Further Understanding the Roles of Solvent, Brønsted Acids, and Hydrogen Bonding in Iron Porphyrin-Mediated Carbon Dioxide Reduction

Bach Xuan Nguyen, Ana Sonea and Jeffrey J. Warren

Inorg. Chem., 2023, 62, 17602
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Silver nanostructure-modified graphite electrode for in-operando SERRS investigation of iron porphyrins during high-potential electrocatalysis

Samir Chattopadhyay, Soumya Samanta, Ankita Sarkar, Aishik Bhattacharya, Suman Patra and Abhishek Dey

The Journal of Chemical Physics, 2023, 158
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Bioinorganic Chemistry on Electrodes: Methods to Functional Modeling

Abhijit Nayek, Md Estak Ahmed, Soumya Samanta, Souvik Dinda, Suman Patra, Somdatta Ghosh Dey and Abhishek Dey

J. Am. Chem. Soc., 2022, 144, 8402
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A Minimalist Iron Porphyrin Which Can Catalyze Both Peroxidation and Oxygen Reduction Reaction

Souvik Dinda, Triparna Roy, Srijan Sengupta, Pritam Baidya and Abhishek Dey

JACS Au, 2025, 5, 6275
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Second Sphere Effects on Oxygen Reduction and Peroxide Activation by Mononuclear Iron Porphyrins and Related Systems

Sarmistha Bhunia, Arnab Ghatak and Abhishek Dey

Chem. Rev., 2022, 122, 12370
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Catalytic Four-Electron Reduction of Oxygen to Water by a Molecular Cobalt Complex Consisting of a Proton Exchanging Site at the Secondary Coordination Sphere

Avijit Das, Afsar Ali, Geetika Gupta, Aakash Santra, Priya Jain, Pravin P. Ingole, Satadal Paul and Sayantan Paria

ACS Catal., 2023, 13, 5285
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Oxygen reduction catalysis by [Cu(cyclen)Cl]Cl·H2O: The relationship of selectivity to proton in nonaqueous solution and aqueous solution

Yan Zhang, Xiao‐Fang Qi, Jie Yang, Hai‐Mei Luo and Shu‐Zhong Zhan

Applied Organom Chemis, 2024, 38
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Regulating Steric Effect of Cobalt Corroles for Promoted Oxygen Electrocatalysis

Yuhan Xu, Xiaotong Jin, Jieling Zhang, Haonan Qin, Benxing Mei, Tao Liu, Siyu Lei, Shen Li, Yongyi Bo, Xialiang Li and Rui Cao

ACS Catal., 2024, 14, 14350
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Amine Groups in the Second Sphere of Iron Porphyrins Allow for Higher and Selective 4e–/4H+ Oxygen Reduction Rates at Lower Overpotentials

Sarmistha Bhunia, Arnab Ghatak, Atanu Rana and Abhishek Dey

J. Am. Chem. Soc., 2023, 145, 3812
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Iron Porphyrin-Based Composites for Electrocatalytic Oxygen Reduction Reactions

Stennard Leetroy George, Linkai Zhao, Ziyi Wang, Zhaoli Xue and Long Zhao

Molecules, 2024, 29, 5655
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Recent Developments in Metalloporphyrin Electrocatalysts for Reduction of Small Molecules: Strategies for Managing Electron and Proton Transfer Reactions

Rui Zhang and Jeffrey J. Warren

ChemSusChem, 2021, 14, 293
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Improving Electrocatalytic Oxygen Reduction Activity and Selectivity with a Cobalt Corrole Appended with Multiple Positively Charged Proton Relay Sites

Jinxiu Han, Ni Wang, Xialiang Li, Wei Zhang and Rui Cao

J. Phys. Chem. C, 2021, 125, 24805
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A Survey of Reaction Energetics for Diverse Small Molecule Activation: Where Do Molecular Electrocatalysts Go From Here?

Ana Sonea and Jeffrey J. Warren

ChemCatChem, 2024, 16
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Controlling the Oxygen Reduction Selectivity of Asymmetric Cobalt Porphyrins by Using Local Electrostatic Interactions

Rui Zhang and Jeffrey J. Warren

J. Am. Chem. Soc., 2020, 142, 13426
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