Issue 4, 2024

Borataalkenes, boraalkenes, and the η2-B,C coordination mode in coordination chemistry and catalysis

Abstract

Borataalkenes and boraalkenes are the boron-containing isoelectronic analogues of alkenes and vinyl cations respectively. Compared with alkenes, the borataalkene and boraalkene ligand motifs in transition metal coordination chemistry are relatively underexplored. In this review, the synthesis of borataalkene and boraalkene complexes and other transition metal complexes featuring the η2-B,C coordination mode is described. The diversity of coordination modes and geometry in these complexes, and the spectroscopic and structural evidence supporting their assignments is disclosed as well as computational analysis of bonding. The applications of the borataalkene ligand motif in synthetic organic homogeneous catalysis, especially those involving geminal bis(pinacolatoboronates) and 1,4-azaborines, are discussed.

Graphical abstract: Borataalkenes, boraalkenes, and the η2-B,C coordination mode in coordination chemistry and catalysis

Article information

Article type
Review Article
Submitted
16 صفر 1445
First published
26 جمادى الثانية 1445

Chem. Soc. Rev., 2024,53, 1915-1935

Borataalkenes, boraalkenes, and the η2-B,C coordination mode in coordination chemistry and catalysis

M. Eaton, Y. Zhang and S. Liu, Chem. Soc. Rev., 2024, 53, 1915 DOI: 10.1039/D3CS00730H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements