Issue 9, 2024

Self-assembly of conformation-adaptive dihydrophenazine-based coordination cages

Abstract

In this study, we designed and synthesized three conformation-adaptive Pd2L4- and Pd3L6-type coordination cages based on three dihydrophenazine-based ligands with different lengths. Interestingly, the shorter ligands L1 and L2 self-assembled into Pd2L4-type coordination cages while the longer ligand L3 formed Pd3L6-type one, mainly driven by the anion template effect. All coordination cages were confirmed through single-crystal X-ray diffraction, and their structural conformations underwent great changes compared with those of their corresponding ligands. Moreover, the conformational changes also significantly affected their photophysical and electrochemical properties which were distinct from their parent ligands.

Graphical abstract: Self-assembly of conformation-adaptive dihydrophenazine-based coordination cages

Supplementary files

Article information

Article type
Communication
Submitted
15 ربيع الأول 1445
Accepted
27 جمادى الأولى 1445
First published
09 جمادى الثانية 1445

Chem. Commun., 2024,60, 1184-1187

Self-assembly of conformation-adaptive dihydrophenazine-based coordination cages

M. Wu, Q. Hong, M. Li, W. Jiang, B. Huang, S. Lu, H. Wang, H. Yang, X. Zhao and X. Shi, Chem. Commun., 2024, 60, 1184 DOI: 10.1039/D3CC04864K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements