Issue 86, 2022

Polymer networks of imine-crosslinked metal–organic cages: tuneable viscoelasticity and iodine adsorption

Abstract

The solution-state structure of an amine-functionalised Cu24L24 cage (MOP-15) is elucidated, enabling its direct covalent crosslinking into a series of highly tuneable organogels. These soft porous networks exhibit up to a ∼10-fold increase in capacity for iodine compared to the discrete cage precursor.

Graphical abstract: Polymer networks of imine-crosslinked metal–organic cages: tuneable viscoelasticity and iodine adsorption

Supplementary files

Article information

Article type
Communication
Submitted
12 صفر 1444
Accepted
09 ربيع الأول 1444
First published
10 ربيع الأول 1444

Chem. Commun., 2022,58, 12122-12125

Polymer networks of imine-crosslinked metal–organic cages: tuneable viscoelasticity and iodine adsorption

M. L. Schneider, J. A. Campbell, A. D. Slattery and W. M. Bloch, Chem. Commun., 2022, 58, 12122 DOI: 10.1039/D2CC04969D

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