Issue 9, 2020

A transmission-type triple grating spectrograph for improved laser scattering diagnostics of low-density plasmas used in chemical analysis

Abstract

A wide variety of plasma geometries and modalities have been utilized for chemical analysis to date, however, there is much left to be understood in terms of the underlying mechanisms. Plasma diagnostics have been used for many years to elucidate these mechanisms, with one of the most powerful techniques being laser scattering approaches. Laser scattering provides information about the energetic species distributions, in terms of kinetic energy and densities, which can provide invaluable insights into the fundamental processes of chemical analysis plasmas with minimal perturbation. Thomson scattering (TS) from free electrons is the most difficult to implement due to the extremely stringent instrumental requirements for discerning the signal from competing scatterers in low-density plasmas, such as those seen in analytical chemistry applications. Nonetheless, relatively few instruments have been developed to satisfy these stringent requirements. In this paper, the design and characterization of a transmission-type triple grating spectrograph (TGS), with high numerical aperture (0.25)/contrast (≤10−6 at 532 ± 0.5 nm)/stray light rejection (∼1.8 × 10−8 at 532 ± 22–32 nm) required for TS, will be presented. In addition, proof-of-principle measurements on glow discharges operated under typical optical emission spectroscopy (OES) conditions demonstrate the high light throughput and low limits-of-detection (∼109 cm−3 at ∼1 eV Te) afforded by the new instrument.

Graphical abstract: A transmission-type triple grating spectrograph for improved laser scattering diagnostics of low-density plasmas used in chemical analysis

Supplementary files

Article information

Article type
Paper
Submitted
03 رمضان 1441
Accepted
11 شوال 1441
First published
11 شوال 1441

J. Anal. At. Spectrom., 2020,35, 1932-1946

Author version available

A transmission-type triple grating spectrograph for improved laser scattering diagnostics of low-density plasmas used in chemical analysis

K. Finch, A. Hernandez, Y. She, S. Shi and G. Gamez, J. Anal. At. Spectrom., 2020, 35, 1932 DOI: 10.1039/D0JA00193G

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