Issue 7, 2019

Synthesis of a [20]phenacene dodeca-ester by controlled condensation of seven naphthalene-based building blocks

Abstract

Complementary protecting techniques for the Perkin reaction between arylacetic acids and arylglyoxylic acids efficiently allowed the multistep condensation of seven naphthalene fragments, linked by maleate bridges. Photocyclisation of this heptameric flexible precursor has led to a [20]phenacene dodeca-ester, the longest known phenacene to date.

Graphical abstract: Synthesis of a [20]phenacene dodeca-ester by controlled condensation of seven naphthalene-based building blocks

Supplementary files

Article information

Article type
Research Article
Submitted
19 جمادى الأولى 1440
Accepted
14 جمادى الثانية 1440
First published
15 جمادى الثانية 1440

Org. Chem. Front., 2019,6, 994-997

Synthesis of a [20]phenacene dodeca-ester by controlled condensation of seven naphthalene-based building blocks

G. Naulet, S. Huet-Exiga, H. Bock and F. Durola, Org. Chem. Front., 2019, 6, 994 DOI: 10.1039/C9QO00125E

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