Issue 43, 2018

Oriented external electric fields as mimics for probing the role of metal ions and ligands in the thermal gas-phase activation of methane

Abstract

In the course of combined computational and mass spectrometry-based mechanistic studies, recently we came across rather unusual, if not unprecedented, effects of transition-metal ions and ligands when simple metal oxides or carbides are subjected to thermal gas-phase reactions with methane. Interestingly, “Gedankenexperiments” demonstrate how these effects can be modeled using oriented external electric fields (OEEFs), thus expanding their predicted role as “smart reagents” (Shaik et al., Nat. Chem., 2016, 8, 1091), and further suggesting that the OEEFs may be used in controlling the adsorption/desorption behavior of methane as well as serving as a tool to explore mechanistic features.

Graphical abstract: Oriented external electric fields as mimics for probing the role of metal ions and ligands in the thermal gas-phase activation of methane

Article information

Article type
Frontier
Submitted
13 ذو القعدة 1439
Accepted
17 ذو الحجة 1439
First published
18 ذو الحجة 1439

Dalton Trans., 2018,47, 15271-15277

Oriented external electric fields as mimics for probing the role of metal ions and ligands in the thermal gas-phase activation of methane

C. Geng, J. Li, M. Schlangen, S. Shaik, X. Sun, N. Wang, T. Weiske, L. Yue, S. Zhou and H. Schwarz, Dalton Trans., 2018, 47, 15271 DOI: 10.1039/C8DT03048K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements