Issue 5, 2017

Synthesis of homoazafullerene [C59N(CH2)]R and azahomoazafullerene [C59N(NH)]R

Abstract

The selective insertion of a CH2 or NH group at the 5,6-junction on the C59N skeleton is achieved through the PCl5 induced reaction of a CH2OH or NHOH group on the cage to form [C59N(CH2)]R or [C59N(NH)]R, respectively. Spectroscopic data and single crystal X-ray diffraction structure analysis confirmed the 5,6-open homoazafullerene structure.

Graphical abstract: Synthesis of homoazafullerene [C59N(CH2)]R and azahomoazafullerene [C59N(NH)]R

Supplementary files

Article information

Article type
Research Article
Submitted
09 جمادى الأولى 1438
Accepted
18 جمادى الأولى 1438
First published
19 جمادى الأولى 1438

Org. Chem. Front., 2017,4, 750-754

Synthesis of homoazafullerene [C59N(CH2)]R and azahomoazafullerene [C59N(NH)]R

D. Xu, Y. Li, N. Lou and L. Gan, Org. Chem. Front., 2017, 4, 750 DOI: 10.1039/C7QO00098G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements