Issue 11, 2017

Metal–organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers

Abstract

We used poly-(3-sulfopropylmethacrylate) brushes as macromolecular 3D primers to promote heterogeneous nucleation and growth of archetypal ZIF-8 MOF thin films. The enhancement can be understood in terms of a high preconcentration of Zn2+ ions in the polymer brush; this leads to a rapid increase of nucleation sites in the primer.

Graphical abstract: Metal–organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers

Supplementary files

Article information

Article type
Research Article
Submitted
28 شعبان 1438
Accepted
27 رمضان 1438
First published
06 شوال 1438

Mater. Chem. Front., 2017,1, 2256-2260

Metal–organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers

M. Rafti, J. A. Allegretto, G. M. Segovia, J. S. Tuninetti, J. M. Giussi, E. Bindini and O. Azzaroni, Mater. Chem. Front., 2017, 1, 2256 DOI: 10.1039/C7QM00235A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements