Template mediated and solvent-free route to a variety of UiO-66 metal–organic frameworks

Chao Zou; Sergei Vagin; Alexander Kronast; Bernhard Rieger

doi:10.1039/C6RA23947A

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Template mediated and solvent-free route to a variety of UiO-66 metal–organic frameworks†

Chao Zou,

^ab Sergei Vagin,^a Alexander Kronast^a and Bernhard Rieger*^a

Author affiliations

* Corresponding authors

^a WACKER-Lehrstuhl für Makrmolekulare Chemie, Technische Universität München, Lichtenbergstraße 4, Garching bei München, Germany
E-mail: rieger@tum.de

^b Department of Chemistry, South University of Science and Technology of China, Shenzhen 518055, Guangdong, P. R. China

Abstract

A facile and efficient solvent-free, template oriented route has been applied for the synthesis of UiO-66 and UiO-66 analogue metal–organic frameworks (MOFs). The crystal growth was observed via time dependent powder X-ray diffraction (PXRD) and the obtained product was fully characterized by PXRD and ATR-IR. Different substances were screened as possible templates and the water content was found to be of vital importance for morphology control.

This article is part of the themed collection: Zeolites and 3D Porous Solids

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Article information

DOI: https://doi.org/10.1039/C6RA23947A
Article type: Communication
Submitted: 25 ذو الحجة 1437
Accepted: 23 محرم 1438
First published: 24 محرم 1438

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RSC Adv., 2016,6, 102968-102971

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Template mediated and solvent-free route to a variety of UiO-66 metal–organic frameworks

C. Zou, S. Vagin, A. Kronast and B. Rieger, RSC Adv., 2016, 6, 102968 DOI: 10.1039/C6RA23947A

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Template mediated and solvent-free route to a variety of UiO-66 metal–organic frameworks†

Abstract

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Template mediated and solvent-free route to a variety of UiO-66 metal–organic frameworks

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