Issue 60, 2016

Atom-economic dehydrogenative amide synthesis via ruthenium catalysis

Abstract

Recently, a class of dehydrogenative transformations for amide bond formation have been developed. These transformations are atom-economic and environmentally-benign processes with their respective starting materials of alcohols and amines, aldehydes and amines, as well as symmetrical esters and amines, showing a promising prospect for applications. These unique protocols have been reported using various ruthenium-based catalytic systems. However, challenges still exist in this area. For example, existing catalytic systems usually suffer from low efficiency, high catalyst loading, and lack of structural diversity.

Graphical abstract: Atom-economic dehydrogenative amide synthesis via ruthenium catalysis

Article information

Article type
Review Article
Submitted
18 رجب 1437
Accepted
25 شعبان 1437
First published
27 شعبان 1437

RSC Adv., 2016,6, 55599-55607

Atom-economic dehydrogenative amide synthesis via ruthenium catalysis

C. Chen, F. Verpoort and Q. Wu, RSC Adv., 2016, 6, 55599 DOI: 10.1039/C6RA10643A

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