Issue 37, 2016
From the journal:

Dalton Transactions

Divergent reactivity of platinum(ii) and palladium(ii) methylperoxo complexes and the formation of an unusual hemi-aminal complex†

Allan R. Petersen,a   Andrew J. P. Whitea  and  George J. P. Britovsek*a  

* Corresponding authors

a Department of Chemistry, Imperial College London, Exhibition Road, London, UK
E-mail: g.britovsek@imperial.ac.uk
Fax: +44(0) 20-75945804
Tel: +44(0) 20-75945863

Abstract

The 6,6′′-diaminoterpyridine palladium(II) methylperoxo complex eliminates methyl hydroperoxide and reacts with acetone to form a novel hemi-aminal palladium complex, whereas the analogous platinum(II) complex generates formaldehyde and a platinum(II) hydroxo complex.

Graphical abstract: Divergent reactivity of platinum(ii) and palladium(ii) methylperoxo complexes and the formation of an unusual hemi-aminal complex

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Article information

DOI
https://doi.org/10.1039/C6DT01691J
Article type
Communication
Submitted
22 رجب 1437
Accepted
20 شعبان 1437
First published
23 شعبان 1437

Dalton Trans., 2016,45, 14520-14523

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Divergent reactivity of platinum(II) and palladium(II) methylperoxo complexes and the formation of an unusual hemi-aminal complex

A. R. Petersen, A. J. P. White and G. J. P. Britovsek, Dalton Trans., 2016, 45, 14520 DOI: 10.1039/C6DT01691J

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