Issue 14, 2016

Reaction of an allylstannylene with adamantyl phosphaalkyne

Abstract

The reaction of a terphenyl tin(II) compound bearing an η3 coordinating allyl ligand with adamantyl phosphaalkyne is reported. The quantitative stochiometric reaction towards one product involves an addition of one Sn–Ar bond across the C[triple bond, length as m-dash]P triple bond and formation of a phosphadistannacyclobutene ring. This kinetically favoured product can be isolated in the solid state, however, in solution, it shows rearrangement towards a new tin-phosphorus molecule over a period of five days.

Graphical abstract: Reaction of an allylstannylene with adamantyl phosphaalkyne

Supplementary files

Article information

Article type
Communication
Submitted
15 ذو الحجة 1436
Accepted
03 محرم 1437
First published
17 محرم 1437

Dalton Trans., 2016,45, 5933-5936

Reaction of an allylstannylene with adamantyl phosphaalkyne

K. M. Krebs, J. Jamin and L. Wesemann, Dalton Trans., 2016, 45, 5933 DOI: 10.1039/C5DT03792A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements