Issue 25, 2015

Control over connectivity and magnetism of tetrahedral FeSe2 chains through coordination Fe–amine complexes

Abstract

The synthesis and structural characterization is reported for [Fe(dien)2][FeSe2]2 and [Fe(tren)][FeSe2]2, two new mixed-valence compounds that contain infinite 1(FeSe2) tetrahedral chains separated by Fe–amine complexes. The inter- and intra-chain magnetic interactions can be controlled by changing the denticity of the amine while preserving the general structural motif.

Graphical abstract: Control over connectivity and magnetism of tetrahedral FeSe2 chains through coordination Fe–amine complexes

Supplementary files

Article information

Article type
Communication
Submitted
06 محرم 1436
Accepted
08 صفر 1436
First published
09 صفر 1436

Chem. Commun., 2015,51, 5355-5358

Author version available

Control over connectivity and magnetism of tetrahedral FeSe2 chains through coordination Fe–amine complexes

J. T. Greenfield, C. Pak, S. Kamali, K. Lee and K. Kovnir, Chem. Commun., 2015, 51, 5355 DOI: 10.1039/C4CC08608B

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