Issue 6, 2009

Structural and chemical complexity in multicomponent inorganic–organic framework materials

Abstract

A family of coordination polymers with remarkable structural and chemical complexity is produced when Cu and Zn are combined with 5-hydroxyisophthalic acid and 4,4′-bipyridyl. The structures of these four- and five-component phases are fully ordered, with the two metals occupying different sites and the ligands playing distinct bridging roles in each structure. In one five-component phase, oxalate forms as a product of partial ligand decomposition and is incorporated alongside the two original ligands into the resultant solid. The valence of Cu and the Cu/Zn ratios differ between the phases, in spite of similar synthetic conditions.

Graphical abstract: Structural and chemical complexity in multicomponent inorganic–organic framework materials

Supplementary files

Article information

Article type
Communication
Submitted
21 ذو القعدة 1429
Accepted
09 محرم 1430
First published
15 صفر 1430

CrystEngComm, 2009,11, 980-985

Structural and chemical complexity in multicomponent inorganic–organic framework materials

R. K. Feller and A. K. Cheetham, CrystEngComm, 2009, 11, 980 DOI: 10.1039/B820718F

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