Issue 32, 2009

Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines

Abstract

Rhodium-catalyzed asymmetric arylation of imines using electronically and sterically-modified chiral diene ligands gave the corresponding diarylmethylamines in high yield and with high enantioselectivity using just 0.3 mol% of catalyst.

Graphical abstract: Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines

Supplementary files

Article information

Article type
Communication
Submitted
09 ربيع الأول 1430
Accepted
28 ربيع الثاني 1430
First published
24 جمادى الأولى 1430

Chem. Commun., 2009, 4815-4817

Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines

K. Okamoto, T. Hayashi and V. H. Rawal, Chem. Commun., 2009, 4815 DOI: 10.1039/B904624K

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