Issue 54, 2024

Direct photocatalytic C–H functionalization mediated by a molybdenum dioxo complex

Abstract

Direct photocatalytic C–H activation mediated by MoO2Cl2(bpy-tBu), a unique photoactive metal OXO, is presented. The limiting step, reoxidation to the Mo dioxo, is evaluated and proposed to occur via a key Cl loss event. Photocatalyst degradation occurs upon substitution of bpy-tBu with H2O generated during catalysis.

Graphical abstract: Direct photocatalytic C–H functionalization mediated by a molybdenum dioxo complex

Supplementary files

Article information

Article type
Communication
Submitted
06 شوال 1445
Accepted
05 ذو الحجة 1445
First published
05 ذو الحجة 1445

Chem. Commun., 2024,60, 6901-6904

Direct photocatalytic C–H functionalization mediated by a molybdenum dioxo complex

C. L. Baumberger, V. Z. Valley and M. B. Chambers, Chem. Commun., 2024, 60, 6901 DOI: 10.1039/D4CC01789G

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