Issue 16, 2023

Recent advances in the photocatalytic synthesis of aldehydes

Abstract

The synthesis of aldehyde compounds under mild conditions enabled by visible light-induced organic reactions is highly attractive in modern chemistry. Reagents including glyoxylic acid (or its derivatives), vinylene carbonate, methylamines, 1,3-dioxolane, and α-chloro N-methoxyphthalimide (PhthOCH2Cl), are found to be sources of the aldehyde group in photocatalytic reactions. This review summarizes the recently developed photocatalytic strategies for the installation of the formyl group into various scaffolds, mainly through the key steps of photocatalytic decarboxylation, oxidation coupling with methylamines/hydrolysis, hydrogen atom transfer of 1,3-dioxolane, and direct generation of formyl radicals.

Graphical abstract: Recent advances in the photocatalytic synthesis of aldehydes

Article information

Article type
Review Article
Submitted
18 ذو الحجة 1444
Accepted
23 ذو الحجة 1444
First published
24 ذو الحجة 1444

Org. Chem. Front., 2023,10, 4198-4210

Recent advances in the photocatalytic synthesis of aldehydes

Y. Wang, X. Liu and W. He, Org. Chem. Front., 2023, 10, 4198 DOI: 10.1039/D3QO01026K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements