Issue 18, 2023

Single-ion magnetism behaviors in lanthanide(iii) based coordination frameworks

Abstract

Single-ion magnets (SIMs) and single-molecule magnets (SMMs) are typically made up of 3d and/or 4f complexes that possess significant energy barriers to prevent the spin reversal behavior at the molecular level. SMMs/SIMs have various promising applications, including high-density information storage, molecular spintronics, and quantum computers. This article offers an overview of single-ion magnetism in lanthanide(III)-based coordination frameworks that consist of self-assemblies in one-, two-, and three-dimensions. The large magnetic moments and magnetic anisotropy of lanthanide(III) ions make them potential candidates for SIMs/SMMs. Additionally, the coordination framework structure enables multi-functionalities such as responsiveness to external stimuli, proton conduction, high structural stability, and host–guest interactions. These multi-functionalities indicate that the lanthanide(III)-based magnetic metal coordination frameworks represent an exciting platform for the development of a new generation of SIMs/SMMs.

Graphical abstract: Single-ion magnetism behaviors in lanthanide(iii) based coordination frameworks

Article information

Article type
Review Article
Submitted
28 شوال 1444
Accepted
06 محرم 1445
First published
07 محرم 1445

Inorg. Chem. Front., 2023,10, 5212-5224

Single-ion magnetism behaviors in lanthanide(III) based coordination frameworks

Q. Wan, M. Wakizaka and M. Yamashita, Inorg. Chem. Front., 2023, 10, 5212 DOI: 10.1039/D3QI00925D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements