Issue 49, 2023

A tetranuclear magnesium hydride cluster with a four-coordinate hydride in near square-planar geometry

Abstract

A tetranuclear magnesium hydride complex based on the β-oxo-δ-diiminate (BODDI) ligand was isolated. In the solid state, the complex features three bridging μ2-hydrides and one unprecedented four-coordinate hydride in a nearly square-planar coordination environment. In the solid state, two different coordination polymers are observed depending on whether the axial or equatorial oxygen lone pairs of 1,4-dioxane are engaged in bonding to magnesium.

Graphical abstract: A tetranuclear magnesium hydride cluster with a four-coordinate hydride in near square-planar geometry

Supplementary files

Article information

Article type
Communication
Submitted
09 رمضان 1444
Accepted
03 ذو القعدة 1444
First published
11 ذو القعدة 1444

Chem. Commun., 2023,59, 7627-7630

A tetranuclear magnesium hydride cluster with a four-coordinate hydride in near square-planar geometry

F. Seifert, H. Görls, S. Kupfer and R. Kretschmer, Chem. Commun., 2023, 59, 7627 DOI: 10.1039/D3CC01608K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements