Issue 10, 2023

Guest-dependent bond flexibility in UiO-66, a “stable” MOF

Abstract

We report “flexibility constants”—a conceptual analog to metal–ligand stability constants—of UiO-66, the prototypical “stable” MOF, across a wide temperature range in both vacuum and in the presence of typical guest solvents. With these data, we extract key thermodynamic parameters governing the reversible bond equilibrium and demonstrate that guest molecules strongly favor the reversible dissociation of MOF metal–linker bonds.

Graphical abstract: Guest-dependent bond flexibility in UiO-66, a “stable” MOF

Supplementary files

Article information

Article type
Communication
Submitted
07 ربيع الثاني 1444
Accepted
16 جمادى الثانية 1444
First published
20 جمادى الثانية 1444

Chem. Commun., 2023,59, 1309-1312

Author version available

Guest-dependent bond flexibility in UiO-66, a “stable” MOF

K. Fabrizio, A. B. Andreeva, K. Kadota, A. J. Morris and C. K. Brozek, Chem. Commun., 2023, 59, 1309 DOI: 10.1039/D2CC05895B

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