Issue 77, 2022

An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation

Abstract

Through the application of a redox-innocent aryl diimine chelate, the discovery and utilization of a cobalt catalyst, (Ph2PPrADI)Co, that exhibits carbonyl hydrosilylation turnover frequencies of up to 330 s−1 is described. This activity is believed to be the highest ever reported for metal-catalyzed carbonyl hydrosilylation.

Graphical abstract: An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation

Supplementary files

Article information

Article type
Communication
Submitted
23 ذو الحجة 1443
Accepted
26 محرم 1444
First published
26 محرم 1444

Chem. Commun., 2022,58, 10793-10796

Author version available

An aryl diimine cobalt(I) catalyst for carbonyl hydrosilylation

A. Sharma, S. So, J. Kim, S. N. MacMillan, M. Baik and R. J. Trovitch, Chem. Commun., 2022, 58, 10793 DOI: 10.1039/D2CC04089A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements