Issue 13, 2022

In situ generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes

Abstract

Atom transfer radical addition of alkyl halides to alkenes was developed using a low amount of a stable initiator, amine borane complexes. Thanks to a slow hydroboration step, the overall carbohalogenation process leads to good isolated yields.

Graphical abstract: In situ generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes

Supplementary files

Article information

Article type
Communication
Submitted
07 ربيع الثاني 1443
Accepted
14 جمادى الثانية 1443
First published
14 جمادى الثانية 1443

Chem. Commun., 2022,58, 2124-2127

In situ generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes

V. Liautard, M. Delgado, B. Colin, L. Chabaud, G. Michaud and M. Pucheault, Chem. Commun., 2022, 58, 2124 DOI: 10.1039/D1CC06390A

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