Issue 2, 2022

Nucleophilic borylation of fluorobenzenes with reduced arylboranes

Abstract

Two challenging but rewarding topics in chemical synthesis are C–F-bond activation and the development of B-centered nucleophiles. We have now tackled both subjects simultaneously by forming aryl–B bonds via SNAr-type reactions on fluorobenzenes under mild conditions using Na2[FluB[double bond, length as m-dash]BFlu], Li2[HBFlu], and Li2[Me2DBA] (BFlu = 9-borafluorenyl, Me2DBA = 9,10-dimethyl-9,10-dihydro-9,10-diboraanthracene).

Graphical abstract: Nucleophilic borylation of fluorobenzenes with reduced arylboranes

Supplementary files

Article information

Article type
Communication
Submitted
29 ربيع الأول 1443
Accepted
24 ربيع الثاني 1443
First published
24 ربيع الثاني 1443

Chem. Commun., 2022,58, 254-257

Nucleophilic borylation of fluorobenzenes with reduced arylboranes

H. Budy, S. E. Prey, C. D. Buch, M. Bolte, H. Lerner and M. Wagner, Chem. Commun., 2022, 58, 254 DOI: 10.1039/D1CC06225E

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